Pt(CNC₆H₄-p-OMe)₂Cl₂ | 27902-71-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Pt(CNC₆H₄-p-OMe)₂Cl₂
• 英文别名: cis-Cl2Pt(CNC64-p-OMe)2；cis-[PtCl2(CNC6H4OMe-4)2]；cis-[PtCl2(CN(4-MeOC6H4))2]；Dichloroplatinum;1-isocyano-4-methoxybenzene
• CAS: 27902-71-2
• 化学式: C₁₆H₁₄Cl₂N₂O₂Pt
• 分子量: 532.285
• InChiKey: PLYPPFKMTFLYGM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.87
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  27.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Pt(CNC₆H₄-p-OMe)₂Cl₂ 、 3-亚氨基异吲哚啉酮 以 氯仿 为溶剂， 生成 [PtCl(CNC6H4OMe-4)2(HN=CC6H4CON)]
  参考文献：
  名称：

  3-Iminoisoindolin-1-ones和复杂的异腈之间的偶联作为金属介导的新型钯和铂亚氨基卡宾物种的金属介导途径。

  摘要：

  在异腈之间的反应顺式- [的MC1 2（C≡NR）2 ] [M =钯，R =赛扬1，卜吨 2，C 6 H ^ 3（2,6--ME 2）3 ; M = PT，R =赛扬4，卜吨 5，C 6 H ^ 3（2,6--ME 2）6 ]和各种未取代或取代iminoisoindolin -1-酮HN═CC 6 - [R 1 - [R 2 - [R 3 - [R 4 CONH [R 1 -R 4 = H 7; R 1，R 3，R 4＝ H，R 2＝ Me / R 1，R 2，R 4＝ H，R 3＝ Me 8（异构体混合物）；R 1，R 4＝ H，R 2，R 3＝ Cl 9 ]在回流条件下在CHCl 3中进行2小时。随后的后处理提供了配合物[{的MC1 Ç（N = C（C 6 - [R 1 - [R 2 - [R 3 - [R 4 CO Ñ））= N（H）R}（C≡NR）]（M = PD，10 -18 ;

  DOI：

  10.1021/om800517c
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 4-甲氧基苯异腈 以 二氯甲烷 为溶剂， 以84%的产率得到Pt(CNC₆H₄-p-OMe)₂Cl₂
  参考文献：
  名称：

  Michelin, Rino A.; Zanotto, Livio; Braga, Dario, Inorganic Chemistry, 1988, vol. 27, # 1, p. 85 - 92

  摘要：

  DOI：

文献信息

• Novel ring opening and halogen transfer from platinum(<scp>II</scp>) to phosphorus in the reaction of [PtCl₂(CNR)₂](R = Bu^t,p-MeOC₆H₄) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBu^t)]₂
  作者：Florence A. Ajulu、Peter B. Hitchcock、François Mathey、Rino A. Michelin、John F. Nixon、A. J. L. Pombeiro

  DOI：10.1039/c39930000142

  日期：——

  A new type of ligating behaviour of the phosphirene ring system [graphic omitted]Ph is described, in which novel dimeric platinum(II) Chlorophosphane complexes result from phosphirene ring opening and a Pt–Cl bond-insertion reaction.

  一种新型磷杂环烯系统的环系行为[图形省略]被描述，其中通过磷杂环开环和Pt-Cl键插入反应形成了新颖的双核铂(II)氯膦配合物。
• C,N-chelated diaminocarbene platinum(II) complexes derived from 3,4-diaryl-1H-pyrrol-2,5-diimines and cis-dichlorobis(isonitrile)platinum(II): Synthesis, cytotoxicity, and catalytic activity in hydrosilylation reactions
  作者：Anastasiia M. Afanasenko、Tatiana G. Chulkova、Irina A. Boyarskaya、Regina M. Islamova、Anton A. Legin、Bernhard K. Keppler、Stanislav I. Selivanov、Anatoly N. Vereshchagin、Michail N. Elinson、Matti Haukka

  DOI：10.1016/j.jorganchem.2020.121435

  日期：2020.9

  The reaction of 3,4-diaryl-1H-pyrrol-2,5-diimines with cis-dichlorobis(isonitrile)platinum(II) affords the C,N-chelated diaminocarbene platinum(II) complexes, which have been fully characterized including molecular spectroscopy, single crystal X-ray diffraction and DFT calculations. The obtained platinum(II) complexes are effective catalysts for the hydrosilylation of alkynes and alkenes. Thus, the

  3,4-二芳基-1 H-吡咯-2,5-二亚胺与顺-二氯双（异腈）铂（II）的反应可得到C，N-螯合的二氨基碳烯铂（II）络合物，其特征包括分子光谱，单晶X射线衍射和DFT计算。所得的铂（II）配合物是炔烃和烯烃的氢化硅烷化的有效催化剂。因此，苯乙炔与三乙氧基硅烷的反应导致形成α-和β-（E）-乙烯基硅烷，从而产生的TON范围为10 3至10 4，TOF范围为10 2至10 3 h -1。而且，通过含乙烯基和氢化物的聚硅氧烷的氢化硅烷化反应获得具有发光性能的交联的有机硅。另外，通过体外细胞毒性研究证明了二氨基碳烯铂（II）配合物对抗CH1 / PA-1，SW480和A549癌细胞系的效率。
• Synthesis, chemical and electrochemical deprotonation reactions of aminocarbene complexes of palladium(II) and platinum(II). X-ray structure of {(PPh3)ClPt[μC,N]}2
  作者：Roberta Bertani、Mirto Mozzon、Rino A. Michelin、Franco Benetollo、Gabriella Bombieri、Tania J. Castilho、Armando J.L. Pombeiro

