4-(苯基磺酰基)苯-1,2-二胺 | 54029-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-(苯基磺酰基)苯-1,2-二胺
• 英文名称: 4-benzenesulfonyl-o-phenylenediamine
• 英文别名: 4-Benzolsulfonyl-o-phenylendiamin；4-Phenylsulfon-o-phenylendiamin；Phenyl-(3.4-diamino-phenyl)-sulfon；2-amino-4-benzenesulfonylaniline；4-Phenylsulfonyl-1,2-diaminobenzol；4-Phenylsulfonyl-o-phenylenediamin；4-(Benzenesulfonyl)benzene-1,2-diamine
• CAS: 54029-75-3
• 化学式: C₁₂H₁₂N₂O₂S
• 分子量: 248.305
• InChiKey: RJQHQUNYKXLSFE-UHFFFAOYSA-N

物化性质

• 熔点：
  126 °C
• 沸点：
  505.4±40.0 °C(Predicted)
• 密度：
  1.361±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  94.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(苯基磺酰基)苯-1,2-二胺 以 乙醚 、 氯仿 为溶剂， 生成 methyl N-[N-[2-amino-5-(benzenesulfonyl)phenyl]-C-methylsulfanylcarbonimidoyl]carbamate
  参考文献：
  名称：

  DE2720290

  摘要：

  公开号：
• 作为产物：
  描述：

  (3-氯-4-硝基-苯基)-苯基砜 在 盐酸 、 氨 、 tin(ll) chloride 作用下， 生成 4-(苯基磺酰基)苯-1,2-二胺
  参考文献：
  名称：

  192. 3-氯-4-硝基和5-氯-2-硝基-二苯基砜中基团的迁移性

  摘要：

  DOI：

  10.1039/jr9390000902

文献信息

• Method for the control of cattle grubs employing a phenylene
  申请人：American Cyanamid Company

  公开号：US04137310A1

  公开（公告）日：1979-01-30

  There is provided a method for controlling the larvae of heel flies which parasitize ruminants and other warm-blooded animals by administering to said animals an effective amount of an unsubstituted or substituted phenylene bis[imino(thio)carbonyl]diphosphor(thio)amidic acid ester.

  提供了一种控制寄生在反刍动物和其他温血动物身上的踵蝇幼虫的方法，该方法是向这些动物投与一定量未取代或取代的苯基双[亚硫(硫)羰基]二磷(硫)酰胺酸酯。
• 2-Imino substituted isothioureidobenzene
  申请人：Rohm and Haas Company

  公开号：US04241079A1

  公开（公告）日：1980-12-23

  2-Imino substituted isothioureidobenzene products useful as anthelmintics and fungicides are disclosed. The products may be prepared by several different methods including treating a 2-iminothioureidobenzene with a base and either an organic halide, a diester of sulfuric acid or a diester of sulfurous acid or treating a 2-aminoisothioureidobenzene with an appropriately substituted aldehyde.

  本文披露了作为驱虫剂和杀真菌剂有用的2-亚氨基取代的异硫脲苯产物。可以通过几种不同的方法制备这些产物，包括用碱和有机卤化物、硫酸二酯或亚硫酸二酯处理2-亚氨基硫脲苯，或用适当取代的醛处理2-氨基异硫脲苯。
• 5(6)-Benzene ring substituted benzimidazole-2-carbamate derivatives
  申请人：Syntex (U.S.A.) Inc.

  公开号：US04002640A1

  公开（公告）日：1977-01-11

  Benzene ring substituted benzimidazole-2-carbamate derivatives represented by the formula: ##STR1## where R is a lower alkyl group having 1 to 4 carbon atoms; R.sup.1 is -SOR.sup.2, -SO.sub.2 R.sup.2, -SCN, -SR.sup.5, -OR.sup.5 or M'(CH.sub.2).sub.n MR.sup.7 where M and M' are independently O, S, ##STR2## R.sup.7 is lower alkyl having 1 to 4 carbon atoms, or aryl, and n is 1-4; R.sup.2 is lower alkyl having from 1 to 6 carbon atoms, cycloalkyl having 3 to 7 carbon atoms, lower alkenyl or lower alkynyl having 3 to 6 carbon atoms, or aralkyl or aryl; and R.sup.5 is lower alkenyl, lower alkynyl, or aralkyl. The R.sup.1 substitution is at the 5(6)-position. The compounds are useful as pesticides, particularly as anthelmintic and antifungal agents.

