N-(diphenylphosphanylmethyl)-N-[[10-[[diphenylphosphanylmethyl(propyl)amino]methyl]anthracen-9-yl]methyl]propan-1-amine | 666179-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-(diphenylphosphanylmethyl)-N-[[10-[[diphenylphosphanylmethyl(propyl)amino]methyl]anthracen-9-yl]methyl]propan-1-amine
• CAS: 666179-11-9
• 化学式: C₄₈H₅₀N₂P₂
• 分子量: 716.886
• InChiKey: UJWDUVHEQRJQQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  52
• 可旋转键数：
  16
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 N-(diphenylphosphanylmethyl)-N-[[10-[[diphenylphosphanylmethyl(propyl)amino]methyl]anthracen-9-yl]methyl]propan-1-amine 以 not given 为溶剂， 以90%的产率得到copper(1+);N-(diphenylphosphanylmethyl)-N-[[10-[[diphenylphosphanylmethyl(propyl)amino]methyl]anthracen-9-yl]methyl]propan-1-amine;diperchlorate
  参考文献：
  名称：

  Bimetallocyclophanes Formed by the π−π Stacking Interaction Approach and Fluorescent Chemosensing Behavior

  摘要：

  A new high-yielding synthetic approach for the preparation of bimetallic cyclophane has been achieved through the pi-pi stacking interaction approach from the flexible ligand 1 and group 11 metal M+. The Cu complex 2a can act as a fluorescent chemosensor for benzenediacetonitrile.

  DOI：

  10.1021/om0340037

文献信息

• Bimetallocyclophanes Formed by the π−π Stacking Interaction Approach and Fluorescent Chemosensing Behavior
  作者：Feng-Bo Xu、Qing-Shan Li、Xian-Shun Zeng、Xue-Bing Leng、Zheng-Zhi Zhang

  DOI：10.1021/om0340037

  日期：2004.2.1

  A new high-yielding synthetic approach for the preparation of bimetallic cyclophane has been achieved through the pi-pi stacking interaction approach from the flexible ligand 1 and group 11 metal M+. The Cu complex 2a can act as a fluorescent chemosensor for benzenediacetonitrile.