4-Ethylnonafluorobiphenyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Ethylnonafluorobiphenyl
• 英文别名: 1-Ethyl-2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)benzene
• 化学式: C₁₄H₅F₉
• 分子量: 344.179
• InChiKey: NJCYTIUUDONJOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 4-Ethylnonafluorobiphenyl 生成 4-Ethyl-4'-(trimethylsilyl)octafluorbiphenyl
  参考文献：
  名称：

  有机镁试剂与全氟芳族化合物的反常反应

  摘要：

  DOI：

  10.1016/s0022-328x(00)86040-4
• 作为产物：
  描述：

  十氟联苯 、 乙基溴化镁 生成 4-Ethylnonafluorobiphenyl
  参考文献：
  名称：

  有机镁试剂与全氟芳族化合物的反常反应

  摘要：

  DOI：

  10.1016/s0022-328x(00)86040-4

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Metallocenes and Catalyst Compositions Derived Tehrefrom
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20150025205A1

  公开（公告）日：2015-01-22

  This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound that is asymmetric having two non-identical indenyl ligands with substitution at R 2 having a branched or unbranched C 1 -C 20 alkyl group substituted with a cyclic group or a cyclic group, R 8 is an alkyl group and R 4 and R 10 are substituted phenyl groups.

  这项发明涉及一种新型的二、三或四组过渡金属茂配体催化剂化合物，具有不对称性，具有两个非相同的茚基配体，R2上有一个支链或非支链的C1-C20烷基基团，该基团被一个环基团或环基团取代，R8是一个烷基基团，R4和R10是取代苯基团。
• ORGANIC ELECTRONIC MATERIAL, INK COMPOSITION, ORGANIC ELECTRONIC ELEMENT, AND ORGANIC ELECTRONIC ELEMENT PRODUCTION METHOD
  申请人：HITACHI CHEMICAL COMPANY, LTD.

  公开号：US20200044154A1

  公开（公告）日：2020-02-06

  The present invention relates to an organic electronic material containing at least an ionic compound represented by general formula (1) shown below and a compound having a charge transport unit. The present invention can provide an organic electronic material that is capable of forming an organic electronic element having a low drive voltage and excellent emission efficiency and lifespan characteristics. In general formula (1), ArF represents a fluoroaryl group or a fluoroheteroaryl group, each of R a and R b independently represents a hydrogen atom (H), an alkyl group, a benzyl group, an aryl group or a heteroaryl group, and A represents an anion.

  本发明涉及一种有机电子材料，其中至少包含一个由下面所示的一般式（1）表示的离子化合物和具有电荷传输单元的化合物。本发明可以提供一种有机电子材料，能够形成具有低驱动电压、优异发射效率和寿命特性的有机电子元件。在一般式（1）中，ArF表示氟芳基或氟杂芳基，每个Ra和Rb独立地表示氢原子（H）、烷基、苄基、芳基或杂芳基，A表示阴离子。
• Bridged Metallocene Compounds, Catalyst Systems and Processes for Polymerization Therewith
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20140179884A1

  公开（公告）日：2014-06-26

  This invention relates to bridged metallocene compounds and catalyst systems comprising these bridged metallocene compounds.

  本发明涉及桥联的金属茂化合物和包括这些桥联金属茂化合物的催化剂系统。
• Pyridyldiamide Metal Catalysts and Processes to Produce Polyolefins
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20140316089A1

  公开（公告）日：2014-10-23

  Disclosed are new classes of pyridyldiamide catalyst components useful in olefin polymerization, an example of which includes: wherein M is a hafnium or zirconium; R 1 and R 11 are selected from phenyl and substituted phenyl, wherein the substitutions are selected from C 1 to C 5 hydrocarbyls, preferably C 2 to C 4 hydrocarbyls, and can reside in any of the ortho, meta, para positions on the phenyl ring; R 2 ′ and R 2 ″ are selected independently from hydrogen and C 1 to C 6 hydrocarbyls, preferably hydrogen; R 10 is a hydrocarbyl bridging group; R 3 , R 4 , and R 5 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; and R 6 , R 7 , R 8 , and R 9 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; wherein R 6 and R 7 form an aromatic ring or R 7 is hydrogen and R 6 is selected from methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, and tert-butyl, preferably methyl.

  本发明涉及一种用于烯烃聚合的新型吡啶二酰胺催化剂组分，其中一个示例包括： 其中，M为钽或锆；R1和R11选自苯基和取代苯基，其中所述取代基选自C1到C5的烃基，优选为C2到C4的烃基，并可以存在于苯环的任何一个邻位、间位或对位上；R2'和R2"独立地选自氢和C1到C6的烃基，优选为氢；R10为烃基桥连基；R3、R4和R5独立地选自氢、烃基和取代烃基；R6、R7、R8和R9独立地选自氢、烃基和取代烃基；其中，R6和R7形成芳香环或R7为氢且R6选自甲基、乙基、丙基、异丙基、丁基、仲丁基和叔丁基，优选为甲基。