(P)-6,6'-di(n-hexyl)-2,2'-di(methoxymethoxy)-1,1'-binaphthyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (P)-6,6'-di(n-hexyl)-2,2'-di(methoxymethoxy)-1,1'-binaphthyl
• 英文别名: 6-Hexyl-1-[6-hexyl-2-(methoxymethoxy)naphthalen-1-yl]-2-(methoxymethoxy)naphthalene
• 化学式: C₃₆H₄₆O₄
• 分子量: 542.759
• InChiKey: HIFGDOBUOVVNAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  40
• 可旋转键数：
  17
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (P)-6,6'-di(n-hexyl)-2,2'-di(methoxymethoxy)-1,1'-binaphthyl 在 仲丁基锂 、 碘 作用下， 以 四氢呋喃 、 环己烷 为溶剂， 反应 2.0h， 以67%的产率得到(M)-6,6'-di(n-hexyl)-3,3'-diiodo-2,2'-di(methoxymethoxy)-1,1'-binaphthyl
  参考文献：
  名称：

  Surprising Substituent Effects on the Self-Assembly of Helicates from Bis(bipyridyl) BINOL Ligands

  摘要：

  A number of different bis(bipyridyl) BINOL ligands were prepared using a convergent building block approach, These were studied with regard to their ability to undergo self-assembly to dinuclear helicatcs upon coordination to suitable late-transition-metal ions. Surprisingly, the substituents at the periphery of the ligand structure were found to have a marked influence on the outcome of the self-assembly processes with regard to the helicates composition, the stereoselectivity of the helicate formation, their redox reactivity, and their electronical properties as scrutinized by NMR- and CD-spectroscopic methods as well as ESI-mass spectrometric methods.

  DOI：

  10.1021/jo900254r
• 作为产物：
  描述：

  (R)-(+)-6,6`-二溴-2,2`-双(甲氧基亚甲氧基)-1,1`-联萘 、 1-碘己烷 在 magnesium 、 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 作用下， 以 乙醚 、 diethel ether 为溶剂， 以89%的产率得到(P)-6,6'-di(n-hexyl)-2,2'-di(methoxymethoxy)-1,1'-binaphthyl
  参考文献：
  名称：

  Surprising Substituent Effects on the Self-Assembly of Helicates from Bis(bipyridyl) BINOL Ligands

  摘要：

  A number of different bis(bipyridyl) BINOL ligands were prepared using a convergent building block approach, These were studied with regard to their ability to undergo self-assembly to dinuclear helicatcs upon coordination to suitable late-transition-metal ions. Surprisingly, the substituents at the periphery of the ligand structure were found to have a marked influence on the outcome of the self-assembly processes with regard to the helicates composition, the stereoselectivity of the helicate formation, their redox reactivity, and their electronical properties as scrutinized by NMR- and CD-spectroscopic methods as well as ESI-mass spectrometric methods.

  DOI：

  10.1021/jo900254r

文献信息

• Surprising Substituent Effects on the Self-Assembly of Helicates from Bis(bipyridyl) BINOL Ligands
  作者：Jens Bunzen、Rainer Hovorka、Arne Lützen

  DOI：10.1021/jo900254r

  日期：2009.8.7

  A number of different bis(bipyridyl) BINOL ligands were prepared using a convergent building block approach, These were studied with regard to their ability to undergo self-assembly to dinuclear helicatcs upon coordination to suitable late-transition-metal ions. Surprisingly, the substituents at the periphery of the ligand structure were found to have a marked influence on the outcome of the self-assembly processes with regard to the helicates composition, the stereoselectivity of the helicate formation, their redox reactivity, and their electronical properties as scrutinized by NMR- and CD-spectroscopic methods as well as ESI-mass spectrometric methods.