1,6-bis[N-(2-naphthyl)-N-phenylamino]pyrene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1,6-bis[N-(2-naphthyl)-N-phenylamino]pyrene
• 英文别名: N1,N6-Di-2-naphthalenyl-N1,N6-diphenyl-1,6-pyrenediamine；1-N,6-N-dinaphthalen-2-yl-1-N,6-N-diphenylpyrene-1,6-diamine
• 化学式: C₄₈H₃₂N₂
• 分子量: 636.795
• InChiKey: XVNGEPFGKAOTSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  50
• 可旋转键数：
  6
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,6-二溴芘 、 N-苯基-2-萘胺 在 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 邻二甲苯 为溶剂， 反应 7.0h， 以77%的产率得到1,6-bis[N-(2-naphthyl)-N-phenylamino]pyrene
  参考文献：
  名称：

  Novel 1,8-bis(diarylamino)pyrenes as OLED materials

  摘要：

  New soluble electroluminescent pyrene derivatives, namely, 1,8-bis(diarylamino)pyrenes, have been synthesized by the Buchwald-Hartwing cross-coupling. Light-emitting devices based on these derivatives have been prepared.

  DOI：

  10.1016/j.mencom.2016.09.025

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：SEO Jeong Dae

  公开号：US20100155714A1

  公开（公告）日：2010-06-24

  Disclosed is an organic electroluminescent device including a substrate, a first and a second electrode, and an emitting layer formed between the first electrode and the second electrode. The emitting layer includes a plurality of materials which is a blue emitting material using a following chemical formula as dopant. In this case, at least one of A 1 and A 2 is selected from a substituted or non-substituted aromatic group, a heterocyclic group, an aliphatic group, and hydrogen.

  揭示了一种有机电致发光器件，包括基板、第一和第二电极，以及形成在第一电极和第二电极之间的发光层。发光层包括多种材料，其中一种是使用以下化学式作为掺杂剂的蓝色发光材料。在这种情况下，A1和A2中至少有一个是从取代或非取代芳香基团、杂环基团、脂肪基团和氢中选择的。
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Gracel Display Inc.

  公开号：EP2098532A1

  公开（公告）日：2009-09-09

  The present invention relates to novel organic electroluminescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same. The organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1):

  本发明涉及一种表现出高发光效率的新型有机电致发光化合物，以及包括它们的有机电致发光装置。本发明的有机电致发光化合物的特点在于它们由化学式（1）所表示：
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20190074449A1

  公开（公告）日：2019-03-07

  Compounds that are organic radicals that can have a dual function. The compounds can be fluorescent emitters that emit in the near-IR. The compounds can also facilitate reverse intersystem crossing (RISC) to convert triplet excitons in an OLED to singlet excited states to maximize utilization of generated excitons in the OLED and approach 100% internal quantum efficiency.

  这是一个有着双重功能的有机基团化合物。这些化合物可以是发射近红外光的荧光发射体。这些化合物也可以促进反交替系统穿越（RISC），将OLED中的三重激子转化为单重激发态，以最大化利用OLED中产生的激子并接近100％的内部量子效率。
• DEVELOPMENT OF MATERIAL FOR HOLE BLOCKING LAYER WITH HIGH EFFICIENCY AND LONG LIFESPAN, AND ORGANIC LIGHT-EMITTING DEVICE AND ELECTRONIC APPARATUS UTILIZING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20210296592A1

  公开（公告）日：2021-09-23

  Disclosed are an organic light-emitting device including a first compound represented by Formula 1 below and a second compound represented by Formula 2 below, and an electronic apparatus including the organic light-emitting device. The variables in Formula 1 and Formula 2 are the same as described in the present specification.

  本发明涉及一种有机发光器件，包括以下由式1所表示的第一化合物和由式2所表示的第二化合物，并且还涉及带有该有机发光器件的电子设备。式1和式2中的变量与本说明书中描述的相同。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20170179404A1

  公开（公告）日：2017-06-22

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a first compound represented by Formula 1 and a second compound represented by Formula 501. The organic light-emitting device including the first compound and the second compound may have low driving voltage, high efficiency, and high luminance.

  有机发光器件包括：第一电极；面向第一电极的第二电极；以及在第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中有机层包括由公式1表示的第一化合物和由公式501表示的第二化合物。包括第一化合物和第二化合物的有机发光器件可能具有低驱动电压、高效率和高亮度。