1,1,1-tris{[tris(dimethylamino)phosphoranylidene]amino}-3,3-bis(dimethylamino)-3-methylamino-1λ5,3λ5-diphosphazene | 873108-13-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,1,1-tris{[tris(dimethylamino)phosphoranylidene]amino}-3,3-bis(dimethylamino)-3-methylamino-1λ5,3λ5-diphosphazene
• 英文别名: N-[dimethylamino-methylimino-[[tris[[tris(dimethylamino)-lambda5-phosphanylidene]amino]-lambda5-phosphanylidene]amino]-lambda5-phosphanyl]-N-methylmethanamine；N-[dimethylamino-methylimino-[[tris[[tris(dimethylamino)-λ5-phosphanylidene]amino]-λ5-phosphanylidene]amino]-λ5-phosphanyl]-N-methylmethanamine
• CAS: 873108-13-5
• 化学式: C₂₃H₆₉N₁₆P₅
• 分子量: 724.777
• InChiKey: VOFBGYMEBMFBCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  44
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  97.4
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  1,1,1-tris{[tris(dimethylamino)phosphoranylidene]amino}-3,3-bis(dimethylamino)-3-methylamino-1λ5,3λ5-diphosphazene 、 tert-butyl {[4-(chloromethyl)benzyl]oxy}dimethylsilane 在 四丁基氟化铵 、 盐酸 、 乙胺 、 sodium iodide 作用下， 以 1,2,3,4-四氢萘 、 四氢呋喃 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  NOVEL SUPPORTED PHOSPHAZENE CATALYSTS, NOVEL COMPOUNDS FOR THE CATALYSTS, AND USE THEREOF

  摘要：

  公开号：

  EP1775301B1
• 作为产物：
  描述：

  四[三(二甲氨基)正膦亚基氨基]氯化磷 在 Kalium-n-octylmercaptid 作用下， 以 1,2,3,4-四氢萘 为溶剂， 反应 5.0h， 生成 1,1,1-tris{[tris(dimethylamino)phosphoranylidene]amino}-3,3-bis(dimethylamino)-3-methylamino-1λ5,3λ5-diphosphazene
  参考文献：
  名称：

  NOVEL SUPPORTED PHOSPHAZENE CATALYSTS, NOVEL COMPOUNDS FOR THE CATALYSTS, AND USE THEREOF

  摘要：

  公开号：

  EP1775301B1

文献信息

• Novel Phosphazene-Supported Catalyst, Novel Compound Thereof and Use Thereof
  申请人：Yoshimura Naritoshi

  公开号：US20080318767A1

  公开（公告）日：2008-12-25

  A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Z n− , a, b, c, d, R, R 1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
• NOVEL SUPPORTED PHOSPHAZENE CATALYSTS, NOVEL COMPOUNDS FOR THE CATALYSTS, AND USE THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1775301B1

  公开（公告）日：2011-08-10