2-phenyl-3-anilino-N-phenylprop-2-enimine | 3920-25-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-phenyl-3-anilino-N-phenylprop-2-enimine
• 英文别名: 3-anilino-2-phenyl-acrylaldehyde phenylimine；3-Anilino-2-phenyl-acrylaldehyd-phenylimin；(3-Anilino-2-phenyl-allyliden)-anilin；Phenylmalonaldehyd-bis-phenylimin；Anilinomethylen-phenylacetaldehyd-anil；Phenylmalondialdehyd-dianil
• CAS: 3920-25-0
• 化学式: C₂₁H₁₈N₂
• 分子量: 298.387
• InChiKey: BOORVYHOLINGKK-MRDIXRINSA-N

物化性质

• 熔点：
  138 °C
• 沸点：
  468.2±45.0 °C(Predicted)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.54
• 重原子数：
  23.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.39
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  盐酸 、 2-phenyl-3-anilino-N-phenylprop-2-enimine 生成 3-anilino-2-phenyl-acrylaldehyde
  参考文献：
  名称：

  Minor- and trace-element zoning in plagioclase: implications for magma chamber processes at Parinacota volcano, northern Chile

  摘要：

  Textural and compositional zoning in plagioclase phenocrysts in a sample from Parinacota volcano (Chile) was investigated using backscattered electron images and electron microprobe analysis of major and trace elements. Large (2 mm) oscillatory zoned crystals (type 1) with resorption surfaces of moderate An discontinuities (less than or equal to 10% An) and decreasing trace-element contents (Sr. Mg, Ti) towards the rim reflect melt differentiation and turbulent convection in the main magma body. Early recharge with a low-Sr mafic magma is seen in the core. Small-scale Sr variations in the core indicate limited diffusion and thus residence and differentiation times of the magma shorter than a few thousand years. Smaller crystals (type II) with low trace-element An ratio reflect the influence of an HO-rich melt probably from a differentiated boundary layer. Closed-system in-situ crystallisation. mafic magma recharge and the role of a water-rich differentiated boundary layer can be distinguished from the An-trace element relationships. Crystals apparently move relatively freely between different parts and regimes in the magma chamber. evidence for "convective crystal dispersion". High-Sr type 11 crystals indicate an earlier input of Sr-rich mafic magma. Recharge of two distinct mafic magma types is thus identified (high-Sr and low-Sr), which must have been present - at increasing recharge rates with time - in the plumbing system throughout the volcano's history.

  DOI：

  10.1007/s00410-002-0351-z
• 作为产物：
  描述：

  β-ethoxystyrene 在 盐酸 、 三氟化硼乙醚 作用下， 生成 2-phenyl-3-anilino-N-phenylprop-2-enimine
  参考文献：
  名称：

  Klimko; Skoldinow, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 4027; engl. Ausg. S. 3987

  摘要：

  DOI：

文献信息

• Method for preparation of an intermediate dye product
  申请人：——

  公开号：US20020022723A1

  公开（公告）日：2002-02-21

  The present invention provides a novel method for the synthesis of an intermediate dye product having the following formula: 1 wherein L is S, Te, or Se; R 1 and R 2 are either the same or different aryl or alkyl compounds; R 3 is hydrogen or a short chain alkyl group; and Z is an anion. The process to formulate this intermediate compound entails reacting an R 1 -acetylene compound with an R 2 -acetylene compound (compounds A) into an enol ether compound with the R 1 and/or R 2 constituents (compound D) And from compound D, it forms into an intermediate dye compound having an L-based cyclic ring with the R 1 and/or R 2 constituents (compound F). With compound F the desired dye can be made with a greater overall yield for mass production.

  本发明提供了一种合成中间染料产物的新方法，其具有以下结构式：其中L为S、Te或Se；R1和R2为相同或不同的芳香族或烷基化合物；R3为氢或短链烷基基团；Z为阴离子。制备这种中间化合物的过程包括将R1-乙炔化合物与R2-乙炔化合物（化合物A）反应成为具有R1和/或R2组分的烯醚化合物（化合物D），然后从化合物D形成具有基于L的环状环的中间染料化合物，其中含有R1和/或R2组分（化合物F）。通过化合物F，可实现所需染料的更高总产量，用于大规模生产。
• Polymeric malondialdehyde dianils—a novel type of electrically conducting polymers
  作者：Rudolf Gompper、Thomas J. J. Müller、Kurt Polborn

  DOI：10.1039/a801654b

  日期：——

  The reaction of vinamidinium salts withpara-substituted aromatic diamines gives rise to polymeric 2-aryl malonaldehyde dianils in good yields. Polymeric cyanines can be obtained from tetramethoxypropane and a pentamethine cyanine, respectively, and para-substituted aromatic diamines. The degree of polymerisation Pn (n=10–40) was estimated by measuring the intrinsic viscosity η. The polymers show high electrical powder conductivities (σ=0.03–50 S cm–1) after doping with iodine or FeCl3 .

  乙脒盐与对位取代的芳香族二胺反应可生成聚合物 2-芳基丙二醛二元胺，产量很高。聚合氰可以分别从四甲氧基丙烷和五甲氧基氰以及对位取代的芳香族二胺中获得。聚合度 Pn（n=10â40）是通过测量固有粘度 δ- 来估算的。在掺入碘或三氯化铁后，聚合物显示出很高的粉末电导率（Ï=0.03â50 S cmâ1）。
• Rupe; Huber, Helvetica Chimica Acta, 1927, vol. 10, p. 848
  作者：Rupe、Huber

  DOI：——

  日期：——
• JAUER E.-A.; FOERSTER E.; HIRSCH B., J. SIGNALAUFZEICHNUNGSMATER., 1975, 3, NO 2, 155-163
  作者：JAUER E.-A.、 FOERSTER E.、 HIRSCH B.

  DOI：——

  日期：——
• US4283475A
  申请人：——

  公开号：US4283475A

  公开（公告）日：1981-08-11