2-肼基萘并[1,2-d][1,3]噻唑 | 16942-72-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并噻唑类
• 中文名称: 2-肼基萘并[1,2-d][1,3]噻唑
• 英文名称: 2-Hydrazinonaphtho<1,2-d>thiazole
• 英文别名: 8-hydrazinonaphtho<1,2-d>thiazole；2-Hydrazinonaphtho<1,2>thiazol；2-hydrazino-naphtho[1,2-d]thiazole；2-Hydrazinylnaphtho[1,2-d]thiazole；benzo[e][1,3]benzothiazol-2-ylhydrazine
• CAS: 16942-72-6
• 化学式: C₁₁H₉N₃S
• 分子量: 215.279
• InChiKey: NVPCSQFCNORIOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.2
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  2-肼基萘并[1,2-d][1,3]噻唑 在 溶剂黄146 、 sodium nitrite 作用下， 以77%的产率得到Naphtho<1',2':4,5>thiazolo<3,2-d>tetrazole
  参考文献：
  名称：

  Syntheses of Naphtho[1′,2′:4,5]thiazolo[2,3-c]-1,2,4-triazoles and-[3,2-d]tetrazole

  摘要：

  DOI：

  10.1002/ardp.19853180320
• 作为产物：
  描述：

  萘并(1,2-d)噻唑-2-胺 在 盐酸肼 、 一水合肼 作用下， 以 乙二醇 为溶剂， 反应 4.0h， 以97%的产率得到2-肼基萘并[1,2-d][1,3]噻唑
  参考文献：
  名称：

  Syntheses of Naphtho[1′,2′:4,5]thiazolo[2,3-c]-1,2,4-triazoles and-[3,2-d]tetrazole

  摘要：

  DOI：

  10.1002/ardp.19853180320

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• [EN] POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY<br/>[FR] COMPOSÉ POLYMÉRISABLE ET CORPS OPTIQUEMENT ANISOTROPE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2017079867A1

  公开（公告）日：2017-05-18

  There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.

  提供一种可聚合的组合物，通过该组合物得到的薄膜聚合物在紫外光照射时，不太容易发生变色或排列缺陷。还提供了通过聚合该聚合物组合物得到的聚合物，以及使用该聚合物的光学各向异性体。本发明提供了一种具有由式（Z-0）表示的部分结构的可聚合低波长色散或可聚合反波长色散化合物。此外，本发明提供了一种含有该化合物的组合物；通过聚合该组合物得到的聚合物；以及通过使用该聚合物得到的光学各向异性体。
• POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY
  申请人：DIC Corporation

  公开号：US20180312481A1

  公开（公告）日：2018-11-01

  The present invention provides a compound represented by the general formula (I), and a polymerizable composition containing the compound. When the polymerizable composition containing the compound represented by the formula (I) is used to form a filmy product, the resulting filmy product exhibits less change over time in phase difference and reverse wavelength dispersion and when the filmy polymer is irradiated with UV light, peeling from a substrate is unlikely to be caused. Further, the invention provides a polymer obtained through polymerization of the polymerizable composition and an optically anisotropic body obtained using the polymer.

  本发明提供了一种由通式（I）表示的化合物，以及含有该化合物的可聚合组合物。当使用含有通式（I）表示的化合物的可聚合组合物形成薄膜产品时，所得的薄膜产品在相位差和反向波长色散方面随时间的变化较小，并且在用紫外光照射薄膜聚合物时，不太可能导致与基底的剥离。此外，本发明提供了通过聚合可聚合组合物获得的聚合物以及使用该聚合物制备的光学各向异性体。
• Reactions of 5-(Trialkyl)silylpent-1-en-4-yn-3-ones with Hydrazines: Original Synthetic Routes to Luminescent Substances Containing Azole Motifs
  作者：Alexander A. Golovanov、Ivan S. Odin、Kareem V. Gordon、Radik N. Itakhunov、Dmitry M. Gusev、Sergey A. Sokov、Anna V. Vologzhanina、Stanislav A. Grabovskiy、Ilya M. Sosnin、Anton I. Ukolov、Olga I. Orlova、Vladimir A. Lazarenko、Pavel V. Dorovatovskii、Darina D. Darmoroz、Anastasiia O. Piven、Tetiana Orlova

  DOI：10.1055/s-0043-1763601

  日期：2024.1

  isoxazoles, thiophenes, thiazoles, benzo[d]thiazoles, and benzo[d]imidazoles. In reactions with hydrazine and its monosubstituted aromatic and heteroaromatic derivatives, the mentioned pent-1-en-4-yn-3-ones, containing Me3Si, Et3Si, and t-BuMe2Si groups at the triple bond, give 3-(trialkylsilyl)ethynylpyrazolines. Following stages of desilylation and 1,3-dipolar cycloaddition with nitrile oxides, the 3-(tr

  在肼与三烷基甲硅烷基取代的交叉共轭烯酮（pent-1-en-4-yn-3-ones）作为基本结构单元的选择性反应的基础上，这项工作提出了合成多取代发光材料的通用方法炔属吡唑啉、吡唑和含有吡唑啉、异恶唑、噻吩、噻唑、苯并[d]噻唑和苯并[d]咪唑结构片段的组合多杂环的衍生物。在与肼及其单取代芳族和杂芳族衍生物的反应中，所提到的在三键处含有Me3Si、Et3Si和t-BuMe2Si基团的pent-1-en-4-yn-3-酮，得到3-(三烷基甲硅烷基)乙炔基吡唑啉。在脱甲硅烷基化和与氧化腈的 1,3-偶极环加成阶段之后，3-(三烷基甲硅烷基)乙炔基吡唑啉形成组合的多杂环衍生物。因此，开发了一种从交叉共轭烯酮、芳基肼和α-氯苯甲醛肟合成含吡唑啉异恶唑的路线。对合成的唑类衍生物的环缩合机理和发光性能的某些方面进行了检查。
• Polymerizable compound, polymerizable composition, polymer, optically anisotropic body, and method for producing polymerizable compound
  申请人：ZEON CORPORATION

  公开号：US10173992B2

  公开（公告）日：2019-01-08

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y1 to Y8 represent —C(═O)—O—, G1 and G2 represent a C1-20 divalent linear aliphatic group, Z1 and Z2 represent a C2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, Ax represents a C2-30 organic group with at least one aromatic ring, Ay represents a hydrogen atom or C1-20 alkyl group, A1 represents a trivalent aromatic group, A2 and A3 represent a C3-30 divalent alicyclic hydrocarbon group, A4 and A5 represent a C6-30 divalent aromatic group or the like, and Q1 represents a hydrogen atom.)

  一种可聚合化合物具有实用的低熔点，在通用溶剂中具有极佳的溶解性，并能以低成本生产光学薄膜，显示出低反射亮度，实现偏振光在宽波段上的均匀转换，即光学各向异性物品。羰基化合物可作为生产可聚合化合物的原料。(在式 (I) 中，Y1 至 Y8 代表 -C(═O)-O-，G1 和 G2 代表 C1-20 二价线性脂肪族基团，Z1 和 Z2 代表未被取代或被卤素原子取代的 C2-10 烯基，Ax 代表至少有一个芳香环的 C2-30 有机基团、Ay 代表氢原子或 C1-20 烷基，A1 代表三价芳基，A2 和 A3 代表 C3-30 二价脂环烃基，A4 和 A5 代表 C6-30 二价芳基或类似基团，Q1 代表氢原子。)