N-(4-甲氧基苯基)-1-(3-苯氧基苯基)甲亚胺 | 285561-79-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-(4-甲氧基苯基)-1-(3-苯氧基苯基)甲亚胺
• 英文名称: (E)-N-(4-Methoxyphenyl)-1-(3-phenoxyphenyl)methanimine
• 英文别名: N-(4-methoxyphenyl)-1-(3-phenoxyphenyl)methanimine
• CAS: 285561-79-7
• 化学式: C₂₀H₁₇NO₂
• 分子量: 303.36
• InChiKey: IISUXYKWFYYFDX-UHFFFAOYSA-N

物化性质

• 沸点：
  464.7±30.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  30.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(4-甲氧基苯基)-1-(3-苯氧基苯基)甲亚胺 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以92%的产率得到N-p-methoxyphenyl-m-phenoxybenzylamine
  参考文献：
  名称：

  Synthesis and Reactions of Azomethines Containing a m-Phenoxyphenyl Group: II. Chemical Transformations >of N-Aryl-m-phenoxyphenylmethanimines and Arylhydrazones of m-Phenoxybenzaldehyde

  摘要：

  Chemical transformations of N-aryl-m-phenoxyphenylmethanimines and m-phenoxybenzaidehyde arythydrazones were studied by examples of reduction thereof with complex metal hydrides and reactions with dialkyl phosphates and dialkyl phosphites.

  DOI：

  10.1023/b:rujo.0000043714.74375.30
• 作为产物：
  描述：

  甲氧苯胺 、 间苯氧基苯甲醛 反应 2.0h， 以67%的产率得到N-(4-甲氧基苯基)-1-(3-苯氧基苯基)甲亚胺
  参考文献：
  名称：

  含间苯氧基苯基的席夫碱的合成与反应：I. N-芳基-间苯氧基苄叉亚胺和N-芳基-N'-（间苯氧基苄叉基）肼

  摘要：

  Condensation of m-phenoxybenzaldehyde with aromatic amines and hydrazines gave the corresponding Schiff bases and m-phenoxybenzaldehyde arylhydrazones. The products are promising as biologically active substances, polyfunctional additives to rubber compounds, and inhibitors of acid corrosion.

  DOI：

  10.1023/a:1012443600020

文献信息

• Synthesis and Reactions of Azomethines Containing a m-Phenoxyphenyl Group: II. Chemical Transformations >of N-Aryl-m-phenoxyphenylmethanimines and Arylhydrazones of m-Phenoxybenzaldehyde
  作者：Yu. V. Popov、T. K. Korchagina、G. V. Chicherina、T. A. Ermakova

  DOI：10.1023/b:rujo.0000043714.74375.30

  日期：2004.5

  Chemical transformations of N-aryl-m-phenoxyphenylmethanimines and m-phenoxybenzaidehyde arythydrazones were studied by examples of reduction thereof with complex metal hydrides and reactions with dialkyl phosphates and dialkyl phosphites.
• ——
  作者：Yu. V. Popov、T. K. Korchagina、G. V. Chicherina

  DOI：10.1023/a:1012443600020

  日期：——

  Condensation of m-phenoxybenzaldehyde with aromatic amines and hydrazines gave the corresponding Schiff bases and m-phenoxybenzaldehyde arylhydrazones. The products are promising as biologically active substances, polyfunctional additives to rubber compounds, and inhibitors of acid corrosion.