  苯环取代苯并咪唑-2-氨基甲酸酯衍生物的化学式如下：##STR1##其中，R是1到4个碳原子的低碳基；R.sup.1是-SOR.sup.2，-SO.sub.2 R.sup.2，-SCN，-SR.sup.5，-OR.sup.5或M'(CH.sub.2).sub.n MR.sup.7，其中M和M'分别是O，S，##STR2## R.sup.7是具有1到4个碳原子的低碳基或芳基，n为1-4；R.sup.2是具有1到6个碳原子的低碳基，具有3到7个碳原子的环烷基，具有3到6个碳原子的低烯基或低炔基，或芳基烷基或芳基；R.sup.5是低烯基，低炔基或芳基烷基。R.sup.1取代位于5(6)位。该化合物可用作杀虫剂，特别是作为驱虫和抗真菌剂。
• Glycidyl sulfonamide compound
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0339137A2

  公开（公告）日：1989-11-02

  A novel glycidyl sulfonamide compound having a (poly)siloxane main chain of its molecule is used alone or in admixture with an epoxy resin to give a cured material being excellent in flexibility, elongation and impact strength without deteriorating thermal resistance, chemical resistance and water absorption thereof. An epoxy resin composition or a resin composition for an epoxy paint containing a glycidyl sulfonamide compound, the epoxy resin and a curing agent for epoxy resin provides a cured material or a coating film having the above-mentioned excellent properties. A process for preparing a glycidyl sulfonamide compound characterized in that subjecting an amine modified silicone having a (poly)siloxane main chain of its molecule to condensation reaction with a sulfonyl chloride to give a sulfonamide compound, which is subjected to an addition reaction with an epihalohydrin to give the glycidyl sulfonamide compound.

  一种新型缩水甘油基磺酰胺化合物的分子主链为（聚）硅氧烷，单独使用或与环氧树脂混合使用，可得到柔韧性、伸长率和冲击强度极佳的固化材料，而不会降低其耐热性、耐化学性和吸水性。含有缩水甘油磺酰胺化合物、环氧树脂和环氧树脂固化剂的环氧树脂组合物或环氧涂料用树脂组合物可提供具有上述优异性能的固化材料或涂膜。一种制备缩水甘油基磺酰胺化合物的工艺，其特征在于将分子主链为(聚)硅氧烷的胺改性有机硅与磺酰氯进行缩合反应，得到磺酰胺化合物，再与表卤代烃进行加成反应，得到缩水甘油基磺酰胺化合物。
• Polyamic acid and polyimide microfine particles and processes for their production
  申请人：OSAKA PREFECTURAL GOVERNMENT

  公开号：EP0982343A2

  公开（公告）日：2000-03-01

  A process for producing polyimide microfine particles which is amenable to free control of particle morphology and particle diameter distribution is provided. A polyamic acid and a polyimide, each in the form of microfine particles with good monodispersibility, are also provided. There is also provided a process for producing polyimide microfine particles from a tetracarboxylic anhydride and a diamine compound which comprises (a) a first step of preparing a first solution containing the tetracarboxylic anhydride and a second solution containing the diamine compound, (b) a second step of mixing the first and second solutions and causing a polyamic acid to precipitate in the form of microfine particles from the mixed solution under ultrasonic agitation, and (c) a third step of imidating the polyamic acid particles to provide the objection polyimide in the form of microfine particles.

  本发明提供了一种生产聚酰亚胺微细颗粒的工艺，可自由控制颗粒形态和颗粒直径分布。本发明还提供了一种聚酰胺酸和一种聚酰亚胺，它们都是具有良好单分散性的微细颗粒形式。还提供了一种用四羧酸酐和二胺化合物生产聚酰亚胺微细颗粒的工艺，该工艺包括 (a) 第一步，制备含有四羧酸酐的第一溶液和含有二胺化合物的第二溶液、(b) 第二步，将第一和第二溶液混合，并在超声波搅拌下使聚酰胺以微细颗粒的形 式从混合溶液中析出，以及 (c) 第三步，将聚酰胺颗粒酰亚胺化，以微细颗粒的形式提供反对聚酰亚胺。