[(E)-[phenyl(pyridin-2-yl)methylidene]amino] benzoate | 100663-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(E)-[phenyl(pyridin-2-yl)methylidene]amino] benzoate
• CAS: 100663-87-4
• 化学式: C₁₉H₁₄N₂O₂
• 分子量: 302.332
• InChiKey: NJKOHADRZRIUBB-DYTRJAOYSA-N

物化性质

• 沸点：
  461.5±37.0 °C(Predicted)
• 密度：
  1.13±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [(E)-[phenyl(pyridin-2-yl)methylidene]amino] benzoate 、 苄胺 以 二氯甲烷 为溶剂， 反应 24.0h， 以94%的产率得到2-吡啶基苯基酮肟
  参考文献：
  名称：

  HIGH CHEMOSELECTIVE SYNTHESIS OF CARBOXAMIDES BY USINGSYN-PHENYLPYRIDYL-O-ACYL OXIMES(PPKO)

  摘要：

  通过使用反式-苯基吡啶酮肟（PPKO）作为功能性离去基团，可以化学选择性地制备多种羧酰胺，并获得良好的产率。

  DOI：

  10.1246/cl.1985.701
• 作为产物：
  描述：

  2-吡啶甲酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 [(E)-[phenyl(pyridin-2-yl)methylidene]amino] benzoate
  参考文献：
  名称：

  HIGH CHEMOSELECTIVE SYNTHESIS OF CARBOXAMIDES BY USINGSYN-PHENYLPYRIDYL-O-ACYL OXIMES(PPKO)

  摘要：

  通过使用反式-苯基吡啶酮肟（PPKO）作为功能性离去基团，可以化学选择性地制备多种羧酰胺，并获得良好的产率。

  DOI：

  10.1246/cl.1985.701

文献信息

• LITHOGRAPHIC PRINTING PLATE PRECURSOR AND LITHOGRAPHIC PRINTING METHOD
  申请人：IWAI Yu

  公开号：US20080087183A1

  公开（公告）日：2008-04-17

  A lithographic printing plate precursor includes an image-recording layer which is capable of being removed with at least one of printing ink and dampening water and contains a compound represented by the following formula (I), a sensitizing dye and a compound having at least one addition-polymerizable ethylenically unsaturated bond: wherein R 1 represents a monovalent substituent, R 2 , R 3 , R 4 , R 5 and R 6 each independently represents a hydrogen atom, a halogen atom or a monovalent substituent, and X − represents an anion.

  一种光刻印刷版前体包括一个图像记录层，该层能够被印刷油墨和润湿水中的至少一种去除，并含有以下式（I）所代表的化合物，一种敏化染料和至少一种含有至少一个加成聚合乙烯基不饱和键的化合物：其中R1代表一个单价取代基，R2、R3、R4、R5和R6各自独立地代表氢原子、卤素原子或单价取代基，X⁻代表一个阴离子。
• POLYMERIZABLE COMPOSITION AND LITHOGRAPHIC PRINTING PLATE PRECURSOR
  申请人：Sugasaki Atsushi

  公开号：US20090053653A1

  公开（公告）日：2009-02-26

  A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R 1 and R 2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R 1 and R 2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.

  一种可聚合的组合物，包括：由使用以下式(I)所表示的化合物之一作为起始材料合成的聚氨酯树脂；光聚合或热聚合引发剂；以及具有乙烯基不饱和键的加成聚合化合物：其中，X代表三价或更高价原子；R1和R2各自独立地表示单键或具有取代基的烷基基团，但R1和R2不能同时表示单键；A表示直链连接基团；n为1到5的整数。
• MIYASAKA, TADAYO;MONOBE, HIDEAKI;NOGUCHI, SHUNSAKU, CHEM. LETT., 1986, N 4, 449-452
  作者：MIYASAKA, TADAYO、MONOBE, HIDEAKI、NOGUCHI, SHUNSAKU

  DOI：——

  日期：——
• DECOMPOSABLE RESIN COMPOSITION AND PATTERN-FORMING MATERIAL INCLUDING THE SAME
  申请人：Taguchi Yoshinori

  公开号：US20080070154A1

  公开（公告）日：2008-03-20

  A decomposable resin composition contains a base generator, and a polyurethane resin capable of being decomposed with a base generated from the base generator.
• Polymer having polymerizable group, polymerizable composition, planographic printing plate precursor, and planographic printing method using the same
  申请人：Kunita Kazuto

  公开号：US20080182205A1

  公开（公告）日：2008-07-31

  A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.