anthracene-9,10-diylbis(methylene)diphosphonic acid | 369362-83-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthracene-9,10-diylbis(methylene)diphosphonic acid
• 英文别名: 9,10-bis(dihydroxyphosphinylmethyl)anthracene；anthracene-9,10-diyldimethyl-bis-phosphonic acid；Anthracen-9,10-diyldimethyl-bis-phosphonsaeure；Anthracendiyl-(9.10)-bis-methylphosphonsaeure；9.10-Bis-phosphonomethyl-anthracen；[10-(phosphonomethyl)anthracen-9-yl]methylphosphonic acid
• CAS: 369362-83-4
• 化学式: C₁₆H₁₆O₆P₂
• 分子量: 366.247
• InChiKey: MGNGFVALGBPJNX-UHFFFAOYSA-N

物化性质

• 熔点：
  215 °C (decomp)
• 沸点：
  765.1±70.0 °C(Predicted)
• 密度：
  1.602±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  9,10-二(氯甲基)蒽 在 盐酸 作用下， 反应 6.0h， 生成 anthracene-9,10-diylbis(methylene)diphosphonic acid
  参考文献：
  名称：

  摘要：

  Water-soluble anthracene derivatives containing carboxy, dihydroxyphosphinyl, or pyridinium fragments bound via methylene groups to 9- and 10-carbon atoms were prepared, and their spectra, solubility, and reactivity toward singlet oxygen were studied. Using sodium alpha,alpha '-(anthracene-9,10-diyl)bis(methylmalonate) as acceptor, it is possible to determine the quantum efficiency of singlet oxygen generation in aqueous solutions and in microheterogeneous media in the presence of biomacromolecules.

  DOI：

  10.1023/a:1012369120376

文献信息

• The Aqueous Solubility of Acetanilide
  作者：Thomas S. Logan

  DOI：10.1021/ja01223a046

  日期：1945.7
• Mesoporous aluminium organophosphonates: a reusable chemsensor for the detection of explosives
  作者：Dongdong Li、Xiang Yu

  DOI：10.1016/j.jssc.2016.04.004

  日期：2016.7

  Rapid and sensitive detection of explosives is in high demand for homeland security and public safety. In this work, electron-rich of anthracene functionalized mesoporous aluminium organophosphonates (En-AlPs) were synthesized by a one-pot condensation process. The mesoporous structure and strong blue emission of En-AlPs were confirmed by the NZ adsorption-desorption isotherms, transmission electron microscopy images and fluorescence spectra. The materials En-AlPs can serve as sensitive chemosensors for various electron deficient nitroderivatives, with the quenching constant and the detection limit up to 1.5 x 10(6) M-1 and 0.3 ppm in water solution. More importantly, the materials can be recycled for many times by simply washed with ethanol, showing potential applications in explosives detection. (C) 2016 Elsevier Inc. All rights reserved.
• US4233251A
  申请人：——

  公开号：US4233251A

  公开（公告）日：1980-11-11
• ——
  作者：N. A. Kuznetsova、N. S. Gretsova、O. A. Yuzhakova、V. M. Negrimovskii、O. L. Kaliya、E. A. Luk'yanets

  DOI：10.1023/a:1012369120376

  日期：——

  Water-soluble anthracene derivatives containing carboxy, dihydroxyphosphinyl, or pyridinium fragments bound via methylene groups to 9- and 10-carbon atoms were prepared, and their spectra, solubility, and reactivity toward singlet oxygen were studied. Using sodium alpha,alpha '-(anthracene-9,10-diyl)bis(methylmalonate) as acceptor, it is possible to determine the quantum efficiency of singlet oxygen generation in aqueous solutions and in microheterogeneous media in the presence of biomacromolecules.