[2,2'-bipyridine]-4,4'-diylbis(methylene) diacrylate | 1376106-06-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [2,2'-bipyridine]-4,4'-diylbis(methylene) diacrylate
• 英文别名: [2-[4-(prop-2-enoyloxymethyl)pyridin-2-yl]pyridin-4-yl]methyl prop-2-enoate
• CAS: 1376106-06-7
• 化学式: C₁₈H₁₆N₂O₄
• 分子量: 324.336
• InChiKey: UXNNPRBXLLGVJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  24.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  78.38
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 [2,2'-bipyridine]-4,4'-diylbis(methylene) diacrylate 以 甲醇 为溶剂， 反应 12.0h， 以90%的产率得到
  参考文献：
  名称：

  基于四氢键的磷光铂（II）联吡啶超分子聚合物

  摘要：

  设计了带有双脲基嘧啶酮的铂（II）联吡啶基络合物（Pt-bisUPy），并对其自组装行为进行了彻底的研究[ 1]。1 H NMR，DOSY NMR，Ubbelohde粘度分析，UV / Vis和发射光谱。Pt-bisUPy在非极性溶剂中经历了浓度依赖性的环链聚合反应。氢键相互作用在超分子聚合物的形成过程中起着重要作用。通过细乳液法，将氢键结合的超分子聚合物在水中转化为纳米颗粒。这些纳米粒子表现出很强的π–π准分子发射。Pt-Pt相互作用产生的金属-金属-配体电荷转移（MMLCT）在发射光谱中不显着。即使在有氧条件下，纳米颗粒的磷光仍然持续。这些磷光纳米材料的三重态是长寿命的，并具有中等的发射量子产率。此外，

  DOI：

  10.1002/chem.201603467
• 作为产物：
  描述：

  2,2'-联吡啶-4,4'-二甲酸 在 sodium tetrahydroborate 、 2,6-二叔丁基-4-甲基苯酚 、 硫酸 、 三乙胺 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 43.0h， 生成 [2,2'-bipyridine]-4,4'-diylbis(methylene) diacrylate
  参考文献：
  名称：

  Establishing Dual Electrogenerated Chemiluminescence and Multicolor Electrochromism in Functional Ionic Transition-Metal Complexes

  摘要：

  A combination of electrochromism and electroluminescence in functional materials could lead to single-layer dual electrochromic/electroluminescent (EC/EL) display devices, capable of simultaneous operation in emissive and reflective modes. Whereas such next generation displays could provide optimal visibility in any ambient lighting situation, materials available that exhibit such characteristics in the active layer are limited due to the required intrinsic multifunctionality (i.e., redox activity, electroluminescence, electrochromism, and ion conductivity) and to date can only be achieved via the rational design of ionic transition-metal I complexes. Reported herein is the synthesis and characterization of a new family of acrylate-containing ruthenium (tris)bipyridine-based coordination complexes with multifunctional characteristics. Potential use of the presented compounds in EC/EL devices is established, as they are applied as cross-linked electrochromic films and electrochemiluminescent layers in light-emitting electrochemical cell devices. Electrochromic switching of the polymeric networks between yellow, orange, green, brown and transmissive states is demonstrated, and electrochemiluminescent devices based on the complexes synthesized show red-orange to deep red emission with lambda(max) ranging from 680 to 722 nm and luminance up to 135 cd/m(2). Additionally, a dual EC/EL device prototype is presented where light emission and multicolor electrochromism occur from the same pixel comprised of a single active layer, demonstrating a true combination of these properties in ionic transition-metal complexes.

  DOI：

  10.1021/ja2065297

文献信息

• Luminescent molecularly imprinted polymer nanocomposites for emission intensity and lifetime rapid sensing of tenuazonic acid mycotoxin
  作者：José Quílez-Alburquerque、Ana B. Descalzo、María C. Moreno-Bondi、Guillermo Orellana

  DOI：10.1016/j.polymer.2021.124041

  日期：2021.9