1-methyl-3-(2',4'-dinitrophenyl)triazene 1-oxide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-methyl-3-(2',4'-dinitrophenyl)triazene 1-oxide
• 英文别名: 1-Methyl-3-(2',4'-dinitrophenyl)triazene 1-oxide；[(2,4-dinitrophenyl)hydrazinylidene]-methyl-oxidoazanium
• 化学式: C₇H₇N₅O₅
• 分子量: 241.163
• InChiKey: DPMMLVDZBODOJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  145
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1-methyl-3-(2',4'-dinitrophenyl)triazene 1-oxide 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 反应 1.5h， 以90%的产率得到N-methyl-O-(2,4-dinitrophenyl)hydroxylamine
  参考文献：
  名称：

  Formation of O,N-disubstituted hydroxylamines and ketoxime esters in reactions between triazene 1-oxides and bases

  摘要：

  A new method has been put forward for the synthesis of O,N-disubstituted hydroxylamines and ketoxime esters that is based on the reaction of triazene 1-oxides containing strong electron-withdrawing substituents with bases.

  DOI：

  10.1007/bf00863828
• 作为产物：
  描述：

  N-甲基羟胺 、 2,4-dinitrobenzene-1-diazonium tertafluoroborate 在 sodium acetate 、 溶剂黄146 作用下， 反应 0.5h， 以96%的产率得到1-methyl-3-(2',4'-dinitrophenyl)triazene 1-oxide
  参考文献：
  名称：

  Formation of O,N-disubstituted hydroxylamines and ketoxime esters in reactions between triazene 1-oxides and bases

  摘要：

  A new method has been put forward for the synthesis of O,N-disubstituted hydroxylamines and ketoxime esters that is based on the reaction of triazene 1-oxides containing strong electron-withdrawing substituents with bases.

  DOI：

  10.1007/bf00863828

文献信息

• Formation of O,N-disubstituted hydroxylamines and ketoxime esters in reactions between triazene 1-oxides and bases
  作者：S. G. Zlotin、O. V. Prokshits、Yu. A. Strelenko、O. A. Luk'yanov

  DOI：10.1007/bf00863828

  日期：1992.10

  A new method has been put forward for the synthesis of O,N-disubstituted hydroxylamines and ketoxime esters that is based on the reaction of triazene 1-oxides containing strong electron-withdrawing substituents with bases.