  DOI：10.1016/s0020-1693(00)80186-3

  日期：1991.11

  complexes cis-Cl2(PPh3)Pt[ CN(Bu t )CH 2 CH 2 N H] (1) and cis-Cl2Pt[ CN(C 6 H 4 -p-OMe)CH 2 CH 2 N H]2 (2) have been prepared by reaction of the corresponding isocyanide derivatives with aziridine/ClCH2CH2NH3+Cl− and aziridine alone, respectively. The aminooxycarbene complex cis-Cl2Pt[ CN(C 6 H 4 -p-OMe)CH 2 CH 2 O ]2 (3) has been prepared by reaction of the bis-isocyanide derivative with 2-chloroethanol/n-BuLi

  摘要二氨基卡宾配合物顺式-Cl2（PPh3）Pt [CN（But）CH 2 CH 2 NH]（1）和顺式-Cl2Pt [CN（C 6 H 4 -p-OMe）CH 2 CH 2 NH] 2（ 2）分别通过使相应的异氰化物衍生物与氮丙啶/ ClCH2CH2NH3 + Cl-和氮丙啶反应制备。通过双异氰酸酯衍生物与2-氯乙醇/正丁基锂的反应制备了氨基氧碳烯配合物顺式- [CN（C 6 H 4 -p-OMe）CH 2 CH 2 O] 2（3）。二聚体复合物（PPh3）BrPd [μ-CN（Me）CH 2 CH 2 N，C，N]} 2（4），（PPh3）ClPd [μ-CN（C6H4-p-OMe）CH2CH2NC ，（N]} 2（5），（PPh3）ClPt [μ-CN（C 6 H 4 -p-OMe）CH 2 CH 2NC，N]} 2（6）已通过带有n-BuLi的相应单核衍生物的NH基团。报告了（PPh3）ClPt
• Interplay of Metallophilic Interactions, π–π Stacking, and Ligand Substituent Effects in the Structures and Luminescence Properties of Neutral Pt^II and Pd^II Aryl Isocyanide Complexes
  作者：Ilya M. Sluch、Anthea J. Miranda、Oussama Elbjeirami、Mohammad A. Omary、LeGrande M. Slaughter

  DOI：10.1021/ic301104a

  日期：2012.10.15

  Packing interactions in the crystal structures of a series of cis-M(CNAr)(2)Cl-2 complexes (M = Pt, Pd; Ar = substituted phenyl) were examined and correlated with the luminescence properties of the Pt complexes. The structures of the PhNC and p-tolyl isocyanide complexes exhibit extended chains of metallophilic interactions with M center dot center dot center dot M distances of 3.24-3.25 and 3.34 angstrom, respectively, with nearly isostructural Pt and Pd compounds. Both structure types contain void channels running parallel to the M center dot center dot center dot M chains. The channels are 3-4 angstrom wide and vacant for the phenyl structures, while those in the p-tolyl structures are up to 7.6 angstrom wide and contain water. These channeled structures are stabilized by a combination of metallophilic bonding and aryl pi-pi stacking interactions. The Pt structure with 4-F substituents also features extended Pt center dot center dot center dot Pt chains, but with longer 3.79 angstrom distances alternating with shorter 3.37 angstrom contacts. Structures with 4-CF3 and 4-OMe substituents exhibit mostly isolated dimers of M center dot center dot center dot M contacts. In complexes with 2,6-dimethylphenyl isocyanide, steric hindrance precludes any short M center dot center dot center dot M contacts. The primary effect of aryl substitution is to provide alternative packing motifs, such as CF3 center dot center dot center dot pi and CH3 center dot center dot center dot pi interactions, that either augment or disrupt the combination of metallophilic contacts and pi-pi stacking needed to stabilize extended M center dot center dot center dot M chains. Differences in the Pt and Pd structures containing 4-F and 4-OMe substituents are consistent with a higher driving force for metallophilic interactions for Pt versus Pd. The M-C and M-Cl bond distances indicate a slightly higher trans influence for aryl isocyanides bound to Pt versus Pd. The three extended Pt center dot center dot center dot Pt chain structures display luminescence assignable to (d sigma*-p sigma) excited states, demonstrating the existence of substantial orbital communication along the metal-metal chains. Face-indexing shows that the preferred crystal growth axis is along the metal-metal chains for the luminescent structures. Variable temperature structural studies showed that both M center dot center dot center dot M and pi-pi interactions contract upon cooling. Overall, this study suggests that synergy with pi-pi and other interactions is necessary to stabilize extended M center dot center dot center dot M chain structures. Thus, efforts to design functional materials based on metallophilic bonding must consider the full array of available packing motifs.
• Bertani, Roberta; Mozzon, Mirto; Michelin, Rino A., Inorganic Chemistry, 1988, vol. 27, # 16, p. 2809 - 2815
  作者：Bertani, Roberta、Mozzon, Mirto、Michelin, Rino A.

  DOI：——

  日期：——