N-hydroxy-α-oxo-N'-(pyridin-2-ylmethyl)[1,1'-biphenyl]-4-ethanimidamide | 906813-19-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-hydroxy-α-oxo-N'-(pyridin-2-ylmethyl)[1,1'-biphenyl]-4-ethanimidamide
• 英文别名: 4-[2-(aminomethyl)pyridylisonitrosoacetyl]biphenyl；N-hydroxy-2-oxo-2-(4-phenylphenyl)-N'-(pyridin-2-ylmethyl)ethanimidamide
• CAS: 906813-19-2
• 化学式: C₂₀H₁₇N₃O₂
• 分子量: 331.374
• InChiKey: SAQUZGXZCAGPLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-hydroxy-α-oxo-N'-(pyridin-2-ylmethyl)[1,1'-biphenyl]-4-ethanimidamide 、 lead(II) acetate trihydrate 以 乙醇 为溶剂， 以61%的产率得到bis[4-(2-(aminomethyl)pyridylisonitrosoacetyl)biphenyl(-1H)]Pb(II)
  参考文献：
  名称：

  Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)biphenyls and their complexes

  摘要：

  Three new substituted 4-(alkylaminoisonitrosoacetyl)biphenyls (ligands) derived from 4-biphenylhydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for ligands: ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl)pyridine. Mononuclear or binuclear cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), and lead(II) complexes with these ligands were synthesized. These compounds were characterized by elemental analyses, AAS, infrared spectra, and magnetic susceptibility measurements. The ligands were additionally characterized by H-1 NMR. The results suggest that the ligands act as tridentate ligands.

  DOI：

  10.1134/s1070328406020059

文献信息

• Cyano-Bridged ‘Oximato’ Complexes: Synthesis, Structure, and Catalase-Like Activities
  作者：Fatma Karipcin、Burcin Culu、Saroj K. Sharma、Kushal Qanungo

  DOI：10.1002/hlca.201100314

  日期：2012.4

  thermal analysis. The four [ML(CN)(H2O)n]+ moieties are connected by a metal(II) ion in the pentanuclear complexe 3–6, each one involving four cyano bridging ligands (Fig. 4). The central metal ion displays a square‐planar or octahedral geometry, with the cyano bridging ligands forming the equatorial plane. The axial positions are occupied by two aqua ligands in the case of the central Mn‐atom. The two [ML(CN)(H2O)n]+

  'oximato'-配体前体A（图1）和金属盐与KCN的反应生成了两个单核络合物[ML（CN）（H 2 O）n ]（ClO 4）（1和2； L = N -（羟基-κO）-α-氧代-N' -[（吡啶-2-基-κN）甲基[1,1'-联苯] -4-乙亚胺达咪多-κN' }; M = Co II（1），的Cu II（2）; ñ = 2钴II，ñ = 0的Cu II ;无花果 2和3）。新的氰基桥五核'oximato'络合物[ML（H 2 O）n（NC）} 4 M 1（H 2 O）x ]（ClO 4）2（3 – 6）和三核络合物[ML（ H 2 O）n（NC）} 2 M 1 L]（ClO 4）（7 – 10）（[M 1 = Mn II，Cu II ; x = 2表示Mn II，x = 0表示CuII ]是从单核络合物合成的，并通过元素分析，磁化率，摩尔电导以及IR和热分析进行了表征。四[ML（CN）（H