o-substituted monosulfonated triphenylphosphine potassium salt

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-substituted monosulfonated triphenylphosphine potassium salt
• 英文别名: potassium 2-{diphenylphosphino}benzenesulfonate；Potassium;2-diphenylphosphanylbenzenesulfonate；potassium;2-diphenylphosphanylbenzenesulfonate
• 化学式: C₁₈H₁₄O₃PS*K
• 分子量: 380.445
• InChiKey: SISDXPNDIABYMU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  o-substituted monosulfonated triphenylphosphine potassium salt 在 双氧水 作用下， 以 水 为溶剂， 反应 4.0h， 以75%的产率得到Potassium; 2-(diphenyl-phosphinoyl)-benzenesulfonate
  参考文献：
  名称：

  Complexation of monosulfonated triphenylphosphine oxides with β-cyclodextrin: spectroscopic study and consequence on the behaviour of cyclodextrins in aqueous-phase organometallic catalysis

  摘要：

  通过核磁共振、紫外可见光和 ESI 质谱，研究了水溶液中 δ² 环糊精与三苯基氧化膦单磺化异构体之间的相互作用。从 31P 和 1H NMR 数据中获得的滴定和连续变化图表明，形成了 1 ⶠ1 包合物。根据 T-ROESY 实验提出了这些包合物的结构。所有包合物都是焓稳定的，但熵失稳。这些络合物的形成不会降低环糊精在水相有机金属催化中的效率。

  DOI：

  10.1039/b304183m
• 作为产物：
  描述：

  2-（二苯基膦基）苯磺酸 在 potassium hydroxide 作用下， 以 水 为溶剂， 以2.9 g的产率得到o-substituted monosulfonated triphenylphosphine potassium salt
  参考文献：
  名称：

  用于烯烃聚合反应 的非对称磺化膦磺酸盐基Pd（ii）催化剂盐的合成†

  摘要：

  直接磺化 2-（二苯基膦基）苯磺酸被广泛研究。获得的不对称功能化反应产物，与广泛应用有关水水溶性膦配位体中号，米，米-TPPTS和米，米-TPPDS，显示螯合κ 2 - （P，O）-coordination与Pd（II）的金属中心。rac-o，m -TPPDS与钾盐的相转移反应18冠6和络合的Pd（II），得到新颖的阴离子催化剂前体[K（18-冠-6）] 2 [κ 2（P，O）{外消旋-邻，米-TPPDS} PdMeCl]适用于烯烃聚合反应。乙烯用这种基于阴离子膦磺酸盐Pd（II）的预催化剂盐研究了与极性官能化烯烃的均聚和共聚反应。

  DOI：

  10.1039/c1dt10372e

文献信息

• Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism
  作者：Antoine Vacher、Anissa Amar、Franck Camerel、Yann Molard、Camille Latouche、Thierry Roisnel、Vincent Dorcet、Abdou Boucekkine、Huriye Akdas-Kiliç、Mathieu Achard

  DOI：10.1039/c8dt04502j

  日期：——

  of various neutral phosphine containing copper(I) complexes exhibiting phosphorescence and TADF are easily achieved by solvent modification restricting intramolecular rotation or by modifying the L–X phosphine-sulfonate chelate. This concept is not limited to solvents as the addition of metallic salts also led to the formation of original well-defined photoluminescent K2CuLX3 and KCuL2X2 cuprate complexes

  通过限制分子内旋转的溶剂修饰或通过修饰L–X膦磺酸盐螯合物，可以轻松实现对各种具有磷光和TADF的中性磷化氢铜（I）配合物的调节。该概念不限于溶剂，因为添加金属盐还导致形成原始的明确定义的光致发光K 2 CuLX 3和KCuL 2 X 2铜酸盐配合物。
• Thermodynamic insight into the origin of the inclusion of monosulfonated isomers of triphenylphosphine into the β-cyclodextrin cavity
  作者：Michaël Canipelle、Laurent Caron、Caline Christine、Sébastien Tilloy、Eric Monflier

  DOI：10.1016/s0008-6215(01)00308-1

  日期：2002.2

  Formation of inclusion complexes between the P-cyclodextrin and the potassium salt of o-, m-, and p-substituted monosulfonated triphenylphosphine derivatives was investigated in aqueous solution by NMR spectroscopy. Titration and continuous variation plots obtained from P-31 and H-1 NMR data indicate the formation of a 1:1 inclusion complex for the three phosphine isomers. T-ROESY NMR experiments show that in all cases a non-sulfonated aromatic ring was included into the hydrophobic cavity of beta-cyclodextrin from the secondary hydroxyl groups side. The standard enthalpy and entropy of the inclusion process were estimated from the temperature dependence of the association constant. All inclusion complexes were enthalpy stabilized, but highly entropy destabilized. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Alkylphosphonous Acids, Salts and Esters, Methods for the Production Thereof, and Use of the Same
  申请人：Hill Michael

  公开号：US20100190901A1

  公开（公告）日：2010-07-29

  The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(═O)(OX)—H (I) wherein A is C 2 -C 20 alkyl, C 2 -C 20 alkylene, and C 8 -C 20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
• US8293938B2
  申请人：——

  公开号：US8293938B2

  公开（公告）日：2012-10-23
• Synthesis of non-symmetrically sulphonated phosphine sulphonate based Pd(ii) catalyst salts for olefin polymerisation reactions
  作者：Timo M. J. Anselment、Carly E. Anderson、Bernhard Rieger、M. Bele Boeddinghaus、Thomas F. Fässler

  DOI：10.1039/c1dt10372e

  日期：——

  2-(diphenylphosphino)benzenesulphonic acid was extensively studied. The non-symmetrically functionalised reaction products obtained, related to the widely applied water soluble phosphine ligands m,m,m-TPPTS and m,m-TPPDS, display chelating κ2-(P,O)-coordination to Pd(II) metal centres. Phase transfer reaction of rac-o,m-TPPDS as the potassium salt with 18-crown-6 and complexation to Pd(II) gives the novel

  直接磺化 2-（二苯基膦基）苯磺酸被广泛研究。获得的不对称功能化反应产物，与广泛应用有关水水溶性膦配位体中号，米，米-TPPTS和米，米-TPPDS，显示螯合κ 2 - （P，O）-coordination与Pd（II）的金属中心。rac-o，m -TPPDS与钾盐的相转移反应18冠6和络合的Pd（II），得到新颖的阴离子催化剂前体[K（18-冠-6）] 2 [κ 2（P，O）外消旋-邻，米-TPPDS} PdMeCl]适用于烯烃聚合反应。乙烯用这种基于阴离子膦磺酸盐Pd（II）的预催化剂盐研究了与极性官能化烯烃的均聚和共聚反应。