6H-dibenz[c,e][1,2]oxaphosphorin-6-(2-methylpropanoic acid butyl ester) 6-oxide

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 6H-dibenz[c,e][1,2]oxaphosphorin-6-(2-methylpropanoic acid butyl ester) 6-oxide
• 英文别名: Methyl 2-methyl-3-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)propanoate；methyl 2-methyl-3-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)propanoate
• 化学式: C₁₇H₁₇O₄P
• 分子量: 316.293
• InChiKey: KZAKVGVLKDSRCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸甲酯 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 反应 1.0h， 以81%的产率得到6H-dibenz[c,e][1,2]oxaphosphorin-6-(2-methylpropanoic acid butyl ester) 6-oxide
  参考文献：
  名称：

  Microwave-Assisted Regioselective Addition of P(O)−H Bonds to Alkenes without Added Solvent or Catalyst

  摘要：

  The addition of P(O)-H bonds to alkenes has been accomplished using microwave irradiation in the absence of added solvent and catalyst. In addition to single addition reactions, tandem hydrophosphinylation reactions with alkynes afforded unsymmetrical species such as phosphine oxide - phosphinates.

  DOI：

  10.1021/ol0474047

文献信息

• [EN] FLAME RETARDANTS, PREPARATION METHODS, AND THERMOPLASTIC COMPOSITIONS THEREOF<br/>[FR] AGENTS IGNIFUGEANTS, LEURS PROCÉDÉS DE PRÉPARATION ET COMPOSITIONS THERMOPLASTIQUES ASSOCIÉES
  申请人：DUPONT CHINA RES & DEV AND MAN CO LTD

  公开号：WO2015180165A1

  公开（公告）日：2015-12-03

  Disclosed are flame retardants comprising compounds of Formula (1), wherein the polyol is a disaccharide or a C12 sugar alcohol, which has at least one glucose or one fructose unit per molecule, R1is H or CH3;R2is H or CH3;mis an integer ranging from 6 to 9; and n is an integer ranging from 2 to 9. Also disclosed are methods for producing the inventive flame retardants, thermoplastic compositions and articles comprising the same, and methods for improving flame retardancy of thermoplastic polymers using the same.

  揭示了包括式（1）化合物的阻燃剂，其中多元醇是二糖或C12糖醇，每个分子至少含有一个葡萄糖或一个果糖单位，R1为H或CH3；R2为H或CH3；m为6至9的整数；n为2至9的整数。还公开了制备新型阻燃剂的方法，含有该阻燃剂的热塑性组合物和制品，以及利用该阻燃剂改善热塑性聚合物的阻燃性的方法。
• FLAME RETARDANTS, PREPARATION METHODS, AND THERMOPLASTIC COMPOSITIONS THEREOF
  申请人：E. I. DU PONT DE NEMOURS AND COMPANY

  公开号：US20170204130A1

  公开（公告）日：2017-07-20

  Disclosed are flame retardants comprising compounds of Formula 1, wherein the polyol is a disaccharide or a C 12 sugar alcohol, which has at least one glucose or one fructose unit per molecule, R 1 is H or CH 3 ; R 2 is H or CH 3 ; m is an integer ranging from 6 to 9; and n is an integer ranging from 2 to 9. Also disclosed are methods for producing the inventive flame retardants, thermoplastic compositions and articles comprising the same, and methods for improving flame retardancy of thermoplastic polymers using the same.
• Microwave-Assisted Regioselective Addition of P(O)−H Bonds to Alkenes without Added Solvent or Catalyst
  作者：Robert A. Stockland,、Ross I. Taylor、Laura E. Thompson、Priti B. Patel

  DOI：10.1021/ol0474047

  日期：2005.3.1

  The addition of P(O)-H bonds to alkenes has been accomplished using microwave irradiation in the absence of added solvent and catalyst. In addition to single addition reactions, tandem hydrophosphinylation reactions with alkynes afforded unsymmetrical species such as phosphine oxide - phosphinates.