6-(苯氧基)苯并[c][1,2]苯并氧杂环己膦烷 | 35948-27-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 6-(苯氧基)苯并[c][1,2]苯并氧杂环己膦烷
• 英文名称: 6-phenoxy-6H-dibenz<1,2>oxaphosphorin
• 英文别名: 6h-Dibenz[c,e][1,2]oxaphosphorin, 6-phenoxy-；6-phenoxybenzo[c][2,1]benzoxaphosphinine
• CAS: 35948-27-7
• 化学式: C₁₈H₁₃O₂P
• 分子量: 292.274
• InChiKey: LPBCBDKFQYOTCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-Phenylphen-1-oxydichlorphosphan 在 三乙胺 、 zinc(II) chloride 作用下， 反应 5.25h， 生成 6-(苯氧基)苯并[c][1,2]苯并氧杂环己膦烷
  参考文献：
  名称：

  Pastor, Stephen D.; Spivack, John D.; Steinhuebel, Leander P., Phosphorus and Sulfur and the Related Elements, 1987, vol. 31, p. 71 - 76

  摘要：

  DOI：

文献信息

• Tuning Product Selectivity in Catalytic Hydroformylation Reactions with Carbon Dioxide Expanded Liquids
  申请人：Subramaniam Bala

  公开号：US20070219399A1

  公开（公告）日：2007-09-20

  An improved hydroformylation process is provided, which comprises reacting an olefin with CO and H 2 in the presence of a hydroformylation catalyst in a liquid that has been volumetrically expanded with a compressed gas, such as supercritical carbon dioxide.

  提供了一种改进的氢甲酰化过程，包括在液体中，该液体已经被压缩气体（如超临界二氧化碳）体积膨胀的情况下，在氢甲酰化催化剂的存在下，将烯烃与CO和H2反应。
• [DE] VERFAHREN ZUR HYDROFORMYLIERUNG VON OLEFINISCH UNGESÄTTIGTEN VERBINDUNGEN, INSBESONDERE OLEFINEN IN GEGENWART CYCLISCHER KOHLENSÄUREESTER<br/>[EN] METHOD FOR THE HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS, ESPECIALLY OLEFINS, IN THE PRESENCE OF CYCLIC CARBONIC ACID ESTERS<br/>[FR] PROCEDE D'HYDROFORMYLATION DE COMPOSES OLEFINIQUEMENT INSATURES, EN PARTICULIER D'OLEFINES, EN PRESENCE D'ESTERS CYCLIQUES D'ACIDE CARBONIQUE
  申请人：OXENO OLEFINCHEMIE GMBH

  公开号：WO2004020380A1

  公开（公告）日：2004-03-11

  Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Aldehyden durch von Metallen der 8. bis 10. Gruppe des Periodensystems der Elemente katalysierte Hydroformylierung von olefinisch ungesättigten Verbindungen in Gegenwart von cyclischen Kohlensäureestern und Liganden, die keine Sulfonsäure- oder Sulfonatgruppe aufweisen.

  本发明涉及一种通过元素周期表第8至第10族金属催化的烯烃不饱和化合物的氢甲酰化制备醛的方法，其中存在环状碳酸酯和不含磺酸或磺酸盐基团的配体。
• Flameproof expandable polymerizates
  申请人：Eberstaller Roman

  公开号：US20120184635A1

  公开（公告）日：2012-07-19

  The invention relates to flameproof expandable polymers containing at least one blowing agent, wherein at least one phosphorus compound is contained as a flame retardant. Novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene derivatives, namely 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione ammonium salt, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-ei-hydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione melaminium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione guanidinium salt, bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthrene-10-yl)sulfide, 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-ylthio)-9-oxa-10-phosphaphenanthrene-10-one, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)sulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)disulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)tetrasulfide, di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)ether and/or 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yloxy)-9-oxa-10-phosphaphenanthrene-10-one, or ring-opened hydrolyzates thereof, are provided as flame retardants.

  本发明涉及至少含有一种发泡剂的阻燃膨胀聚合物，其中至少含有一种磷化合物作为阻燃剂。提供了新型的9,10-二氢-9-氧-10-磷杂菲衍生物，包括9,10-二氢-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮铵盐，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三聚氰胺盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮胍盐，双(9,10-二氢-9-氧-10-氧-10-磷杂菲-10-基)硫化物，9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基硫基)-9-氧-10-磷杂菲-10-酮，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)二硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)四硫化物，二(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)醚和/或9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-氧基)-9-氧-10-磷杂菲-10-酮及其开环水解物作为阻燃剂。
• Polymer-Supported Transition Metal Catalyst Complexes and Methods of Use
  申请人：Tunge Jon

  公开号：US20110230620A1

  公开（公告）日：2011-09-22

  A catalyst composition comprising a polymer functionalized with a ligand for binding a transition metal containing compound to form a transition metal complex, wherein said functionalized polymer has a number average molecular weight of about 5,000 to 30,000 g/mol and a polydispersity index of about 1.0 to 2.0. The catalyst is used in a hydroformylation reaction, preferably one in which the liquid phase has been volumetrically expanded with a compressed gas, is readily recyclable using nanofiltration.

  催化剂组成包括聚合物，其功能化以与过渡金属含配合物结合形成过渡金属配合物的配体。所述功能化聚合物的数量平均分子量约为5,000至30,000克/摩尔，聚分散指数约为1.0至2.0。该催化剂用于羰基化反应，最好是液相已经通过压缩气体体积膨胀，可以通过纳滤技术方便地回收利用。
• Aromatische cyclische Phosphonigsäure-diester und mit diesen Verbindungen stabilisiertes organisches Material
  申请人：CIBA-GEIGY AG

  公开号：EP0000352A1

  公开（公告）日：1979-01-24

  Aromatische cyclische Phosphonigsäure-diester der Formeln eignen sich als Stabilisatoren für organisches Material.

  式中的芳香族环状膦酸二酯 可用作有机材料的稳定剂。