| 1550004-02-8

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 1550004-02-8
• 化学式: C₂₂H₁₈N₂O₂Pd
• 分子量: 448.817
• InChiKey: DQWRXYZWMGJTJP-XSEMBQBTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛 、 4，5-二甲基-1，2-苯二胺 在 盐酸 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Synthesis, spectroscopic, fluorescence properties and biological evaluation of novel Pd(II) and Cd(II) complexes of NOON tetradentate Schiff bases

  摘要：

  The solid complexes of Pd(II) and Cd(II) with N,N/bis(salicylaldehyde)4,5-dimethyl-1,2-phenylenediamine (H2L1), and N,N/bis(salicylaldehyde)4,5-dichloro-1,2-phenylenediamine (H2L2) have been synthesized and characterized by several techniques using elemental analysis (CHN), FT-IR, H-1 NMR, UV-Vis spectra and thermal analysis. Elemental analysis data proved 1:1 stoichiometry for the reported complexes while spectroscopic data indicated square planar and octahedral geometries for Pd(II) and Cd(II) complexes, respectively. The prepared ligands, Pd(II) and Cd(II) complexes exhibited intraligand (pi-pi*) fluorescence and can potentially serve as photoactive materials. Thermal behavior of the complexes was studied and kinetic parameters were determined by Coats-Redfern method. Both the ligands and their complexes have been screened for antimicrobial activities. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2013.10.015