dimethyl 4,4'-(((5-(((4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)methyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzoate | 960070-58-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl 4,4'-(((5-(((4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)methyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzoate
• CAS: 960070-58-0
• 化学式: C₃₇H₃₂O₈
• 分子量: 604.656
• InChiKey: IEJBKFVRFVVAFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.37
• 重原子数：
  45.0
• 可旋转键数：
  12.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  100.52
• 氢给体数：
  1.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  dimethyl 4,4'-(((5-(((4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)methyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzoate 、 1-(溴甲基)-3,5-双[(4-乙烯基苯基)甲氧基]苯 在 18-冠醚-6 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以97%的产率得到Methyl 4-[[3-[[4-[4-[[3,5-bis[(4-ethenylphenyl)methoxy]phenyl]methoxy]phenyl]phenoxy]methyl]-5-[(4-methoxycarbonylphenyl)methoxy]phenoxy]methyl]benzoate
  参考文献：
  名称：

  Catalysis by titanocene-functionalized polymer-supported dendrimers

  摘要：

  A series of variously-functionalized first-, second-, and third-generation dendrimers have been prepared and linked via a biphenyl core to a bis-styryl moiety suitable for use as a crosslinker in polymerization. Attachment of titanocene moieties to the first-generation system and copolymerization with styrene affords polymeric disks that exhibit catalytic properties superior to comparable solution-phase systems in a multicomponent coupling of chlorosilanes with Grignards to give bis-allylic silanes. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.115
• 作为产物：
  描述：

  4,4'-二羟基联苯 、 3,5-bis(4-methoxycarbonylbenzyloxy)benzyl bromide 在 18-冠醚-6 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 以82%的产率得到dimethyl 4,4'-(((5-(((4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)methyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzoate
  参考文献：
  名称：

  Catalysis by titanocene-functionalized polymer-supported dendrimers

  摘要：

  A series of variously-functionalized first-, second-, and third-generation dendrimers have been prepared and linked via a biphenyl core to a bis-styryl moiety suitable for use as a crosslinker in polymerization. Attachment of titanocene moieties to the first-generation system and copolymerization with styrene affords polymeric disks that exhibit catalytic properties superior to comparable solution-phase systems in a multicomponent coupling of chlorosilanes with Grignards to give bis-allylic silanes. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.115