10-(2-乙基己基)吩噻嗪-3,7-二甲醛 | 403610-12-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 中文名称: 10-(2-乙基己基)吩噻嗪-3,7-二甲醛
• 英文名称: N-(2-ethylhexyl)-3,6-diformylphenothiazine
• 英文别名: 10-(2-Ethylhexyl)-10H-phenothiazine-3,7-dicarbaldehyde；10-(2-ethylhexyl)phenothiazine-3,7-dicarbaldehyde
• CAS: 403610-12-8
• 化学式: C₂₂H₂₅NO₂S
• 分子量: 367.512
• InChiKey: QRJDUVNCYIKAJM-UHFFFAOYSA-N

物化性质

• 沸点：
  550.9±50.0 °C(Predicted)
• 密度：
  1.159±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  10-(2-乙基己基)吩噻嗪-3,7-二甲醛 在 sodium hydroxide 、 三氯氧磷 作用下， 以 乙醇 为溶剂， 反应 16.5h， 生成
  参考文献：
  名称：

  Numbers of cyanovinyl substitutes and their effect on phenothiazine based organic dyes for dye-sensitized solar cells

  摘要：

  苯噻嗪基染料（OMS1-3），包括不同的共轭长度和电子亏损（氰乙烯基）官能团的数量已经合成。OMS3染料在苯噻嗪核心之间有两个氰乙烯基官能团，展现出4.00%的最佳电池性能。

  DOI：

  10.1039/c7ra13751f
• 作为产物：
  描述：

  溴代异辛烷 在 sodium hydroxide 、 三氯氧磷 作用下， 以 二甲基亚砜 、 1,2-二氯乙烷 为溶剂， 生成 10-(2-乙基己基)吩噻嗪-3,7-二甲醛
  参考文献：
  名称：

  Synthesis of Polyazomethine Type Conjugated Polymers as Light Emitting Materials

  摘要：

  Aromatic dialdehyde based on phenothiazine and aromatic diamine were used to synthesize polyazomethine type conjugated polymer, poly(PZ-PI) which had good solubility in common organic solvents. The UV absorption maximum(lambda (max,UV)) and edge(lambda (edg,UV)) of poly(PZ-PI) were observed at 415 and 510 nm, respectively. The threshold voltage of ITO/polymer/Mg and ITO/polymer/Alq3(100 Angstrom)/Mg device was at 10 V and 7 V, respectively. Besides double layer LED with Alq3 exhibited both enhanced emission intensity and efficiency compared to the single layer LED.

  DOI：

  10.1080/10587250108024748

文献信息

• Dye compound for dye-sensitized solar cells, dye-sensitized photoelectric converter and dye-sensitized solar cells
  申请人：Samsung Electro-Mechanics Co., Ltd

  公开号：EP2192159A3

  公开（公告）日：2011-03-09

  A dye compound for solar cells, a dye-sensitized photoelectric converter and dye-sensitized solar cells are provided. The photoelectric conversion efficiency of solar cells is improved by using the dye compound: of which X is at least one aromatic group and symmetric about the X-R1 bond axis or at least hetero aromatic group having at least one hetero atom chosen from N and S and symmetric about the X-R1 bond axis; R1is substituted or unsubstituted C1 to C20 cyclic alkyl or substituted or unsubstituted C1 to C20 linear alkyl; L1 and L2 are substituted or unsubstituted hydrocarbons having 2 to 8 conjugated p-orbitals; Y1 and Y2 are better electron-withdrawing groups than X and may contain at least one acidic hydrogen which is able to form a hydrogen bond.

