3,3’-diallyl-4,4’-bis(allyloxy)biphenyl | 213615-88-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3’-diallyl-4,4’-bis(allyloxy)biphenyl
• 英文别名: 3,3'-diallyl-4,4'-bis(allyloxy)biphenyl；3,3'-diallyl-4,4'-diallyloxy biphenyl；3,3'-diallyl-4,4'-diallyloxy-biphenyl；3,3'-Diallyl-4,4'-diallyloxybiphenyl；1-Prop-2-enoxy-4-(4-prop-2-enoxy-3-prop-2-enylphenyl)-2-prop-2-enylbenzene
• CAS: 213615-88-4
• 化学式: C₂₄H₂₆O₂
• 分子量: 346.469
• InChiKey: QCTRNYMYEADONM-UHFFFAOYSA-N

物化性质

• 熔点：
  82 °C
• 沸点：
  456.5±45.0 °C(predicted)
• 密度：
  0.996±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,3’-diallyl-4,4’-bis(allyloxy)biphenyl 在 potassium carbonate 作用下， 以 邻二氯苯 、 乙腈 为溶剂， 反应 8.0h， 生成 2,2'-(3,3',5,5'-tetraallylbiphenyl-4,4'-diyl)bis(oxy)bis(methylene)dioxirane
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF

  摘要：

  揭示了一种具有烷氧基硅基团的环氧化合物，其复合材料具有良好的耐热性能和/或其固化产物具有良好的阻燃性能，以及其制备方法，包括该化合物的组合物，固化产物和组合物的用途。所述的烷氧基硅化环氧化合物包括至少一种化学式S1取代基和至少两个环氧基团在核心中，通过烯丙基化、克莱森重排、环氧化和烷氧基硅化制备环氧化合物的方法，包括该环氧化合物的环氧组合物，固化产物和组合物的用途。所述的复合材料具有改善的化学键合、良好的耐热性能、低CTE、高玻璃转变温度或Tg-less。该组合物的固化产物具有良好的阻燃性能。

  公开号：

  US20140179836A1
• 作为产物：
  描述：

  4,4'-二羟基联苯 在 potassium carbonate 作用下， 以 邻二氯苯 、 丙酮 为溶剂， 反应 72.0h， 生成 3,3’-diallyl-4,4’-bis(allyloxy)biphenyl
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF

  摘要：

  揭示了一种具有烷氧基硅基团的环氧化合物，其复合材料具有良好的耐热性能和/或其固化产物具有良好的阻燃性能，以及其制备方法，包括该化合物的组合物，固化产物和组合物的用途。所述的烷氧基硅化环氧化合物包括至少一种化学式S1取代基和至少两个环氧基团在核心中，通过烯丙基化、克莱森重排、环氧化和烷氧基硅化制备环氧化合物的方法，包括该环氧化合物的环氧组合物，固化产物和组合物的用途。所述的复合材料具有改善的化学键合、良好的耐热性能、低CTE、高玻璃转变温度或Tg-less。该组合物的固化产物具有良好的阻燃性能。

  公开号：

  US20140179836A1

文献信息

• THERMOSETTING ALKOXYSILYL COMPOUND HAVING TWO OR MORE ALKOXYSILYL GROUPS, COMPOSITION AND CURED PRODUCT COMPRISING SAME, USE THEREOF, AND METHOD FOR PREPARING ALKOXYSILYL COMPOUND
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20180155370A1

  公开（公告）日：2018-06-07

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”)having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及一种热固性烷氧基硅基化合物（以下简称“烷氧基硅基化合物”），其具有两个或两个以上的烷氧基硅基团，在复合材料中表现出优异的耐热特性；包括该烷氧基硅基化合物的组合物和固化产物；其用途；以及制备烷氧基硅基化合物的方法。根据本发明的一种烷氧基硅基化合物的组合物显示出改善的耐热特性，即降低烷氧基硅基化合物组合物的CTE并且不显示玻璃转变温度（以下简称“Tg-less”）的效果。此外，根据本发明的一种烷氧基硅基化合物的固化产物由于烷氧基硅基团表现出优异的阻燃性能。
• COMPOSITION AND CURED ARTICLE COMPRISING INORGANIC PARTICLES AND EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, USE FOR SAME, AND PRODUCTION METHOD FOR EPOXY COMPOUND HAVING ALKOXYSILYL GROUP
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20150148452A1

