6,7-Dichloro-2-dodecylbenzo[de]isoquinoline-1,3-dione | 712326-76-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 6,7-Dichloro-2-dodecylbenzo[de]isoquinoline-1,3-dione
• 英文别名: 6,7-dichloro-2-dodecylbenzo[de]isoquinoline-1,3-dione
• CAS: 712326-76-6
• 化学式: C₂₄H₂₉Cl₂NO₂
• 分子量: 434.406
• InChiKey: MSKBIHAJMVYLRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N-二甲基乙二胺 、 6,7-Dichloro-2-dodecylbenzo[de]isoquinoline-1,3-dione 以 乙腈 为溶剂， 反应 7.0h， 以77%的产率得到6,7-bis[2-(dimethylamino)ethylamino]-2-dodecylbenzo[de]isoquinoline-1,3-dione
  参考文献：
  名称：

  A novel chromatism switcher with double receptors selectively for Ag+ in neutral aqueous solution: 4,5-diaminoalkeneamino-N-alkyl-l,8-naphthalimides

  摘要：

  Two novel fluorosensors of 4,5-disubstituted-N-alkyl-1,8-naphthalimide derivatives (H1, H2, H3) with double ethylenediamino receptors, double propylenediamino receptors, or one methylpiperazine receptor were synthesized, respectively. Their fluorescence and absorption in the presence or absence of nine metal ions were studied. In the presence of Ag+, HI's absorption moved to long wavelength with color change from yellow-green to red, its quenching and red shift in fluorescence were also remarkable. Similarly, HI's fluorescence was also strongly quenched in the presence Of CU2+. In addition, H1 and H2 show high pH sensitively. There was 139-folds fluorescence enhancement for H1, 22-folds for H2, and 4-folds for H3 when pH was changed from 8 to 3, respectively. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.03.105
• 作为产物：
  描述：

  苊 在 chromium(VI) oxide 、 potassium dichromate 、 磺酰氯 作用下， 以 乙醇 、 二氯甲烷 、 溶剂黄146 为溶剂， 反应 10.0h， 生成 6,7-Dichloro-2-dodecylbenzo[de]isoquinoline-1,3-dione
  参考文献：
  名称：

  A novel chromatism switcher with double receptors selectively for Ag+ in neutral aqueous solution: 4,5-diaminoalkeneamino-N-alkyl-l,8-naphthalimides

  摘要：

  Two novel fluorosensors of 4,5-disubstituted-N-alkyl-1,8-naphthalimide derivatives (H1, H2, H3) with double ethylenediamino receptors, double propylenediamino receptors, or one methylpiperazine receptor were synthesized, respectively. Their fluorescence and absorption in the presence or absence of nine metal ions were studied. In the presence of Ag+, HI's absorption moved to long wavelength with color change from yellow-green to red, its quenching and red shift in fluorescence were also remarkable. Similarly, HI's fluorescence was also strongly quenched in the presence Of CU2+. In addition, H1 and H2 show high pH sensitively. There was 139-folds fluorescence enhancement for H1, 22-folds for H2, and 4-folds for H3 when pH was changed from 8 to 3, respectively. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.03.105

文献信息

• A novel chromatism switcher with double receptors selectively for Ag+ in neutral aqueous solution: 4,5-diaminoalkeneamino-N-alkyl-l,8-naphthalimides
  作者：Lihua Jia、Yu Zhang、Xiangfeng Guo、Xuhong Qian

  DOI：10.1016/j.tetlet.2004.03.105

  日期：2004.5

  Two novel fluorosensors of 4,5-disubstituted-N-alkyl-1,8-naphthalimide derivatives (H1, H2, H3) with double ethylenediamino receptors, double propylenediamino receptors, or one methylpiperazine receptor were synthesized, respectively. Their fluorescence and absorption in the presence or absence of nine metal ions were studied. In the presence of Ag+, HI's absorption moved to long wavelength with color change from yellow-green to red, its quenching and red shift in fluorescence were also remarkable. Similarly, HI's fluorescence was also strongly quenched in the presence Of CU2+. In addition, H1 and H2 show high pH sensitively. There was 139-folds fluorescence enhancement for H1, 22-folds for H2, and 4-folds for H3 when pH was changed from 8 to 3, respectively. (C) 2004 Elsevier Ltd. All rights reserved.