8-(5,8,11,14-Tetraoxa-2,17,19,21-tetrathiabicyclo[16.3.0]henicos-1(18)-en-20-ylidene)-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene | 1541205-64-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 8-(5,8,11,14-Tetraoxa-2,17,19,21-tetrathiabicyclo[16.3.0]henicos-1(18)-en-20-ylidene)-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
• 英文别名: 8-(5,8,11,14-tetraoxa-2,17,19,21-tetrathiabicyclo[16.3.0]henicos-1(18)-en-20-ylidene)-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
• CAS: 1541205-64-4
• 化学式: C₂₄H₂₆N₂O₄S₄
• 分子量: 534.745
• InChiKey: ANFIWYLNGRLKEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  164
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 8-(5,8,11,14-Tetraoxa-2,17,19,21-tetrathiabicyclo[16.3.0]henicos-1(18)-en-20-ylidene)-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene 、 potassium nitrate 以 乙醇 、 水 、 乙腈 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes

  摘要：

  Two novel redox-active 1,3-dithiole (DT) ring-fused 4,5-diazafluorene ligands with crown ether moieties (L1 and L2) were synthesized and characterized. The crystal structure of Ll was studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding bis(bipyridine)ruthenium(II) complexes [4: Ru L1(bpy)(2) and 5: Ru L2(bpy)(2)], were also been investigated. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.12.013
• 作为产物：
  描述：

  4,5-二氮芴-9-酮 、 5,8,11,14-tetraoxa-2,17,19,21-tetrathiabicyclo<161.3.0>henicos.1(18)-ene-20-thione 在 三甲氧基磷 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以31%的产率得到8-(5,8,11,14-Tetraoxa-2,17,19,21-tetrathiabicyclo[16.3.0]henicos-1(18)-en-20-ylidene)-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
  参考文献：
  名称：

  Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes

  摘要：

  Two novel redox-active 1,3-dithiole (DT) ring-fused 4,5-diazafluorene ligands with crown ether moieties (L1 and L2) were synthesized and characterized. The crystal structure of Ll was studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding bis(bipyridine)ruthenium(II) complexes [4: Ru L1(bpy)(2) and 5: Ru L2(bpy)(2)], were also been investigated. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.12.013

文献信息

• Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes
  作者：Katsuya Sako、Toshiaki Kakehi、Shota Nakano、Hiroyuki Oku、Xu Feng Shen、Tetsuo Iwanaga、Manami Yoshikawa、Kouta Sugahara、Shinji Toyota、Hiroyuki Takemura、Teruo Shinmyozu、Michito Shiotsuka、Hitoshi Tatemitsu

  DOI：10.1016/j.tetlet.2013.12.013

  日期：2014.1

  Two novel redox-active 1,3-dithiole (DT) ring-fused 4,5-diazafluorene ligands with crown ether moieties (L1 and L2) were synthesized and characterized. The crystal structure of Ll was studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding bis(bipyridine)ruthenium(II) complexes [4: Ru L1(bpy)(2) and 5: Ru L2(bpy)(2)], were also been investigated. (C) 2013 Elsevier Ltd. All rights reserved.