[PtMe2(bpox)] | 105040-59-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [PtMe2(bpox)]
• 英文别名: [PtMe₂(bpox)]；[PtMe2(2,5-bis(2-pyridyl)-1,3,4-oxadiazole)]；[(2,5-di-2-pyridyl-1,3,4-oxadiazole)PtMe2]
• CAS: 105040-59-3
• 化学式: C₁₄H₁₄N₄OPt
• 分子量: 449.371
• InChiKey: IMOKNKZJIIPCPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PtMe2(bpox)] 在 碘甲烷 作用下， 以 二氯甲烷 为溶剂， 以>99的产率得到
  参考文献：
  名称：

  Scott, John D.; Puddephatt, Richard J., Organometallics, 1986, vol. 5, # 12, p. 2522 - 2529

  摘要：

  DOI：
• 作为产物：
  描述：

  bis[dimethyl(μ-dimethylsulfide)platinum(II)] 、 2,5-bis(2-pyridyl)-1,3,4-oxadiazole 以 二氯甲烷 为溶剂， 以97%的产率得到[PtMe2(bpox)]
  参考文献：
  名称：

  Scott, John D.; Puddephatt, Richard J., Organometallics, 1986, vol. 5, # 12, p. 2522 - 2529

  摘要：

  DOI：

文献信息

• The role of solvent in organometallic chemistry — Oxidative addition with dichloromethane or chloroform
  作者：Anwar Abo-Amer、Matthew S. McCready、Fenbao Zhang、Richard J. Puddephatt

  DOI：10.1139/v11-096

  日期：2012.1

  Dimethylplatinum(II) complexes [PtMe₂(NN)], with NN = diimine ligand, can react with dichloromethane or chloroform solvent to give the corresponding organoplatinum(IV) complexes [PtClMe₂(CH₂Cl)(NN)] or [PtClMe₂(CHCl₂)(NN)], respectively. The products can exist in isomeric forms, corresponding to products of cis or trans oxidative addition. The structures of three dichloromethane adducts and one chloroform adduct are reported.

  二甲基铂(II)配合物[PtMe₂(NN)]，其中NN为双亚胺配体，可以与二氯甲烷或氯仿溶剂反应，生成相应的有机铂(IV)配合物[PtClMe₂(CH₂Cl)(NN)]或[PtClMe₂(CHCl₂)(NN)]。产物可以存在于顺式或反式氧化加成产物对应的同分异构体形式。报道了三个二氯甲烷加合物和一个氯仿加合物的结构。
• Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids
  作者：Muhieddine A. Safa、Anwar Abo-Amer、Aneta Borecki、Benjamin F. T. Cooper、Richard J. Puddephatt

  DOI：10.1021/om2009217

  日期：2012.4.9

  Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)(2) to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic acids [PtBrMe2CH2C6H4B(OH)(2)}(NN)], with the bidentate ligand NN = 4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine or 2,5-bis(2-pyridyl)-1,3,4-oxadiazole. The complexes undergo self-assembly in the solid state through hydrogen bonding to give dimers, polymers, or sheet structures.
• The supramolecular chemistry of organoplatinum complexes containing amide or alcohol functional groups
  作者：Anwar Abo-Amer、Paul D. Boyle、Richard J. Puddephatt

  DOI：10.1016/j.jorganchem.2014.08.006

  日期：2014.11

  The oxidative addition of alkyl bromides, RBr, to the dimethylplatinum(II) complex [PtMe2(bpox)], 1, bpox = 2,5-bis(2-pyridyl)-1,3,4-oxadiazole gave the corresponding organoplatinum(IV) complexes [PtBrMe2(R)(bpox)], R = CH2-4-C6H4C(=O)NHCH2Ph, 2; R = CH2-4-C6H4C(=O)NH-4-C6H4-t-Bu, 3; R = CH2-4-C6H4C(=O)NH-3,5-C6H3-t-Bu-2, 4; R = CH2-2-C6H4CH2OH, 5, which contain amide or alcohol functional groups. Several of these complexes form supramolecular polymers in the solid state through intermolecular hydrogen bonding. In complex 2 there is complementary hydrogen bonding between amide groups, while in complexes 3 and 5 the hydrogen bonding involves the oxygen atom of the bpox ligand as acceptor. (C) 2014 Elsevier B. V. All rights reserved.