[Au(mesityl)(AsPh3)] | 159123-24-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Au(mesityl)(AsPh3)]
• 英文别名: [Au(2,4,6-Me3C6H2)(AsPh3)]；[Au(Mes)(AsPh3)]
• CAS: 159123-24-7
• 化学式: C₂₇H₂₆AsAu
• 分子量: 622.392
• InChiKey: WRKCGKDPEVDDRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Au(mesityl)(AsPh3)] 在 PPh₃ 作用下， 以 二氯甲烷 为溶剂， 生成 [(Ph3P)Au(μ-mesityl)Ag(PPh3)]SO3CF3
  参考文献：
  名称：

  Mesitylgold complexes: synthesis and reactivity; crystal structure of [{(Ph₃P)Au(µ-mes)Ag(tht)}₂][SO₃CF₃]₂(mes = mesityl, tht = tetrahydrothiophene)

  摘要：

  The complex [AuCl(AsPh3)] reacted with MgBr(mes) (mes - mesityl) to give the corresponding gold(I) derivative [Au(mes)(AsPh3)], which undergoes substitution reactions with neutral ligands to give the neutral complexes [Au(mes)L] (L = Ph2PCH2PPh2, PPh3 or PPh2Me) or with QX to afford anionic complexes Q[Au (mes) X] [X = Cl, Q = P(CHPh) Ph3; X = Br, Q = N (PPh3)2]. The latter reacted with X, (X = Cl or Br) to give gold(III) complexes, Q[Au(mes)X3] [X = Cl, Q = P(CH2Ph)Ph3; X = Br, Q = N(PPh3)2]. The reaction of [Au(mes)(PPh3)] with [Ag(OSO2CF3)L] [L = PPh3 or tetrahydrothiophene (tht)] afforded [{(Ph3P)Au(mu-mes)AgL)n][SO3CF3]n (L = PPh3, n = 1; L = tht, n = 2). The structure of [{(Ph3P)Au(P-mes)Ag(tht))2][SO3CF3]2 has been determined by a single-crystal X-ray diffraction study, which shows an Au-Ag distance of 2.8245(6) angstrom.

  DOI：

  10.1039/dt9940002515
• 作为产物：
  描述：

  (2,4,6-trimethylphenyl)(triphenylphosphanyl)gold 以 四氢呋喃 、 氘代乙腈 为溶剂， 生成 [Au(mesityl)(AsPh3)]
  参考文献：
  名称：

  涉及大基团的斯蒂勒偶联法与金助催化剂可行

  摘要：

  穿梭金币：不会（或非常缓慢地）与锡烷和廉价配体进行Stille偶联的庞大基团，可以使用双金属催化有效地偶联。通过减少过渡态的空间拥挤，金助催化剂可以有效地将庞大的基团从锡转移到钯（请参见方案）。

  DOI：

  10.1002/anie.201209262

文献信息

• Tetrathiafulvalene-functionalized phosphine as a coordinating ligand. X-Ray structures of (PPh2)4TTF and [(AuCl)4{(PPh2)4TTF}]
  作者：Elena Cerrada、Carmelo Diaz、M. Cristina Diaz、Michael B. Hursthouse、Mariano Laguna、Mark E. Light

  DOI：10.1039/b106310n

  日期：2002.3.8

  The phosphine (PPh2)4TTF (P4) (1) reacts with the gold(I) complexes [AuX(tht)] (X = Cl, C6F5; tht = tetrahydrothiophene) or [Au(Mes)(AsPh3)] (Mes = 2,4,6-Me3C6H2) to give tetranuclear derivatives [(AuX)4P4] (X = Cl, 2; C6F5, 3; Mes, 4). The analogous reaction starting with [Au(Trip)(AsPh3)] (Trip = 2,4,6-Pri3C6H2) provides the dinuclear derivative [(AuTrip)2P4] (5). When the phosphine P4 reacts with [Cu(MeCN)4]PF6, AgCF3SO3 or [Au(tht)2]CF3SO3 in a 2∶1 molar ratio, complexes [M(P4)2]A (A = PF6, M = Cu, 6; A = CF3SO3, M = Ag, 7, Au, 8) are obtained, or [M2P4](CF3SO3)2}n (M = Ag, 9; Au, 10) when 1∶1 molar ratios are used instead. Visible-ultraviolet and electrochemical studies of the new complexes are reported. Two, reversible one-electron oxidations to the mono- and di-cation occur in complexes 2–10 at more positive potentials than the two reversible oxidations exhibited by the free P4 (1) ligand. The structures of 1 and 2 have been confirmed by X-ray analysis.

  膦 (PPh2)4TTF (P4) (1) 与金（I）配合物 [AuX(tht)] （X = Cl、C6F5；tht = 四氢噻吩）或 [Au(Mes)(AsPh3)] （Mes = 2,4,6-Me3C6H2）反应，得到四核衍生物 [(AuX)4P4]（X = Cl，2； ，3；Mes，4）。以[Au(Trip)(AsPh3)]（Trip = 2,4,6-Pri3C6H2）为起点的类似反应可得到二核衍生物[(AuTrip)2P4] (5)。当膦类化合物 P4 与 [Cu(MeCN)4]PF6、AgCF3SO3 或 [Au(tht)2]CF3SO3 以 2∶1 的摩尔比反应时，络合物 [M(P4)2]A （A = PF6，M = Cu，6；A＝CF3SO3，M＝Ag，7，Au，8），或者使用 1∶1 摩尔比时得到[M2P4](CF3SO3)2}n（M＝Ag，9；Au，10）。报告了对这些新络合物的可见紫外光和电化学研究。与游离 P4 (1) 配体的两种可逆氧化作用相比，络合物 2-10 在更正的电位下会发生两种单电子氧化作用，生成单阳离子和双阳离子。X 射线分析证实了 1 和 2 的结构。
• Trinuclear Au₂Ag and Au₂Cu Complexes with Mesityl Bridging Ligands. X-ray Structure of the Chain Polymer [{Au(μ-mes)AsPh₃}₂Ag](ClO₄)
  作者：María Contel、Julián Garrido、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna

  DOI：10.1021/om9602062

  日期：1996.11.12

  The reaction of the complex [Au(mes)L] (mes = mesityl, L = PPh(3), AsPh(3)) with Ag(OSO2CF3), Ag(OClO3), or [Cu(CNMe)(4)]PF6, in molar ratio 2:1, affords trinuclear derivatives [Au-mu-mes)L}(2)M]A [M = Ag, L = PPh(3), A = SO3CF3- (1); L = AsPh(3), A = ClO4- (2a), SO3CF3-(2b); M = Cu, A = PF6- L = PPh(3) (3), AsPh(3) (4)]. Complexes 1 and 2 react further with various ligands in a 1:1 molar ratio to give the dinuclear compounds [AuAg(mu-mes)(PPh(3))L]SO3CF3 (L = PPh(3), tetrahydrothiophene, 2,2'-bipyridine, or SPPh(3)) or [AuAg(mu-mes)(AsPh(3))L]A (L = AsPh(3), A = SO3CF3-; L = 1/2 Ph(2)AsCH(2)AsPh(2), A = ClO4-). The structure of [Au(mu-mes)AsPh(3)}Ag-2](ClO4) (2a) has been determined by a single-crystal X-ray diffraction study, which shows an Au-Ag distance of 2.7758(8) Angstrom; the trinuclear species are connected by short Au Au contacts of 3.132 Angstrom to form a chain polymer.