  公开（公告）日：2015-05-28

  There is provided a composition including an alkoxysilylated epoxy compound, a composition of which exhibits good heat resistance properties, low CTE and high glass transition temperature or Tg-less and not requiring a separate coupling agent, and inorganic particles, a cured product formed of the composition, and a use of the cured product. An epoxy composition including an alkoxysilylated epoxy compound and inorganic particles, an epoxy composition including an epoxy compound, inorganic particles and a curing agent, a cured product of the composition, and a use of the composition are provided. Since chemical bonds may be formed between the alkoxysilyl group and the inorganic particles and between the alkoxysilyl groups, a composition of the composition including the alkoxysilylated epoxy compound and the inorganic particles exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less.

  提供一种包括烷氧硅基化环氧化合物的组合物，该组合物的性质具有良好的耐热性能，低CTE和高玻璃转变温度或Tg-无需单独的偶联剂，并且包括无机颗粒，所述组合物形成的固化产物，以及所述固化产物的用途。提供一种包括烷氧硅基化环氧化合物和无机颗粒的环氧组合物，一种包括环氧化合物、无机颗粒和固化剂的环氧组合物，所述组合物的固化产物，以及所述组合物的用途。由于烷氧硅基团与无机颗粒之间以及烷氧硅基团之间可能形成化学键，因此包括烷氧硅基化环氧化合物和无机颗粒的组合物具有改善的耐热性能、降低的CTE和增加的玻璃转变温度或Tg less。
• Sequential Double Claisen Rearrangement and Two-Directional Ring-Closing Metathesis as a Route to Various Benzofused Bisoxepin and Bisoxocin Derivatives
  作者：Shital Chattopadhyay、Titas Biswas、Susama Maity

  DOI：10.1055/s-2006-950398

  日期：2006.9

  A synthetic strategy based on tandem application of double Claisen rearrangement and two-directional ring-closing metathesis reaction as key-steps has been developed for the synthesis of various hitherto unknown tri-, tetra- and pentacyclic benzofused bisoxepin and bisoxocin derivatives.

  已经开发了一种基于串联应用双克莱森重排和双向闭环复分解反应作为关键步骤的合成策略，用于合成各种迄今为止未知的三环、四环和五环苯并稠合双氧氟沙星和双氧星环衍生物。
• Novel compositions of monomers, oligomers and polymers and methods for making the same
  申请人：Panambur Gangadhar

  公开号：US20060089510A1

  公开（公告）日：2006-04-27

  A novel monomer composition is described. The novel monomer composition includes at least one property imparting unit. The property imparting unit has at least one member selected from the group consisting of conductivity imparting unit, stability imparting unit and any combinations thereof. The novel monomer may further include a delinking agent, which is attached to at least one of said property imparting unit. The delinking agent includes at least one member selected from the group consisting of C—C bond, CH 2 , CH 3 , CF 2 , CF 3 , Si, O, S, functional groups, aromatic residues and any combinations thereof.

  本文描述了一种新型单体组成物。该新型单体组成物包括至少一个赋予性能的单元。该赋予性能的单元具有来自以下组中至少一个成员的单元：导电赋予单元、稳定性赋予单元和任何组合。该新型单体还可以包括一个解离剂，该解离剂附着在至少一个赋予性能的单元上。该解离剂包括来自以下组中至少一个成员的单元：C-C键，CH2，CH3，CF2，CF3，Si，O，S，功能性基团，芳香残基和任何组合。
• Thermosetting alkoxysilyl compound having two or more alkoxysilyl groups, composition and cured product comprising same, use thereof, and method for preparing alkoxysilyl compound
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US10428176B2

  公开（公告）日：2019-10-01

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”) having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及：一种热固性烷氧基硅烷化合物（以下简称 "烷氧基硅烷化合物"），该化合物具有两个或两个以上的烷氧基硅烷基团，在复合材料中显示出优异的耐热特性；一种包含该化合物的组合物和固化产品；其用途；以及一种制备烷氧基硅烷化合物的方法。根据本发明，由新型烷氧基硅基化合物组成的烷氧基硅基化合物组合物在复合材料中显示出更好的耐热特性，即降低烷氧基硅基化合物组合物的 CTE，并且不显示玻璃化转变温度（以下称为 "无 Tg"）。此外，根据本发明，由烷氧基硅烷化合物组成的固化产品因含有烷氧基硅烷基团而具有优异的阻燃性能。