1-苯氧基-2-(3-苯氧基苯基)苯 | 3111-80-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-苯氧基-2-(3-苯氧基苯基)苯
• 英文名称: 2,3'-diphenoxybiphenyl
• 英文别名: 2,3'-Diphenoxy-1,1'-biphenyl；1-phenoxy-2-(3-phenoxyphenyl)benzene
• CAS: 3111-80-6
• 化学式: C₂₄H₁₈O₂
• 分子量: 338.406
• InChiKey: SUMVVGSFUBAVKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909309090

反应信息

• 作为产物：
  描述：

  二苯醚 、 白铁矿 生成 1-苯氧基-2-(3-苯氧基苯基)苯
  参考文献：
  名称：

  SMITH, P. A. S.;MUNAVU, R. M.;GILBERTSON, S. R., TETRAHEDRON LETT., 1984, 25, N 28, 2949-2952

  摘要：

  DOI：

文献信息

• HEAT-RESISTANT LUBRICATING OIL COMPOSITION
  申请人：Tonen Corporation

  公开号：EP0778334A1

  公开（公告）日：1997-06-11

  There are provided a heat resistant lubricating oil composition comprising a lubricating base oil comprising an organic ester or a mixture of an organic ester and a polyphenyl ether or an organopolysiloxane, and incorporated with from 0.05% by weight to 10% by weight, based on the total weight of the lubricating oil composition, of a polyphenyl thioether represented by the following general formula [I]: where R1, R2 and R3 which may be identical or different with each other each represent a hydrogen atom or a hydrocarbon group of 1 to 24 carbon atoms, x, y and z which may be identical or different with each other each represent an integer of 1 to 4 and m represent 0 or an integer of 1 to 3, a heat resistant lubricating oil composition containing, as a lubricating base oil, at least from 10% by weight to 90% by weight of a component selected from the group consisting of an organic ester, and a mixture of an organic ester and a polyphenyl ether or an organopolysiloxane and from 90% by weight to 10% by weight of the polyphenyl thioether represented by the general formula [I] described above, as well as a method of preventing oxidation of a heat resistant lubricating oil composition, further, a process for producing a polyphenyl thioether including a purification treatment for the improvement of the weather resistance of the polyphenyl thioether. The heat resistant lubricating oil composition obtained by the present invention has high heat resistance and oxidation resistance under a high temperature condition and can withstand severe working conditions such as in jet engines or gas turbines.

  提供了一种耐热润滑油组合物，该组合物包含由有机酯或有机酯与聚苯醚或有机聚硅氧烷的混合物组成的润滑基础油，并掺入了以润滑油组合物总重量为基准，按重量计0.05%至10%的由下式通式[I]表示的聚苯硫醚： 其中，R1、R2 和 R3 可相互相同或不同，各自代表氢原子或 1 至 24 个碳原子的烃基；x、y 和 z 可相互相同或不同，各自代表 1 至 4 的整数；m 代表 0 或 1 至 3 的整数； 一种耐热润滑油组合物，作为润滑基础油，至少含有 10%（重量）至 90%（重量）选自有机酯组的组分、和有机酯与聚苯醚或有机聚硅氧烷的混合物，以及由上述通式[I]表示的聚苯硫醚的重量百分比从90%到10%，以及防止耐热润滑油组合物氧化的方法。 本发明获得的耐热润滑油组合物在高温条件下具有很高的耐热性和抗氧化性，可承受喷气发动机或燃气轮机等恶劣的工作条件。
• COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM
  申请人：Asahi Glass Company, Limited

  公开号：EP3109303A1

  公开（公告）日：2016-12-28

  To provide a composition for a heat cycle system having less influence over the ozone layer, having a low global warming potential and having excellent durability, and a heat cycle system. A composition for a heat cycle system comprising a working fluid containing trifluoroethylene and difluoromethane, and a lubricating oil, wherein the interaction distance (Ra1123) between trifluoroethylene and the lubricating oil as determined from the Hansen solubility parameters is shorter than the interaction distance (Ra32) between difluoromethane and the lubricating oil.

  提供一种对臭氧层影响较小、全球升温潜能值较低且具有出色耐久性的热循环系统组合物以及一种热循环系统。 一种用于热力循环系统的组合物，包括含有三氟乙烯和二氟甲烷的工作流体以及润滑油，其中根据汉森溶解度参数确定的三氟乙烯与润滑油之间的相互作用距离（Ra1123）短于二氟甲烷与润滑油之间的相互作用距离（Ra32）。
• Composition for heat cycle system, and heat cycle system
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US10196552B2

  公开（公告）日：2019-02-05

  To provide a composition for a heat cycle system having less influence over the ozone layer, having a low global warming potential and having excellent durability, and a heat cycle system. A composition for a heat cycle system comprising a working fluid containing trifluoroethylene and difluoromethane, and a lubricating oil, wherein the interaction distance (Ra1123) between trifluoroethylene and the lubricating oil as determined from the Hansen solubility parameters is shorter than the interaction distance (Ra32) between difluoromethane and the lubricating oil.

  提供一种对臭氧层影响较小、全球升温潜能值较低且具有出色耐久性的热循环系统组合物以及一种热循环系统。 一种用于热力循环系统的组合物，包括含有三氟乙烯和二氟甲烷的工作流体以及润滑油，其中根据汉森溶解度参数确定的三氟乙烯与润滑油之间的相互作用距离（Ra1123）短于二氟甲烷与润滑油之间的相互作用距离（Ra32）。
• Nucleophilic substitution inO-phenyldibenzofuranium and 10-phenylxanthonium cations
  作者：T. P. Tolstaya、M. S. Bobyleva、A. N. Vanchikov、G. V. Kovalysheva、N. S. Kulikov、D. A. Tsariev

  DOI：10.1007/bf02495215

  日期：1997.4

  Reactions of O-phenyldibenzofuranium tetrafluoroborate with nucleophiles (OH-, NO2-, AcO-) in aqueous media follow the SNAr-mechanism and involve dehydroarenes. In DMSO, this salt smoothly reacts with NO2- and I- with predominant opening of the furan ring. 10-Phenylxanthonium tetrafluoroborate readily arylates the NO2- ion in water (at the N and O atoms), mainly with predominant opening of the central ring, and is completely decomposed even with weak bases (N H2OH, 2,4-dinitrophenylhydrazine). The Baeyer-Villiger oxidation of this salt affords xanthone and 2-phenoxybenzoic acid.
• The reaction of pyrite with diphenyl ether
  作者：Peter A.S. Smith、Raphael M. Munavu、Scott R. Gilbertson

  DOI：10.1016/s0040-4039(01)81334-4

  日期：1984.1