TC8A-SO2 | 953814-17-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: TC8A-SO2
• 英文别名: 5,11,17,23,29,35,41,47-Octatert-butyl-2,2,8,8,14,14,20,20,26,26,32,32,38,38,44,44-hexadecaoxo-2lambda6,8lambda6,14lambda6,20lambda6,26lambda6,32lambda6,38lambda6,44lambda6-octathianonacyclo[43.3.1.13,7.19,13.115,19.121,25.127,31.133,37.139,43]hexapentaconta-1(48),3,5,7(56),9,11,13(55),15,17,19(54),21,23,25(53),27(52),28,30,33(51),34,36,39(50),40,42,45(49),46-tetracosaene-49,50,51,52,53,54,55,56-octol；5,11,17,23,29,35,41,47-octatert-butyl-2,2,8,8,14,14,20,20,26,26,32,32,38,38,44,44-hexadecaoxo-2λ6,8λ6,14λ6,20λ6,26λ6,32λ6,38λ6,44λ6-octathianonacyclo[43.3.1.13,7.19,13.115,19.121,25.127,31.133,37.139,43]hexapentaconta-1(48),3,5,7(56),9,11,13(55),15,17,19(54),21,23,25(53),27(52),28,30,33(51),34,36,39(50),40,42,45(49),46-tetracosaene-49,50,51,52,53,54,55,56-octol
• CAS: 953814-17-0
• 化学式: C₈₀H₉₆O₂₄S₈
• 分子量: 1698.16
• InChiKey: YVRLNLIOEINPJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.9
• 重原子数：
  112
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  502
• 氢给体数：
  8
• 氢受体数：
  24

反应信息

• 作为产物：
  描述：

  5,11,17,23,29,35,41,47-Octatert-butyl-2,8,14,20,26,32,38,44-octathianonacyclo[43.3.1.13,7.19,13.115,19.121,25.127,31.133,37.139,43]hexapentaconta-1(48),3,5,7(56),9,11,13(55),15,17,19(54),21,23,25(53),27(52),28,30,33(51),34,36,39(50),40,42,45(49),46-tetracosaene-49,50,51,52,53,54,55,56-octol 在 sodium tungstate 、 双氧水 、 sodium acetate 、 溶剂黄146 、 硫酸 作用下， 以 水 为溶剂， 反应 6.0h， 以94.2%的产率得到TC8A-SO2
  参考文献：
  名称：

  OXIDIZED CYCLIC PHENOL SULFIDE MIXTURE, AND CHARGE CONTROLLING AGENT OR TONER USING THE SAME

  摘要：

  公开号：

  EP2011793B1

文献信息

• METHODS FOR PRODUCING OXIDIZED CYCLIC PHENOL SULFIDES
  申请人：Yasumura Masateru

  公开号：US20090275783A1

  公开（公告）日：2009-11-05

  A method for producing an oxidized cyclic phenol sulfide which comprises the step of oxidizing a cyclic phenol sulfide of the following formula (1) as a raw material: wherein R represents a straight or branched alkyl group having 1 to 6 carbon atoms, and m is an integer from 4 to 8, in a solvent(s) other than a halogenated hydrocarbon in an amount of 2 or more and less than 10 parts by weight per 1 part by weight of the cyclic phenol sulfide, with an oxidizing agent(s) to obtain an oxidized cyclic phenol sulfide of the following formula (2): wherein R represents a straight or branched alkyl group having 1 to 6 carbon atoms, m is an integer from 4 to 8, and n is 1 or 2.

  一种制备氧化环状苯基硫醚的方法，包括以下步骤：将以下式（1）的环状苯基硫醚作为原料，在非卤代烃类溶剂中，每1份环状苯基硫醚中加入2份或更多但少于10份的氧化剂，将其氧化，得到以下式（2）的氧化环状苯基硫醚：其中，R表示1至6个碳原子的直链或支链烷基，m为4至8的整数，n为1或2。
• OXIDIZED CYCLIC PHENOL SULFIDE MIXTURE, AND CHARGE CONTROLLING AGENT OR TONER USING THE SAME
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2011793B1

  公开（公告）日：2014-09-10