Triphenyl(phenylsulfanylmethyl)germane | 153360-70-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Triphenyl(phenylsulfanylmethyl)germane
• CAS: 153360-70-4
• 化学式: C₂₅H₂₂GeS
• 分子量: 427.106
• InChiKey: COTQOKITUCGXKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.49
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Triphenyl(phenylsulfanylmethyl)germane 在 Br₂ 作用下， 以 甲醇 、 乙醚 、 二氯甲烷 、 水 为溶剂， 生成 [(Benzenesulfonyl)methyl](triphenyl)germane
  参考文献：
  名称：

  Alkyl- and aryl-sulphinylmethylgermanium compounds Ph3GeCH2S(O)R: structure of Ph3GeCH2S(O)C6H4tBu-p

  摘要：

  Triphenyl[(organosulphinyl)methyl]germanium compounds [Ph(3)GeCH(2)S(O)R: 1 R = Me, C(6)H(4)X-p, X = H, Me or (t)Bu] have been prepared by oxidation of the corresponding sulphido compounds, Ph(3)GeCH(2)SR, with m-chloroperbenzoic acid. Further oxidation of 1 by m-ClC6H4CO3H produces the corresponding sulphones, Ph(3)GeCH(2)S(O)(2)R. Compounds (1 R = Me or C(6)H(4)(t)Bu-p) are extensively decomposed on heating to 170 degrees C. A crystal structure determination of (1 R = C(6)H(4)(t)Bu) indicated it to be a molecular species with a tetrahedral geometry at germanium. The S-O bond is twisted out of the plane of the attached aryl ring by 7.0(3)degrees.

  DOI：

  10.1016/0022-328x(96)06140-2
• 作为产物：
  描述：

  氯甲基苯硫醚 、 三苯基溴化锗 在 Li 作用下， 以 四氢呋喃 为溶剂， 以47%的产率得到Triphenyl(phenylsulfanylmethyl)germane
  参考文献：
  名称：

  Alkyl- and aryl-sulphinylmethylgermanium compounds Ph3GeCH2S(O)R: structure of Ph3GeCH2S(O)C6H4tBu-p

  摘要：

  Triphenyl[(organosulphinyl)methyl]germanium compounds [Ph(3)GeCH(2)S(O)R: 1 R = Me, C(6)H(4)X-p, X = H, Me or (t)Bu] have been prepared by oxidation of the corresponding sulphido compounds, Ph(3)GeCH(2)SR, with m-chloroperbenzoic acid. Further oxidation of 1 by m-ClC6H4CO3H produces the corresponding sulphones, Ph(3)GeCH(2)S(O)(2)R. Compounds (1 R = Me or C(6)H(4)(t)Bu-p) are extensively decomposed on heating to 170 degrees C. A crystal structure determination of (1 R = C(6)H(4)(t)Bu) indicated it to be a molecular species with a tetrahedral geometry at germanium. The S-O bond is twisted out of the plane of the attached aryl ring by 7.0(3)degrees.

  DOI：

  10.1016/0022-328x(96)06140-2

文献信息

• Alkyl- and aryl-sulphinylmethylgermanium compounds Ph3GeCH2S(O)R: structure of Ph3GeCH2S(O)C6H4tBu-p
  作者：James L. Wardell、Phillip J. Cox

  DOI：10.1016/0022-328x(96)06140-2

  日期：1996.5

  Triphenyl[(organosulphinyl)methyl]germanium compounds [Ph(3)GeCH(2)S(O)R: 1 R = Me, C(6)H(4)X-p, X = H, Me or (t)Bu] have been prepared by oxidation of the corresponding sulphido compounds, Ph(3)GeCH(2)SR, with m-chloroperbenzoic acid. Further oxidation of 1 by m-ClC6H4CO3H produces the corresponding sulphones, Ph(3)GeCH(2)S(O)(2)R. Compounds (1 R = Me or C(6)H(4)(t)Bu-p) are extensively decomposed on heating to 170 degrees C. A crystal structure determination of (1 R = C(6)H(4)(t)Bu) indicated it to be a molecular species with a tetrahedral geometry at germanium. The S-O bond is twisted out of the plane of the attached aryl ring by 7.0(3)degrees.