2-(9-Anthryl)ethyl bromide | 122875-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-(9-Anthryl)ethyl bromide
• 英文别名: 9-Bromoethylanthracene；9-(2-bromoethyl)anthracene
• CAS: 122875-66-5
• 化学式: C₁₆H₁₃Br
• 分子量: 285.183
• InChiKey: XMDHVBVIADIYSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-(9-Anthryl)ethyl bromide 在 sodium carbonate 作用下， 以 乙腈 为溶剂， 反应 24.0h， 生成 9-[2-(N-methyl-N-phenylamino)ethyl]-10-cyanoanthracene
  参考文献：
  名称：

  Donor−Acceptor Interaction and Photochemistry of Polymethylene-Linked Bichromophores in Solution

  摘要：

  The ground-state and the excited-state spectroscopic properties of four series of polymethylene-linked anthracene-dialkylaniline bichromophores were compared as a probe to the relationship between energetics and distance in photoinduced electron transfer (PET). The results demonstrate that, when the energy level of the charge transfer (CT) stale is lowered below that of the localized excited state by appropriate substituents, there is a strong electron-donor-acceptor (EDA) interaction in the ground state which is absent in other bichromophores. Absorption and fluorescence excitation studies revealed that there is an unusually strong EDA interaction in the ground state of A-2 which is absent in other members in the A series. When A-2 is excited directly into this EDA absorption, it exhibits two CT emissions, one at 490 nm and the other at 605 nm. The quantum yield (tau(f)) and the lifetime (Phi(f)) of the two emissions are dependent on the viscosity of the alkane solvent. The Phi(f) and the tau(f) of the 490 nm emission increased when the solvent viscosity tvas increased; however, those of the 605 nm emission remained essentially unchanged. The risetime of the 605 nm emission is 420 ps, but that of the 490 nm emission is instrument-function limiting. The results suggest that the two CT emissions may be derived from the two different conformations of the CT state. The 490 nm emission may be derived from the trans conformer of A-2, which is the major conformer at equilibrium. The EDA interaction in the trans conformer of A-2 may be treated as a type of through-sigma-bond interaction via the spacer between the n orbital of the anilino nitrogen and the pi orbital of the anthryl group. The direct excitation of A-2 from its EDA ground state to the CT state indicates that PET may occur in a sigma-linked bichromophoric system upon light absorption, thus reaching the limiting rate of a photochemical process.

  DOI：

  10.1021/ja9523698
• 作为产物：
  描述：

  9-(2-羟乙基)蒽 在 三溴化磷 作用下， 以 苯 为溶剂， 反应 1.0h， 以76%的产率得到2-(9-Anthryl)ethyl bromide
  参考文献：
  名称：

  2-(9-蒽基)乙基自由基的neophyl样重排

  摘要：

  实验练习与迁移理论 1,2 du groupe aryle dans les radicaux ([anthryl-9]-2) Ethe et ([phenyl-10 anthryl-9]-2) Ethe

  DOI：

  10.1021/ja00202a010

文献信息

• Systematic Investigation of Photoinduced Electron Transfer Controlled by Internal Charge Transfer and Its Consequences for Selective PdCl₂Coordination
  作者：Thomas Schwarze、Wulfhard Mickler、Carsten Dosche、Roman Flehr、Tillmann Klamroth、Hans-Gerd Löhmannsröben、Peter Saalfrank、Hans-Jürgen Holdt

  DOI：10.1002/chem.200902281

  日期：2010.2.8

  fluorophore–spacer–receptor format were prepared for detection of PdCl2 by fluorescence enhancement. The fluorescent probes 1–13 consist of a fluorophore group, an alkyl spacer and a dithiomaleonitrile PdCl2 receptor. First, varying the length of the alkylene spacer (compounds 1–3) revealed a dominant through‐space pathway for oxidative photoinduced electron transfer (PET) in CH2‐bridged dithiomaleonitrile fluoroionophores

  制备了荧光团-间隔基-受体形式的氟离子载体，用于通过荧光增强检测PdCl 2。所述荧光探针1 - 13包括荧光团基团，烷基间隔基和dithiomaleonitrile的PdCl的2受体。首先，改变所述亚烷基间隔（化合物的长度1 - 3）揭示了氧化光致电子在CH转移（PET）显性通过空间通路2 -bridged dithiomaleonitrile fluoroionophores。其次，荧光探针4 – 9包含两个通过CH 2连接的蒽或pyr片段合成了二硫代马来腈单元的桥。的氧化电势（的调制Ë牛通过吸电子或在蒽部分-donating组）规定了氧化PET（Δ热力学驱动力ģ PET在双）（anthrylmethylthio）maleonitriles，因此荧光量子产率（Φ ˚F） ， 也。确认了新概念并将其转移到pyr配体上，并且在PdCl 2存在下，荧光增强（FE）分别通过7和8（FE = 5
• Viscosity improver grafted with unsaturated acylating agent and a polyaromatic hydrocarbon
  申请人：McDougall Patrick J.

  公开号：US09234153B2

  公开（公告）日：2016-01-12

  Disclosed is an oil-soluble lubricating oil additive composition, suitable for use as a dispersant viscosity index improver in lubricating oils; prepared by the process which comprises reacting a hydrocarbon polymer having a number average molecular weight (Mn) between about 7,000 and about 500,000 wherein the polymer backbone has been functionalized with an ethylenically unsaturated acylating agent and a hydroxyl-linked polycyclic fused ring component.

  公开了一种油溶性润滑油添加剂组合物，适用于作为润滑油中的分散剂粘度指数改进剂；该组合物是通过反应具有平均数分子量（Mn）在约7,000至约500,000之间的烃基聚合物制备的，其中聚合物骨架已经与乙烯基不饱和酰化剂和羟基连接的多环融合环组分进行了官能化。
• Sugimoto, Akira; Matsumoto, Keisuke; Maruyama, Hideyuki, Journal of Chemical Research, Miniprint, 1999, # 2, p. 601 - 727
  作者：Sugimoto, Akira、Matsumoto, Keisuke、Maruyama, Hideyuki、Mizuno, Kazuhiko、Uehara, Kaku

  DOI：——

  日期：——
• US20140274842A1
  申请人：——

  公开号：——

  公开（公告）日：——
• Photopolymerization initiator and photopolymerizable composition
  申请人：TOKUYAMA CORPORATION

  公开号：EP1431315B1

  公开（公告）日：2007-10-17