p-bis(2-thienylseleno)benzene | 1290542-05-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-bis(2-thienylseleno)benzene
• CAS: 1290542-05-0
• 化学式: C₁₄H₁₀S₂Se₂
• 分子量: 400.285
• InChiKey: VHPHZADDMLMIJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.12
• 重原子数：
  18.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  benzene-1,4-diselenol 在 双氧水 、 溶剂黄146 作用下， 以 乙酸乙酯 为溶剂， 反应 12.0h， 生成 p-bis(2-thienylseleno)benzene
  参考文献：
  名称：

  Electrophilic organic selenium reagents—protonated seleninic acids as precursors for unsymmetrical aromatic selenides

  摘要：

  Arylselenylations of methylbenzenes, methoxybenzenes and thiophene were smoothly achieved with selenenium ions generated by comproportionation of 1:1 mixtures of p-toluenesulfonic acid salts of seleninic acids and the corresponding diselenides. A series of p-toluenesulfonic salts of seleninic acids were prepared by hydrogen peroxide oxidation of the corresponding diselenides in the presence of p-toluenesulfonic acid. Novel 2-(organylseleno)thiophenes were obtained by heating the protonated seleninic acids with a 50-fold excess of thiophene in glacial acetic acid. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2011.02.004

文献信息

• CuMoO ₄ Catalyzed Csp ² −Se Cross‐Coupling of Aryl Bromide and Iodide with Diaryldiselenides in Water
  作者：Prabhupada Choudhury、Amit Kumar Pradhan、Soumyaranjan Jena、Bikash Kumar Sahoo、Santosh Kumar Sahu、Pradyota Kumar Behera、Papita Behera、Amlan Swain、Laxmidhar Rout

  DOI：10.1002/ejoc.202201194

  日期：2022.12.27

  An new bimetallic CuMoO4 nanocatalyst is used for synthesis of diarylselenoether in water. Reaction is free from co-reductant and ligand and shows broad substrate scope with good functional group tolerance. The catalyst is recyclable.

  一种新型双金属 CuMoO 4纳米催化剂用于在水中合成二芳基硒醚。反应不含共还原剂和配体，显示出广泛的底物范围和良好的官能团耐受性。催化剂是可回收的。
• Electrophilic organic selenium reagents—protonated seleninic acids as precursors for unsymmetrical aromatic selenides
  作者：Nicolai Stuhr-Hansen、Theis Ivan Sølling、Lars Henriksen

  DOI：10.1016/j.tet.2011.02.004

  日期：2011.4

  Arylselenylations of methylbenzenes, methoxybenzenes and thiophene were smoothly achieved with selenenium ions generated by comproportionation of 1:1 mixtures of p-toluenesulfonic acid salts of seleninic acids and the corresponding diselenides. A series of p-toluenesulfonic salts of seleninic acids were prepared by hydrogen peroxide oxidation of the corresponding diselenides in the presence of p-toluenesulfonic acid. Novel 2-(organylseleno)thiophenes were obtained by heating the protonated seleninic acids with a 50-fold excess of thiophene in glacial acetic acid. (C) 2011 Published by Elsevier Ltd.