benzyl 2-((3-hydroxynaphthalen-2-yl)methylene)hydrazine-1-carbodithioate | 136493-63-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: benzyl 2-((3-hydroxynaphthalen-2-yl)methylene)hydrazine-1-carbodithioate
• CAS: 136493-63-5
• 化学式: C₁₉H₁₆N₂OS₂
• 分子量: 352.481
• InChiKey: JNMBSLIJWJSFTI-UHFFFAOYSA-N

物化性质

• 熔点：
  205 °C
• 沸点：
  548.4±60.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.69
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  44.62
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  benzyl 2-((3-hydroxynaphthalen-2-yl)methylene)hydrazine-1-carbodithioate 、 copper diacetate 在 pyridine 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  The preparation and characterization of some nickel(II) and copper(II) complexes of ons ligands

  摘要：

  New nickel(II) and copper(II) complexes of four Schiff base ligands formed from benzoylacetone and 2-hydroxynaphthaldehyde with S-alkyl esters of dithiocarbazic acid have been prepared and characterized by IR, NMR, ESR and electronic spectroscopic techniques. The Schiff bases yield neutral 1:1 complexes of general formula M(ONS) (ONS2- = dinegatively charged anions of the Schiff base ligands; M = Ni, Cu). Magnetic and spectral evidence support a dimeric structure for these complexes. The complexes, M(ONS)B (B = py, dipy, phen), were also prepared. The complexes, M(ONS)py, are square-planar but electronic and ESR spectroscopic data support a five-coordinate geometry for the Cu(ONS)B (B = dipy, phen) complexes. Based on spectroscopic and magnetic data, a thiolato, sulphur-bridged, octahedral structure is assigned to the Ni(ONS)B (B = dipy, phen) complexes.

  DOI：

  10.1016/s0277-5387(00)81265-6

文献信息

• Singh, Ritu; Mittal; Malik, Sachin, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2007, vol. 46, # 9, p. 1406 - 1413
  作者：Singh, Ritu、Mittal、Malik, Sachin、Singh

  DOI：——

  日期：——