  提供了一种用于太阳能电池的染料化合物，染料敏化光电转换器和染料敏化太阳能电池。通过使用染料化合物，提高了太阳能电池的光电转换效率：其中X至少是一个芳香族基团，并且关于X-R1键轴对称，或者至少是一个含有至少一个来自N和S的杂原子的杂环芳基团，并且关于X-R1键轴对称；R1被取代或未取代的C1到C20环烷基或取代或未取代的C1到C20直链烷基；L1和L2是取代或未取代的具有2到8个共轭p轨道的碳氢化合物；Y1和Y2比X更好地吸电子基团，并且可能含有至少一个能够形成氢键的酸性氢。
• Electroluminescent Properties of Heterocyclic Conjugated Random Copolymers Containing Phenothiazine and Carbazole Moieties
  作者：Yoon Soo Han、Hoyoung Kim、Hyeon Jin Seo、Younghwan Kwon、Youngjune Hur、Dong-Uk Kim、Jung Moo Kim、Hyun Suk Kim、Lee Soon Park

  DOI：10.1080/15421400600922232

  日期：2006.12

  Electroluminescent properties of polymer light-emitting diode (PLED)s fabricated from heterocyclic conjugated random copolymers, poly(PZV-ran-CZV), containing (N-2-ethylhexyl)-3,6-phenothiazinylene vinylene (PZV), (N-2-ethylhexyl)-3,6-carbazolylene vinylene (CZV) and phenylene vinylene (PV) unit as a light emitting layer were investigated. PLEDs made with corresponding alternating copolymers, poly(PZV-PV) and poly(CZV-PV), as a light emitting layer were also studied and exhibited EL maximum at 570 nm and 500 nm, respectively. Single-layered PLEDs made with poly(PZV-ran-CZV) copolymers, however, showed EL maxima shifted to longer wavelength. Double-layered PLED made with poly(PZV-ran-CZV) copolymer as a light emitting layer and Alq(3) as an electron transporting layer exhibited enhanced EL emission compared to that of single-layered PLED.
• Synthesis and Photolithographic Property of Conjugated Polymers with Polyazomethine Structure
  作者：Sang Chul Ryu、Young Chul Jeong、Lee Soon Park

  DOI：10.1080/15421400903240803

  日期：2009.11.11

  Two different polyazomethine-type conjugated polymers, poly(phenoxiazine-3, 3'-dihydroxybensidine)(PZ-DHB) and poly(phenoxiazine-2,4-diamino-6-hydroxypyrimidine)(PZ-DHP) containing phenothiazine moiety and azomethine linkage in the main chain were synthesized by Schiff-base polycondensation reactions. The polymer poly(PZ-DHB) was converted to the photosensitive type, through Mitsunobu reaction by incorporation of a photocrosslinkable group, hydroxyhexyloxystyryl-2-pyridine(2-HHSP) into the polymer side chains. The photosensitive conjugated polymer, poly(PZ-DHB)-PS, exhibited both strong fluorescence emission at 555 nm and good patterning property in the standard photolithographic processes.
• 10.1080/10587250290088483
  作者：Park, Lee Soon、Ryu, Hyeon Sool、Seo, Hyeon Jin、Kim, Woo Sik、Lee, Dong H.O.、Min, Kyung Eun、Seo, Kwan H.O.、Kang, Inn Kyu

  DOI：10.1080/10587250290088483

  日期：——
• Synthesis of Polyazomethine Type Conjugated Polymers as Light Emitting Materials
  作者：Lee Soon Park、Yoon Soo Han、Sang Dae Kim、Jin Sang Hwang

  DOI：10.1080/10587250108024748

  日期：2001.10

  Aromatic dialdehyde based on phenothiazine and aromatic diamine were used to synthesize polyazomethine type conjugated polymer, poly(PZ-PI) which had good solubility in common organic solvents. The UV absorption maximum(lambda (max,UV)) and edge(lambda (edg,UV)) of poly(PZ-PI) were observed at 415 and 510 nm, respectively. The threshold voltage of ITO/polymer/Mg and ITO/polymer/Alq3(100 Angstrom)/Mg device was at 10 V and 7 V, respectively. Besides double layer LED with Alq3 exhibited both enhanced emission intensity and efficiency compared to the single layer LED.