chloro(hydrido)ruthenium;triphenylphosphane | 54055-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloro(hydrido)ruthenium;triphenylphosphane
• CAS: 54055-67-3
• 化学式: C₃₆H₃₁ClP₂Ru
• 分子量: 662.113
• InChiKey: ADPIWCINCYEGAV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloro(hydrido)ruthenium;triphenylphosphane 、 1,3-环庚二烯 以 二氯甲烷-D2 为溶剂， 生成 (η5-cycloheptadienyl)chloro-bis(triphenylphosphino)ruthenium 、 (η(3)-C7H11)RuCl(PPh3)2
  参考文献：
  名称：

  The reaction between [(η5-C7H9)RuCl(H)(PPh3)2] and dihydrogen

  摘要：

  [(eta(5)-C7H9)RuCl(PPh3)(2)] has been shown to react with hydrogen to give [(eta(3)-C7H11)RuCl(PPh3)(2)] initially, and then [RuCl(HXPPh3)(3)], [Ru2H4Cl2(PPh(3)4)], and unidentified compound(s). This is a rare example of the hydrogenation of a coordinated ligand, where the ligand remains coordinated to the metal. It is suggested that the reverse reaction, involving the conversion of [(eta(3)-C7H11)RuCl(PPh3)(2)] to [(eta(5)-C7H9)RuCl(PPh3)(2)] is a rare example of the loss of dihydrogen from a coordinated ligand. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00428-2
• 作为产物：
  描述：

  (η5-cycloheptadienyl)chloro-bis(triphenylphosphino)ruthenium 、 氢气 以 二氯甲烷-D2 为溶剂， 生成 chloro(hydrido)ruthenium;triphenylphosphane 、
  参考文献：
  名称：

  The reaction between [(η5-C7H9)RuCl(H)(PPh3)2] and dihydrogen

  摘要：

  [(eta(5)-C7H9)RuCl(PPh3)(2)] has been shown to react with hydrogen to give [(eta(3)-C7H11)RuCl(PPh3)(2)] initially, and then [RuCl(HXPPh3)(3)], [Ru2H4Cl2(PPh(3)4)], and unidentified compound(s). This is a rare example of the hydrogenation of a coordinated ligand, where the ligand remains coordinated to the metal. It is suggested that the reverse reaction, involving the conversion of [(eta(3)-C7H11)RuCl(PPh3)(2)] to [(eta(5)-C7H9)RuCl(PPh3)(2)] is a rare example of the loss of dihydrogen from a coordinated ligand. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00428-2