[4,4'-Bipyridine]-3,3'-dicarboxylic acid, dicesium salt | 131366-90-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [4,4'-Bipyridine]-3,3'-dicarboxylic acid, dicesium salt
• 英文别名: dicesium 4,4'-bipyridinyl-3,3'-dicarboxylate；Dicesium-4,4'-bipyridine-3,3'-dicarboxylate
• CAS: 131366-90-0
• 化学式: C₁₂H₆N₂O₄*2Cs
• 分子量: 508.001
• InChiKey: FMEIMTXKRVOARB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.13
• 重原子数：
  19.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [4,4'-Bipyridine]-3,3'-dicarboxylic acid, dicesium salt 以 N,N-二甲基甲酰胺 为溶剂， 反应 96.5h， 生成 3,18-di(3-sulfonatopropyl)-7,8,10,11,13,14-hexahydro-6,9,12,15-tetraoxa-3,18-diazonia-dibenzo[a,c]cyclohexadecene-5,16-dione
  参考文献：
  名称：

  Synthesis of Crown-Ester-Bipyridines and Crown-Ester-Viologens

  摘要：

  Six novel 4,4'-bipyridine-crown-esters, derived from [4,4']bipyridinyl-3,3'-dicarboxylic acid, [4,4']bipyridinyl-2,2'-dicarboxylic acid and [4,4']bipyridinyl-2,2',6,6'-tetra-carboxylic acid were synthesized employing a procedure closely related to the 'cesium carbonate method'. The 4,4'-bipyridine-crown-esters differ in their substitution positions of the aromatic bipyridine-units, as well as in the geometric extensions of their crown-ester moieties. Addition of 1,3-propane sultone to the 4,4'-bipyridine-crown-esters resulted in five novel propanesultonated 4,4'-bipyridine-crown-esteiviologens.

  DOI：

  10.1055/s-2005-861829
• 作为产物：
  描述：

  4-溴-3-甲基吡啶 在 barium dihydroxide 、 potassium permanganate 、 苄基三乙基氯化铵 、 三苯基膦 、 nickel dichloride 、 锌 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 50.0h， 生成 [4,4'-Bipyridine]-3,3'-dicarboxylic acid, dicesium salt
  参考文献：
  名称：

  Synthesis of Crown-Ester-Bipyridines and Crown-Ester-Viologens

  摘要：

  Six novel 4,4'-bipyridine-crown-esters, derived from [4,4']bipyridinyl-3,3'-dicarboxylic acid, [4,4']bipyridinyl-2,2'-dicarboxylic acid and [4,4']bipyridinyl-2,2',6,6'-tetra-carboxylic acid were synthesized employing a procedure closely related to the 'cesium carbonate method'. The 4,4'-bipyridine-crown-esters differ in their substitution positions of the aromatic bipyridine-units, as well as in the geometric extensions of their crown-ester moieties. Addition of 1,3-propane sultone to the 4,4'-bipyridine-crown-esters resulted in five novel propanesultonated 4,4'-bipyridine-crown-esteiviologens.

  DOI：

  10.1055/s-2005-861829

文献信息

• Duerr, Heinz; Kilburg, Heike; Bossmann, Stefan, Synthesis, 1990, # 9, p. 773 - 778
  作者：Duerr, Heinz、Kilburg, Heike、Bossmann, Stefan

  DOI：——

  日期：——