1-chloro-(E,Z)-7,9-dodecadiene | 71701-09-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-chloro-(E,Z)-7,9-dodecadiene
• 英文别名: 1-chloro-(7E,9E)-7,9-dodecadiene；1-chloro-E,Z-7,9-dodecadiene；3,5-Dodecadiene, 12-chloro-, (3Z,5Z)-；(3E,5E)-12-chlorododeca-3,5-diene
• CAS: 71701-09-2
• 化学式: C₁₂H₂₁Cl
• 分子量: 200.752
• InChiKey: XEXGEIAGKDOJQX-VNKDHWASSA-N

物化性质

• 沸点：
  274.3±19.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-chloro-1,1-diethoxy-2-nonyne 在 盐酸 、 potassium tert-butylate 、 氢气 、 nickel diacetate 、 乙二胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.83h， 生成 1-chloro-(E,Z)-7,9-dodecadiene
  参考文献：
  名称：

  Yamamoto, Akira; Fukumoto, Takehiko, Agricultural and Biological Chemistry, 1989, vol. 53, # 9, p. 2521 - 2522

  摘要：

  DOI：

文献信息

• 1-substituted conjugated alka-(E,Z)-diene compounds and a method for the preparation thereof
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0241335B1

  公开（公告）日：1992-06-03
• YAMAMOTO, AKIRA;FUKUMOTO, TAKEHIKO, AGR. AND BIOL. CHEM., 53,(1989) N, C. 2521-2522
  作者：YAMAMOTO, AKIRA、FUKUMOTO, TAKEHIKO

  DOI：——

  日期：——
• US20140275657A1
  申请人：——

  公开号：US20140275657A1

  公开（公告）日：2014-09-18
• US9845273B2
  申请人：——

  公开号：US9845273B2

  公开（公告）日：2017-12-19
• ORGANOHALOGEN COMPOUND HAVING CONJUGATED DOUBLE BOND, PROCESS FOR PREPARING ACETATE COMPOUND AND ALCOHOL COMPOUND THEREOF, AND COMPOUND USED TO SYNTHESIZE THE ORGANOHALOGEN COMPOUND
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20240174701A1

  公开（公告）日：2024-05-30

  The present invention relates to a process for preparing an organohalogen compound of the following general formula (5), wherein R 2 represents a linear, branched, or aromatic monovalent hydrocarbon group having 1 to 10 carbon atoms, n is the number of methylene groups of 1 to 10, and X 2 represents a halogen atom, the process comprising: obtaining a reaction product mixture by subjecting a (ω-halo-2-alkenyl)triphenylphosphonium halide compound of the following general formula (1), wherein n is as defined for the general formula (5) above, X 1 and X 2 represent, independently of each other, a halogen atom, and Ph represents a phenyl group, to a phosphorus ylide preparation reaction with an alkali metal alkoxide of the following general formula (3), wherein R 1 represents a linear or branched alkyl group having 1 to 6 carbon atoms, and M represents an alkali metal atom, in the presence of a lithium halide of the following general formula (2), wherein X 3 represents a halogen atom, and then subjecting the aforesaid reaction product mixture to a Wittig reaction with an aldehyde compound of the following general formula (4), wherein R 2 is as defined for the general formula (5) above, to form the organohalogen compound of the general formula (5) above.