1-(Anthracen-9-ylmethyl)-1-methyl-3-phenylthiourea | 375368-26-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-(Anthracen-9-ylmethyl)-1-methyl-3-phenylthiourea
• CAS: 375368-26-6
• 化学式: C₂₃H₂₀N₂S
• 分子量: 356.491
• InChiKey: JYLMPYYUIHWCTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  546.9±43.0 °C(Predicted)
• 密度：
  1.259±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  47.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dichloro(2-benzylpyridine)gold(III) 、 1-(Anthracen-9-ylmethyl)-1-methyl-3-phenylthiourea 在 吡啶 作用下， 以 甲醇 为溶剂， 生成 [(2-bp)Au{SC(NMeCH₂An)NPh}](1+)
  参考文献：
  名称：

  Cycloaurated gold(III) complexes with monoanionic thiourea ligands

  摘要：

  Using a simple one-pot procedure, reaction of cycloaurated gold(III) dihalide complexes [LAuCl2] (L = 2-benzylpyridyl, 2-anilinopyridyl) with trisubstituted thioureas PhNHC(S)NR2 (R = Me, Cy) and Me3N in methanol, followed by addition of excess NaBPh4 gave the salts [LAu{SC(= NR2)NPh}]+BPh4- containing N,S-chelated thiourea monoanion ligands. The compounds were obtained in good yields, and were characterised by ESI MS, elemental microanalysis and in two cases by X-ray structure determinations. The series of complexes was extended by additional microscale reactions of LAuCl2 complexes (L = 2-benzyl-pyridyl, 2-anilinopyridyl, 2-benzoylpyridyl or picolinamide) with a wide range of trisubstituted thioureas, with products identified by ESI MS. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.07.027

文献信息

• Platinum(II) complexes of chelating and monodentate thiourea monoanions incorporating chiral, fluorescent or chromophoric groups
  作者：William Henderson、Brian K. Nicholson、Clifton E.F. Rickard

  DOI：10.1016/s0020-1693(01)00473-x

  日期：2001.8

  with triethylamine base, followed by addition of NaBPh4 gives the salts [PtSC(NR1R2)NR3}(PPh3)2]BPh4 in high yield; a range of thiourea substituents, including chiral, fluorescent and chromophoric groups can be incorporated. The azo dye-derived complex [PtSC(N(CH2CH2)2O)NC6H4NNC6H4NMe2}(PPh3)2]BPh4 has been characterised by a single-crystal X-ray diffraction study. The formation of a fluorescein-derivatised

  摘要顺式-[PtCl2（PPh3）2]与三取代硫脲[R1R2NC（S）NHR3]在回流的甲醇中与三乙胺碱反应，然后添加NaBPh4得到盐[Pt SC（NR1R2）NR3}（ PPh3）2] BPh4高产；可以引入许多硫脲取代基，包括手性，荧光和发色基团。偶氮染料衍生的配合物[Pt SC（N（CH2CH2）2O）NC6H4NNC6H4NMe2}（PPh3）2] BPh4的特征在于单晶X射线衍射研究。还描述了荧光素衍生的铂-硫脲复合物的形成。顺式[[PtCl2（PPh3）2]与PhNHC（S）NHPh或EtNHC（S）NHEt，三乙胺和NaBPh4的反应分别得到[Pt SC（NHPh）NPh}（PPh3）2] +和已知的阳离子[Pt SC（= NHEt）NEt}（PPh3）2] +，以四苯基硼酸盐的形式分离。顺式-[PtCl2（PPh3）2]与过量的Na [MeNHC（S）N
• Thiourea monoanion and dianion complexes of rhodium(III) and ruthenium(II)
  作者：William Henderson、Brian K Nicholson、Maarten B Dinger、Rachel L Bennett

  DOI：10.1016/s0020-1693(02)01017-4

  日期：2002.10

  as ligands is shown by the synthesis and characterisation of a range of rhodium(III) complexes of substituted thioureas, with support from a ruthenium(II) analogue in one case. Reaction of the complexes [LMCl(μ-Cl)] 2 [M=Rh, L=η 5 -C 5 Me 5 (Cp*); M=Ru, L=η 6 - p -cymene] with Na[MeNHC(S)NCN] and excess trimethylamine base gives the dinuclear complexes [LMSC(NCN)NMe}] 2 containing chelate-bridging

  摘要在一种情况下，在钌（II）类似物的支持下，一系列取代的硫脲的铑（III）配合物的合成和表征显示了去质子化的硫脲作为配体的多功能性。配合物[LMCl（μ-Cl）] 2的反应[M = Rh，L =η5 -C 5 Me 5（Cp *）； [M + H] +。M ＝ Ru，L ＝η6-对甲基苯甲基，具有Na [MeNHC（S）NCN]和过量的三甲胺碱，得到含有螯合桥联硫脲双阴离子配体的双核配合物[LM SC（＝ NCN）NMe}] 2。通过X射线衍射研究表征Ru配合物。通过类似的反应，制备了含有螯合硫脲双阴离子配体的单核络合物[Cp * Rh SC（NCN）NMe}（PPh 3）]和[Cp * Rh SC（NPh）NPh}（PPh 3）]。在三苯基膦存在下。[Cp * Rh SC（= NCN）NMe}（PPh 3）]与HCl或[Cp * RhCl（μ-Cl）] 2与2当量的反应。PPh