BAPU

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: BAPU
• 英文别名: 1,3-Bis[2-(4-aminophenyl)ethyl]urea
• 化学式: C₁₇H₂₂N₄O
• 分子量: 298.388
• InChiKey: BWTPUFNHSVZIDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  93.2
• 氢给体数：
  4
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  丙二酸环(亚)异丙酯 、 BAPU 、 原甲酸三甲酯 反应 3.0h， 以99%的产率得到1,3-bis(4-((2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methylamino)phenethyl)urea
  参考文献：
  名称：

  TWI588139

  摘要：

  公开号：
• 作为产物：
  描述：

  1,3-bis(4-nitrophenylethyl)urea 在 5%-palladium/activated carbon 、 氢气 作用下， 以 1,4-二氧六环 为溶剂， 以91%的产率得到BAPU
  参考文献：
  名称：

  액정 배향 처리제

  摘要：

  提供了一种液晶取向处理剂，其在液晶取向处理时对阻挡层表面的划痕或磨损较少，液晶的取向性良好，并且液晶单元格的电压保持率高，离子密度低。液晶取向处理剂包含由二胺成分和四羧酸衍生物反应得到的聚酰亚胺树脂或聚酰亚胺的任意一种。上述二胺成分特征在于包含如下式(1)所示的二胺。式(1)中，X是氧原子或硫原子，Y和Y'各自独立地为单键，-O-, -S-, -OCO-, 或-COO-，R和R'各自独立地为碳数为1至3的烷基。

  公开号：

  KR20150138410A

文献信息

• LIQUID CRYSTAL ALIGNING AGENT, LIQUID CRYSTAL ALIGNMENT FILM AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160244673A1

  公开（公告）日：2016-08-25

  To provide a liquid crystal aligning agent to obtain a liquid crystal alignment film which is excellent in the adhesion to a sealing agent and in the liquid crystal alignment property. A liquid crystal aligning agent containing at least one polymer selected from the group consisting of a polyimide precursor having structural units represented by the formula (1) and structural units represented by the formula (3) and an imidized polymer of the polyimide precursor: wherein X 1 and X 4 are a tetravalent organic group, Y 1 is a bivalent organic group having a thermally-leaving group, Y 2 is a bivalent organic group, R 1 and R 2 are a hydrogen atom or a C 1-5 alkyl group, and Z 1 and Z 2 are a hydrogen atom, or a C 1-10 alkyl group, C 2-10 alkenyl group or C 2-10 alkynyl group which may have a substituent.

  提供一种液晶定向剂，以获得具有优异密封剂附着性和液晶定向性的液晶定向膜。所述液晶定向剂包含至少一种聚合物，所述聚合物从以下组中选择：具有由公式（1）和公式（3）表示的结构单元的聚酰亚胺前体和聚酰亚胺前体的缩酐聚合物：其中X1和X4是四价有机基团，Y1是具有热离基的双价有机基团，Y2是双价有机基团，R1和R2是氢原子或C1-5烷基基团，Z1和Z2是氢原子或C1-10烷基基团、C2-10烯基基团或C2-10炔基基团，可以具有取代基。
• LIQUID CRYSTAL ALIGNING AGENT CONTAINING POLYIMIDE PRECURSOR HAVING THERMALLY-LEAVING GROUP AND/OR POLYIMIDE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160264867A1

  公开（公告）日：2016-09-15

  To provide a liquid crystal aligning agent to obtain a liquid crystal alignment film which is excellent in the adhesion to a sealing agent and a substrate of a liquid crystal display device, and of which a decomposed product formed after irradiation with ultraviolet rays will easily be removed. A liquid crystal aligning agent containing at least one polymer selected from the group consisting of a polyimide precursor having a bond represented by the following formula (1) in its main chain and an imidized polymer of the polyimide precursor: wherein each of R 1 , R 2 , R 3 and R 4 which are independent of one another, is a hydrogen atom or a C 1-20 monovalent hydrocarbon group which may have a substituent, and D is a protecting group to be replaced with a hydrogen atom by heat.

  提供一种液晶定向剂，以获得在液晶显示器的密封剂和基板上具有优异附着性的液晶定向膜，并且在紫外线照射后形成的分解产物易于去除。该液晶定向剂包含至少一种聚合物，所述聚合物从以下群组中选择：具有其主链中表示如下式（1）的键的聚酰亚胺前体和聚酰亚胺前体的缩合聚合物：其中，R1、R2、R3和R4各自独立地是氢原子或C1-20个单价烃基，可以具有取代基，D是保护基，可通过热被氢原子取代。
• Liquid crystal aligning agent, liquid crystal alignment film and liquid crystal display device
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US10011772B2

  公开（公告）日：2018-07-03

  To provide a liquid crystal aligning agent to obtain a liquid crystal alignment film which is excellent in the adhesion to a sealing agent and in the liquid crystal alignment property. A liquid crystal aligning agent containing at least one polymer selected from the group consisting of a polyimide precursor having structural units represented by the formula (1) and structural units represented by the formula (3) and an imidized polymer of the polyimide precursor: wherein X1 and X4 are a tetravalent organic group, Y1 is a bivalent organic group having a thermally-leaving group, Y2 is a bivalent organic group, R1 and R2 are a hydrogen atom or a C1-5 alkyl group, and Z1 and Z2 are a hydrogen atom, or a C1-10 alkyl group, C2-10 alkenyl group or C2-10 alkynyl group which may have a substituent.

  提供一种液晶配向剂，以获得一种与密封剂的粘附性和液晶配向性都很好的液晶配向膜。 一种液晶配向剂含有至少一种聚合物，该聚合物选自具有式（1）和式（3）所代表结构单元的聚酰亚胺前体以及聚酰亚胺前体的亚胺化聚合物组成的组： 其中 X1 和 X4 为四价有机基团，Y1 为具有热离去基团的二价有机基团，Y2 为二价有机基团，R1 和 R2 为氢原子或 C1-5 烷基，Z1 和 Z2 为氢原子或可能具有取代基的 C1-10 烷基、C2-10 烯基或 C2-10 烷基。
• JP5790645
  申请人：——

  公开号：——

  公开（公告）日：——
• ARRAY ANTENNA, METHOD FOR PRODUCING SAME, AND LIQUID CRYSTAL ALIGNING AGENT FOR ARRAY ANTENNA
  申请人：JSR CORPORATION

  公开号：US20200286923A1

  公开（公告）日：2020-09-10

  This array antenna 10 comprises a plurality of antenna units 11 . This array antenna 10 is provided with a patch substrate 12 , a slotted substrate 13 and a liquid crystal layer 14 . At least one of the patch substrate 12 and the slotted substrate 13 is provided with a liquid crystal alignment film 22, 23 on the liquid crystal layer 14 side. The liquid crystal alignment film 22, 23 is formed using a polymer composition that contains a compound (M) which has at least one structure selected from the group consisting of partial structures represented by formula (1) and nitrogen-containing heterocyclic rings (in formula (1), R1 represents a hydrogen atom or a monovalent organic group having 1-10 carbon atoms; and each of R2 and R3 independently represents a divalent organic group, provided that the R2 and R3 moieties are not aromatic ring groups at the same time).