1,21,23,25-tetramethyl-5,9,13,17-tetramethoxy-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2λ⁵]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:1',2'-d']bis[1,3,2λ⁵]benzodioxaphosphocine | 212052-41-0

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 1,21,23,25-tetramethyl-5,9,13,17-tetramethoxy-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2λ⁵]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:1',2'-d']bis[1,3,2λ⁵]benzodioxaphosphocine
• 英文别名: 3,9,15,21-Tetramethoxy-25,29,33,37-tetramethyl-2,4,8,10,14,16,20,22-octaoxa-3,9,15,21-tetraphosphanonacyclo[21.15.1.124,38.05,36.07,34.011,32.013,30.017,28.019,26]tetraconta-1(39),5,7(34),11,13(30),17(28),18,23,26,31,35,38(40)-dodecaene
• CAS: 212052-41-0
• 化学式: C₃₆H₃₆O₁₂P₄
• 分子量: 784.57
• InChiKey: NGNUUYXTGRPYOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  52
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  111
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,21,23,25-tetramethyl-5,9,13,17-tetramethoxy-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2λ⁵]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:1',2'-d']bis[1,3,2λ⁵]benzodioxaphosphocine 在 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 生成 1,21,23,25-tetraethyl-5,9,13,17-tetraethoxy-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2λ⁵]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ⁵]benzodioxaphosphocine 5,9,13,17-tetrasulfide
  参考文献：
  名称：

  AMIDOPHOSPHITES IN THE CHEMISTRY OF CALYX[4]RESORCINOLARENE

  摘要：

  The possibility of using phosphorous amides for the phosphorylation of calyx[4]resorcinolarenes is found. This reaction can be directed to the synthesis of their octaphosphorylated derivatives or phosphocavitands. It is shown that the obtained compounds demonstrate substantially different properties depending on the character of their molecular matrix.

  DOI：

  10.1080/10426509608046391
• 作为产物：
  描述：

  Calix[4]resorcinarene 、 alkaline earth salt of/the/ methylsulfuric acid 以 1,4-二氧六环 为溶剂， 以77%的产率得到1,21,23,25-tetramethyl-5,9,13,17-tetramethoxy-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2λ⁵]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:1',2'-d']bis[1,3,2λ⁵]benzodioxaphosphocine
  参考文献：
  名称：

  AMIDOPHOSPHITES IN THE CHEMISTRY OF CALYX[4]RESORCINOLARENE

  摘要：

  The possibility of using phosphorous amides for the phosphorylation of calyx[4]resorcinolarenes is found. This reaction can be directed to the synthesis of their octaphosphorylated derivatives or phosphocavitands. It is shown that the obtained compounds demonstrate substantially different properties depending on the character of their molecular matrix.

  DOI：

  10.1080/10426509608046391

文献信息

• Maslennikova; Shkarina; Vasyanina, Russian Journal of General Chemistry, 1998, vol. 68, # 3, p. 350 - 360
  作者：Maslennikova、Shkarina、Vasyanina、Lysenko、Antipin、Nifant'ev

  DOI：——

  日期：——
• Shkarina; Maslennikova; Vasyanina, Russian Journal of General Chemistry, 1997, vol. 67, # 12, p. 1867 - 1873
  作者：Shkarina、Maslennikova、Vasyanina、Lysenko、Antipin、Nifant'ev

  DOI：——

  日期：——
• AMIDOPHOSPHITES IN THE CHEMISTRY OF CALYX[4]RESORCINOLARENE
  作者：Vera I. Maslennikova、Elena V. Panina、Anna R. Bekker、Larisa K. Vasyanina、Eduard E. Nifantyev

  DOI：10.1080/10426509608046391

  日期：1996.6.1

  The possibility of using phosphorous amides for the phosphorylation of calyx[4]resorcinolarenes is found. This reaction can be directed to the synthesis of their octaphosphorylated derivatives or phosphocavitands. It is shown that the obtained compounds demonstrate substantially different properties depending on the character of their molecular matrix.