| 244011-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 244011-93-6
• 化学式: C₅₄H₄₆ClOsP₃
• 分子量: 1013.53
• InChiKey: FVVNHOZIHAMQPO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  10.75
• 重原子数：
  59.0
• 可旋转键数：
  12.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Os: SVol.1, 4.9.4.1.3, page 309 - 310

  摘要：

  DOI：
• 作为产物：
  描述：

  tetrahydridotris(triphenylphosphine)osmium(IV) 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Os: SVol.1, 4.9.4.1.3, page 309 - 310

  摘要：

  DOI：

文献信息

• Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh ₃ ) ₃ (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C ₆ H ₃ ‐2,6‐Trip ₂ )GeCl (Trip = 2,4,6‐ <i>i</i> Pr ₃ C ₆ H ₂ )
  作者：Peng Nie、Qian Yu、Hongping Zhu、Ting‐Bin Wen

  DOI：10.1002/ejic.201700991

  日期：2017.11.2

  The reactions of MXCl(PPh3)3 (M = Ru, Os; X = H, Cl) with (C6H3-2,6-Trip2)GeCl (Trip = 2,4,6-iPr3C6H2) have been investigated. Teatment of MXCl(PPh3)3 with (C6H3-2,6-Trip2)GeCl led to the formation of the dichlorogermyl chloro- or hydrido- ruhenium/osmium complexes (PPh3)XMGeCl2(C6H3-2-η6-Trip}-6-Trip) (M = Ru, X = Cl, 1; M = Os, X = Cl, 2; M = Ru, X = H, 3; M = Os, X = H, 4) via insertion of the germylene

  已经研究了 MXCl(PPh3)3 (M = Ru, Os; X = H, Cl) 与 (C6H3-2,6-Trip2)GeCl (Trip = 2,4,6-iPr3C6H2) 的反应。用 ( -2,6-Trip2)GeCl 处理 MXCl(PPh3)3 导致形成二氯锗基氯-或氢化-钌/锇络合物 (PPh3)XMGeCl2( -2-η6-Trip}-6 -Trip) (M = Ru, X = Cl, 1; M = Os, X = Cl, 2; M = Ru, X = H, 3; M = Os, X = H, 4) 通过将锗烯插入M-Cl 键，然后是三联苯的 Trip 基团之一与 Ru/Os 中心的 6 配位，伴随着 PPh3 配体的解离。值得注意的是，在 OsHCl(PPh3)3 上的反应还导致形成了意想不到的次要产物 Os(H)(PPh2C6H4)GeCl( -2-η6-Trip}-6-Trip)
• Isomerization of CH₃C⋮CPh to Phenylallene Promoted by an Osmium Hydride Complex
  作者：Ting Bin Wen、Zhong Yuan Zhou、Chak-Po Lau、Guochen Jia

  DOI：10.1021/om0004141

  日期：2000.9.1

  Treatment of OsH3Cl(PPh3)3 in benzene with excess CH3C⋮CPh produced cis-CH3CHCHPh and the novel complex OsCl(C(CH3)CHPh)(CH2CCHPh)(PPh3)2, which contains a β-agostic vinyl ligand and a phenylallene ligand. The structure of the latter unusual complex has been confirmed by a single-crystal X-ray diffraction study.

  用过量的CH 3 C⋮CPh处理苯中的OsH 3 Cl（PPh 3）3可产生顺式-CH 3 CH CHPh和新型络合物OsCl（C（CH 3）CHPh）（CH 2 C CHPh）（PPh 3）2，其中包含一个β-声色乙烯基配体和一个苯丙二烯配体。后者异常配合物的结构已通过单晶X射线衍射研究得到证实。
• Oudeman, A.; Rantwijk, F. van; Bekkum, H. van, Journal of Coordination Chemistry, 1974, vol. 4, p. 1 - 7
  作者：Oudeman, A.、Rantwijk, F. van、Bekkum, H. van

  DOI：——

  日期：——
• Synthesis and Structure of New Osmium−PCP Complexes. Osmium-Mediated C−C Bond Activation
  作者：Régis M. Gauvin、Haim Rozenberg、Linda J. W. Shimon、David Milstein

  DOI：10.1021/om000878z

  日期：2001.4.1

  The new complex Os1,3-((Pr2PCH2)-Pr-i)(2)C6H3}(Cl)(PPh3) (2) was obtained from the reaction between the diphosphine 1,3-((Pr2PCH2)-Pr-i)(2)C6H4} (1) and OsCl2(PPh3)(3). 2 reacts with H-2 to yield the dihydrido species Os1,3-((Pr2PCH2)-Pr-i)(2)C6H3}(H)(2)(Cl)(PPh3) (3). Addition of 1 equiv of carbon monoxide to 2 led to the formation of Os1,3-((Pr2PCH2)-Pr-i)(2)C6H3}(CO)(Cl)(PPH3) (4), while in the presence of excess CO, the bis-carbonyl complex Os1,3-((Pr2PCH2)-Pr-i)(2)C6H3}(CO)(2)-(Cl) (5) was formed. Both 2 and 5 were structurally characterized by X-ray diffraction studies. The reaction of OsCl2(PPh3)(3) (under hydrogen pressure) and OsHCl(PPh3)(3) with the diphosphine 1,3,5-(CH3)(3)-2,6-((Pr2PCH2)-Pr-i)(2)C6H} (6) led to the formation of the C-C activation products Os3,5-(CH3)-2,6-((Pr2PCH2)-Pr-i)(2)C6H}(H-2)(Cl) (7) and Os3,5-(CH3)-2,6-(Pr-i(2)-PCH2)(2)C6H}(Cl)(PPh3) (8), respectively.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Os: SVol.1, 4.9.4.2.1, page 310 - 311
  作者：

  DOI：——

  日期：——