Triethyl(prop-2-enyl)ammonium perchlorate | 60198-96-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Triethyl(prop-2-enyl)ammonium perchlorate
• 英文别名: N,N,N-Triaethylallylammonium；triethyl(prop-2-enyl)azanium;perchlorate
• CAS: 60198-96-1
• 化学式: C₉H₂₀N*ClO₄
• 分子量: 241.715
• InChiKey: UPGNPKIIWSGXQI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  乙烯双(三苯基磷)铂 、 Triethyl(prop-2-enyl)ammonium perchlorate 以 四氢呋喃 为溶剂， 以82%的产率得到[Pt(η3-CH2CHCH2)(PPh3)2]ClO4
  参考文献：
  名称：

  通过氧化烯丙基从铵阳离子转移到Platinum（0）底物上，方便地合成具有叔膦的阳离子烯丙基铂（II）配合物。晶体和η的分子结构3 -propenyl-和η 3 -2-甲基丙烯基-双（三苯基膦）铂（II）高氯酸盐

  摘要：

  种类繁多的阳离子η的3 -allylplatinum（II）的类型的配合物[铂（η 3 -CH 2 C（R）C（R'）（R“）（PPH 3）2 ] +（1A - ˚F）是通过从铵阳离子[净氧化烯丙基转移以高收率制备3 CH 2 C（R）C（R'）（R“] +为[铂（η 2 -C 2 H ^ 4）（PPH 3）2 ] 。[NEt 3 CH 2 C（R）C（R'）2 ] +与[Pt（cod）2的相似反应]的产率相关的配合物[铂（η 3 -CH 2 C（R）C（R'）2（COD）] +（2A - Ç。），表明这种合成路线的一个相当普遍可行性1,5-环辛二烯配体络合物的图2a，ç可以很容易地由单-和二齿叔膦移位。阳离子η的溶液行为3 -烯丙基铂（II）配合物，研究了多核NMR光谱学。配合物的固态结构[铂（η 3 -CH 2 CHCH 2）（PPH 3）2 ] +（1A）和[PT（η 3 -CH

  DOI：

  10.1016/s0022-328x(00)00251-5
• 作为产物：
  描述：

  三乙胺 在 3-CH2CH=CH2)(NC5H4(CH=NC6H4OMe-4)-2)>ClO4 、 反丁烯二腈 作用下， 以 氯仿 为溶剂， 生成 Triethyl(prop-2-enyl)ammonium perchlorate
  参考文献：
  名称：

  Equilibrium studies of α-diimine displacement in cationic allylpalladium(II) complexes by monodentate N-donors and the mechanism of allyl amination by triethylamine and pyridine

  摘要：

  In the cationic complexes [Pd(eta3-allyl)(L-L)]ClO4 [L-L = 1,2-bis(imino)ethanes or 2-(iminomethyl)-pyridines] the chelated alpha-diimine was rapidly and reversibly displaced by secondary amines (N-methylaniline, morpholine or piperidine), triethylamine and 4-substituted pyridines. The observed equilibrium constants K(e) increased with increasing basicity and decreasing steric requirements of the entering N-donor. They strongly depend on the alpha-diimine and decrease in the order RN=CHCH=NR much-greater-than RN=C(Me)C(Me)=NR almost-equal-to NC5H4(CH=NR)-2 (R = C6H4OMe-4). The cationic complex [Pd(eta3-C3H5){NC5H4(CH=NC6H4OMe-4)-2}]+ underwent a slow allyl amination by triethylamine or pyridine (L') in the presence of fumaronitrile (fn), yielding [Pd(eta2-fn){NC5H4(CH=NC6H4OMe-4)-2}] and Et3N+CH2CH=CH2 or C5H5N+CH2CH=CH2. Kinetic studies showed that the pseudo-first-order rate constants for amination (k(obs)) are given by k(obs) = k2[L'], suggesting a direct bimolecular attack of L' on the eta3-allyl ligand. Amination hardly proceeds in the presence of the less-activated olefin dimethyl fumarate (dmf). The pi-accepting properties of the olefinic ligands play an important role also in the reaction of Et3N+CH2CH=CH2 or C5H5N+CH2CH=CH2 with [Pd(eta2-olefin){NC5H4(CH=NC6H4OMe-4)-2}] (olefin = fn or dmf), i.e. the reverse of the amination reaction.

  DOI：

  10.1039/dt9940003113

文献信息

• Platinum complexes with unsaturated amines. Part III. The thermodynamics of formation of complexes (CH₂:CH·[CH₂]_n·LR₂R′)⁺PtCl₃^–(L = N, P, and As; n= 1 and 2)
  作者：R. G. Denning、F. R. Hartley、L. M. Venanzi

  DOI：10.1039/j19670000324

  日期：——

  Stability constants and entropies and enthalpies of formation of platinum(II)–olefin complexes of the type (CH2:CH·[CH2]n·LR2R′)+PtCl3–(L = N, P, and As; n= 1 and 2) have been obtained in aqueous solution, by a spectrophotometric method. It is shown that these olefins have affinities for platinum(II) comparable with those of the heavier halide ions. Analysis of the enthalpy and entropy changes indicates

  稳定常数和熵和形成铂（的焓II）的类型的烯烃配合物（CH 2：CH·[CH 2 ] Ñ ·LR 2 R'）+氯铂酸3 -（L = N，P，和As;通过分光光度法在水溶液中获得了n = 1和2）。结果表明，这些烯烃对铂（II）的亲和力可与重卤离子的亲和力相媲美。对焓和熵变化的分析表明，对于形成稳定的铂-烯烃键，烯烃的π-受体容量比其σ-供体容量更为重要。