3-Methyl-2-(p-chlorophenyl)butyl m-bromobenzyl ether

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-Methyl-2-(p-chlorophenyl)butyl m-bromobenzyl ether
• 英文别名: 1-Bromo-3-[[2-(4-chlorophenyl)-3-methylbutoxy]methyl]benzene
• 化学式: C₁₈H₂₀BrClO
• 分子量: 367.713
• InChiKey: MPJQAGLHLGTCPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴苄溴 、 2-(4-Chlorophenyl)-3-methyl-1-butanol 在 氢氧化钾 、 四丁基碘化铵 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以72%的产率得到3-Methyl-2-(p-chlorophenyl)butyl m-bromobenzyl ether
  参考文献：
  名称：

  Synthesis of ethophenprox analogs

  摘要：

  The synthesis of ethophenprox analogs was performed by condensation of alcohols with benzyl halides under conditions of the phase transfer catalysis. The ultrasonic irradiation was shown to accelerate the reaction and to increase the yield of ethers. The trends in fragmentation of new generation pyrethroids under the electron impact were established. Insecticidal activity of the compounds obtained was evaluated.

  DOI：

  10.1007/bf02757439

文献信息

• Synthesis of ethophenprox analogs
  作者：F. Z. Galin、R. G. Rakhimov、E. M. Vyrypaev、M. P. Bogdanov、D. V. Amirkhanov、I. I. Furlei、G. A. Tolstikov

  DOI：10.1007/bf02757439

  日期：2000.6

  The synthesis of ethophenprox analogs was performed by condensation of alcohols with benzyl halides under conditions of the phase transfer catalysis. The ultrasonic irradiation was shown to accelerate the reaction and to increase the yield of ethers. The trends in fragmentation of new generation pyrethroids under the electron impact were established. Insecticidal activity of the compounds obtained was evaluated.