Bicyclo<4.2.0>octa-2,4,7-trien | 4011-16-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: Bicyclo<4.2.0>octa-2,4,7-trien
• 英文别名: bicyclo<4.2.0>octa-2,4,7-triene；cis-Bicyclo[4.2.0]octa-2,4,7-triene；bicyclo[4.2.0]octa-2,4,7-triene
• CAS: 4011-16-9
• 化学式: C₈H₈
• 分子量: 104.152
• InChiKey: ODPJJUMAGHWOOY-UHFFFAOYSA-N

物化性质

• 沸点：
  167.8±25.0 °C(Predicted)
• 密度：
  1.012±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Bicyclo<4.2.0>octa-2,4,7-trien 生成 1,3,5,7-cyclooctatetraene
  参考文献：
  名称：

  Trapping of 1,3,5,7-cyclooctatetraene valence tautomers. Thermodynamic stability of bicyclo[4.2.0]octa-2,4,7-triene

  摘要：

  DOI：

  10.1021/jo00370a036
• 作为产物：
  描述：

  1,3,5,7-cyclooctatetraene 生成 Bicyclo<4.2.0>octa-2,4,7-trien
  参考文献：
  名称：

  Trapping of 1,3,5,7-cyclooctatetraene valence tautomers. Thermodynamic stability of bicyclo[4.2.0]octa-2,4,7-triene

  摘要：

  DOI：

  10.1021/jo00370a036

文献信息

• Fullerene Derivatives and Organic Electronic Device Comprising the Same
  申请人：Yoon Sung Cheol

  公开号：US20120004476A1

  公开（公告）日：2012-01-05

  The present invention relates to fullerene derivatives and an organic electronic device using the same, and more specifically, to a novel fullerene derivative incorporating an aromatic fused ring compound and to an organic electronic device with excellent electrical properties by employing the fullerene derivative. In more detail, the novel fullerene derivative incorporating an aromatic fused ring compound according to the present invention exhibits excellent solubility in organic solvents and has a high electrochemical electron mobility and a high LUMO energy level, thereby making the fullerene derivative a suitable material for organic solar cells featuring a high open circuit voltage (Voc) and an improved energy conversion efficiency, or applicable for use in organic electronic devices such as organic thin film transistors.

  本发明涉及富勒烯衍生物及其应用于有机电子器件的技术领域，更具体地说，涉及一种新颖的富勒烯衍生物，其中包含一个芳香融合环化合物，并且通过采用该富勒烯衍生物，可以制备出具有优异电学性能的有机电子器件。更详细地说，本发明的新颖富勒烯衍生物中包含一个芳香融合环化合物，具有在有机溶剂中良好的溶解性，并且具有高的电化学电子迁移率和高的LUMO能级，从而使该富勒烯衍生物成为适用于具有高开路电压（Voc）和改善的能量转换效率的有机太阳能电池的合适材料，或者适用于有机薄膜晶体管等有机电子器件。
• Photoisomerisation of cyclo-octatetraene radical cations in a solid freon matrix
  作者：Christopher J. Rhodes

  DOI：10.1039/c39900000592

  日期：——

  Following γ-irradiation of cyclo-octatetraene in Freon solvents at 77 K, a single central feature was observed by ESR spectroscopy, from the parent radical cation; after bleaching with visible light, this changed to a triplet (36.4 G) of quintets (7.8 G) pattern, assigned to the rearranged cation (IV).

  在氟利昂溶剂中于77 Kγ辐射环辛酸酯后，通过ESR光谱从母体自由基阳离子观察到一个中心特征。在用可见光漂白后，其变为三重态（36.4 G）的五重态（7.8 G）模式，分配给重排的阳离子（IV）。
• 1-Thia-3,4-diazolidine-2,5-dione functionality: a photochemical synthon for the azo group
  作者：Michael Squillacote、James De Felippis

  DOI：10.1021/jo00092a013

  日期：1994.7

  The 1-thia-3,4-diazolidine-2,5-dione functional group was shown to yield azo compounds upon photolysis. This photoreaction when combined with the known ability of this group to react in a Diels-Alder fashion or as a dinucelophile toward alkylating agents greatly increases the utility of this functionality. The dual reactivity of this group was demonstrated in the synthesis of a number of 3,4-dialkyl-1-thia-3,4-diazolidine-2,5-diones. The photolysis of these compounds produced either thermally stable cyclic azo compounds or the decomposition products of thermally unstable azo compounds.
• Synthesis of the endoperoxide anti-7,8-dioxatricyclo[4.2.2.02,5]deca-3,9-diene via singlet oxygenation of the bicyclic valence tautomer of cyclooctatetraene and its transformations
  作者：Waldemar Adam、Omar Cueto、Ottorino De Lucchi、Karl Peters、Eva-Maria Peters、Hans Georg Von Schnering

  DOI：10.1021/ja00409a033

  日期：1981.9
• Oxygen functionalization of cyclooctatetraene via singlet oxygenation: synthesis and transformations of anti-7,8-dioxatricyclo[4.2.2.02,5]deca-3,9-diene, the endoperoxide of the bicyclic valence tautomer of cyclooctatetraene
  作者：Waldemar Adam、Omar Cueto、Ottorino De Lucchi

  DOI：10.1021/jo01313a046

  日期：1980.12