| 136501-25-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 136501-25-2
• 化学式: C₁₀H₈N₂*C₁₉H₁₄N₂OS₂*Cu
• 分子量: 570.198
• InChiKey: LVHKITHFHQDYSD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.98
• 重原子数：
  37.0
• 可旋转键数：
  5.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  75.3
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  benzyl 2-((3-hydroxynaphthalen-2-yl)methylene)hydrazine-1-carbodithioate 、 copper diacetate 在 2,2'-bipyridyl 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  The preparation and characterization of some nickel(II) and copper(II) complexes of ons ligands

  摘要：

  New nickel(II) and copper(II) complexes of four Schiff base ligands formed from benzoylacetone and 2-hydroxynaphthaldehyde with S-alkyl esters of dithiocarbazic acid have been prepared and characterized by IR, NMR, ESR and electronic spectroscopic techniques. The Schiff bases yield neutral 1:1 complexes of general formula M(ONS) (ONS2- = dinegatively charged anions of the Schiff base ligands; M = Ni, Cu). Magnetic and spectral evidence support a dimeric structure for these complexes. The complexes, M(ONS)B (B = py, dipy, phen), were also prepared. The complexes, M(ONS)py, are square-planar but electronic and ESR spectroscopic data support a five-coordinate geometry for the Cu(ONS)B (B = dipy, phen) complexes. Based on spectroscopic and magnetic data, a thiolato, sulphur-bridged, octahedral structure is assigned to the Ni(ONS)B (B = dipy, phen) complexes.

  DOI：

  10.1016/s0277-5387(00)81265-6