2,2-diphenyl-5,5-di(hydroxymethyl)-1,3,2,5-dioxaborataphosphoniarinane | 129402-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-diphenyl-5,5-di(hydroxymethyl)-1,3,2,5-dioxaborataphosphoniarinane
• 英文别名: [5-(Hydroxymethyl)-2,2-diphenyl-1,3-dioxa-5-phosphonia-2-boranuidacyclohex-5-yl]methanol
• CAS: 129402-50-2
• 化学式: C₁₆H₂₀BO₄P
• 分子量: 318.117
• InChiKey: KKKORUDXQYCTSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.12
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,2-diphenyl-5,5-di(hydroxymethyl)-1,3,2,5-dioxaborataphosphoniarinane 、 2-甲基丙氧基(二苯基)硼烷 在 三乙胺 作用下， 以 丙酮 为溶剂， 以83%的产率得到triethylammonium 5,5'-spirobi(2,2-diphenyl-1,3,2,5-dioxaborataphosphoniarinane)
  参考文献：
  名称：

  Tautomerism in 1,3,2,5-dioxaborataphosphorinanes and their analogs

  摘要：

  In solutions ammonium 2,2,5-triphenyl-4,6-di-R-1,3,2,5-dioxaborataphosphorinanes are characterized by ion-complex tautomerism. The complex form dissociates reversibly to a secondary phosphine and an aldehyde. The reaction of tris(hydroxymethyl)phosphine with isobutyl diphenylborate in the presence of formaldehyde and a tertiary amine gave 5,5'-spirobi(2,2-diphenyl-1,3,2,5-dioxaborataphosphorinanes).

  DOI：

  10.1007/bf00961705
• 作为产物：
  描述：

  三(羟基甲基)磷化氢 、 2-甲基丙氧基(二苯基)硼烷 以 丙酮 为溶剂， 以44%的产率得到2,2-diphenyl-5,5-di(hydroxymethyl)-1,3,2,5-dioxaborataphosphoniarinane
  参考文献：
  名称：

  Tautomerism in 1,3,2,5-dioxaborataphosphorinanes and their analogs

  摘要：

  In solutions ammonium 2,2,5-triphenyl-4,6-di-R-1,3,2,5-dioxaborataphosphorinanes are characterized by ion-complex tautomerism. The complex form dissociates reversibly to a secondary phosphine and an aldehyde. The reaction of tris(hydroxymethyl)phosphine with isobutyl diphenylborate in the presence of formaldehyde and a tertiary amine gave 5,5'-spirobi(2,2-diphenyl-1,3,2,5-dioxaborataphosphorinanes).

  DOI：

  10.1007/bf00961705

文献信息

• NIKONOV, G. N.;KARASIK, A. A., IZV. AN CCCP. CEP. XIM.,(1990) N, S. 1133-1139
  作者：NIKONOV, G. N.、KARASIK, A. A.

  DOI：——

  日期：——
• Tautomerism in 1,3,2,5-dioxaborataphosphorinanes and their analogs
  作者：G. N. Nikonov、A. A. Karasik

  DOI：10.1007/bf00961705

  日期：1990.5

  In solutions ammonium 2,2,5-triphenyl-4,6-di-R-1,3,2,5-dioxaborataphosphorinanes are characterized by ion-complex tautomerism. The complex form dissociates reversibly to a secondary phosphine and an aldehyde. The reaction of tris(hydroxymethyl)phosphine with isobutyl diphenylborate in the presence of formaldehyde and a tertiary amine gave 5,5'-spirobi(2,2-diphenyl-1,3,2,5-dioxaborataphosphorinanes).