1,2,4,5-tetrachloro-3,6-divinyl-benzene | 23588-85-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,4,5-tetrachloro-3,6-divinyl-benzene
• 英文别名: 1,2,4,5-Tetrachlor-3,6-divinyl-benzol；Tetrachlor-phenylene ethylene；1,2,4,5-tetrachloro-3,6-bis(ethenyl)benzene
• CAS: 23588-85-4
• 化学式: C₁₀H₆Cl₄
• 分子量: 267.97
• InChiKey: INMPEUIPFUEEAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,4,5-tetrachloro-3,6-divinyl-benzene 在 氢溴酸 、 苯 作用下， 生成 1,4-bis-(2-bromo-ethyl)-2,3,5,6-tetrachloro-benzene
  参考文献：
  名称：

  The Preparation of 1,4-Divinyl-2,3,5,6-tetrachlorobenzene and its Copolymerization with Styrene¹

  摘要：

  DOI：

  10.1021/ja01159a017
• 作为产物：
  描述：

  1,4-bis-(1-bromo-ethyl)-2,3,5,6-tetrachloro-benzene 在 氢氧化钾 作用下， 生成 1,2,4,5-tetrachloro-3,6-divinyl-benzene
  参考文献：
  名称：

  The Preparation of 1,4-Divinyl-2,3,5,6-tetrachlorobenzene and its Copolymerization with Styrene¹

  摘要：

  DOI：

  10.1021/ja01159a017

文献信息

• Photographisches Material
  申请人：Agfa-Gevaert AG

  公开号：EP0003043A1

  公开（公告）日：1979-07-25

  Die mechanischen und elektrostatischen Eigenschaften photographischer, wenigstens eine Silberhalogenidschicht enthaltender Materialien werden durch Zusatz vernetzter Acrylsäure- und/oder Methacrylsäurepolymerisatteilchen zu wenigstens einer der Schichten des Materials verbessert. Die Polymerisatteilchen werden hergestellt entweder (a) durch innerte Emulsionspolymerisation von Acrylsaüre-und/oder Methacrylsäuremonomeren in Gegenwart vernetztend wirkender Monomerer, Brechen der Emulsion und Redispergieren der Polymerteilchen in Wasser, oder (b) durch Emulsionspolymerisation kurzkettiger Ester der Acrylsäure- und/oder Methacrylsäuremonomeren in Gegenwart vernetzend wirkender Monomerer und anschließender Verseifung des Polymeren.

  将交联的丙烯酸和/或甲基丙烯酸聚合物颗粒添加到至少一层材料中，可改善含有至少一层卤化银层的感光材料的机械和静电特性。聚合物微粒的制备方法有两种：(a) 在有交联单体存在的情况下，对丙烯酸和/或甲基丙烯酸单体进行内部乳液聚合，然后破碎乳液并将聚合物微粒重新分散在水中；或 (b) 在有交联单体存在的情况下，对丙烯酸和/或甲基丙烯酸单体的短链酯进行乳液聚合，然后对聚合物进行皂化。
• A recording material having antistatic properties
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0505626A1

  公开（公告）日：1992-09-30

  A recording material comprising a sheet, ribbon or web support and a hydrophilic colloid binder layer incorporating an ionic copolymer in the form of dispersed particulate material providing to said material an antistatic character, characterized in that said ionic copolymer is a cross-linked addition copolymer wherein at least 30 mole % of its recurring units are recurrring units containing a sulphonic acid salt group that has been obtained via a reaction of propane sultone or butane sultone with carboxylate salt groups present originally in recurring units of said copolymer.

  一种记录材料，包括片状、带状或网状支撑物和亲水性胶体粘合剂层，粘合剂层中含有一种以分散微粒材料形式存在的离子共聚物，可为所述材料提供抗静电特性，其特征在于所述离子共聚物是一种交联加成共聚物，其中至少有 30 摩尔%的递归单元是含有磺酸盐基的递归单元，该磺酸盐基是通过丙烷磺酸酮或丁烷磺酸酮与所述共聚物递归单元中原有的羧酸盐基反应而获得的。
• Highly durable polymer electrolytic membrane for a fuel cell having a cross-linked structure
  申请人：Yoshida Masaru

  公开号：US20060134493A1

  公开（公告）日：2006-06-22

  The objective of the invention is to solve the problems of conventional polymer electrolyte membranes, including small ion-exchange capacity and low oxidation and methanol resistance. A polymer film substrate is irradiated with γ-rays, electron beams or other radiations to perform multi-graft polymerization with functional monomers and then the polymer film substrate containing the grafted molecular chains or the graft molecular chains into which sulfonic acid groups have been introduced is crosslinked by irradiation to produce a polymer electrolyte membrane that has outstanding oxidation resistance, dimensional stability, electrical conductivity and methanol resistance and which can be controlled in ion-exchange capacity over a wide range.

  本发明的目的是解决传统聚合物电解质膜的问题，包括离子交换容量小、抗氧化性和抗甲醇性低。用 γ 射线、电子束或其他辐射辐照聚合物薄膜基材，使其与功能性单体进行多接枝聚合，然后通过辐照交联含有接枝分子链或引入磺酸基团的接枝分子链的聚合物薄膜基材，生产出具有出色的抗氧化性、尺寸稳定性、导电性和耐甲醇性，且离子交换容量可在较大范围内控制的聚合物电解质膜。
• THERMOSET POLYMERS OF STYRENE TERMINATED TETRAKIS PHENOLS
  申请人：ALLIED CORPORATION

  公开号：EP0344165A1

  公开（公告）日：1989-12-06
• Crosslinked polymer electrolyte fuel cell membranes and their producing process
  申请人：Asano Masaharu

  公开号：US20060281824A1

  公开（公告）日：2006-12-14

  A polymer electrolyte membrane produced by a process in which a monofunctional vinyl monomer into which sulfonic acid groups can be introduced and a vinyl monomer having a halogen at a terminal are co-grafted into a polymer base film that has been exposed to an ionizing radiation, and the base film is exposed again to an ionizing radiation and/or heat treated so that the terminal halogen is eliminated to introduce a crosslinking structure in which the graft molecular chains are bound together.