3-乙基-2-亚甲基-苯并[g][1,3]苯并噻唑 | 444986-72-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并噻唑类
• 中文名称: 3-乙基-2-亚甲基-苯并[g][1,3]苯并噻唑
• 英文名称: 3-ethyl-2-methylene-2,3-dihydro-naphtho[2,1-d]thiazole
• 英文别名: 3-ethyl-2-methyl-naphtho[2,1-d]thiazolium; betaine；3-Aethyl-2-methylen-2,3-dihydro-naphtho[2,1-d]thiazol；3-Aethyl-2-methyl-naphtho[2,1-d]thiazolium; Betain；3-Ethyl-2-methylidenebenzo[g][1,3]benzothiazole
• CAS: 444986-72-5
• 化学式: C₁₄H₁₃NS
• 分子量: 227.33
• InChiKey: NXYSFGNJESMUTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-乙基-2-亚甲基-苯并[g][1,3]苯并噻唑 、 苯亚胺代甲酸乙酯 在 zinc(II) chloride 作用下， 生成 (3-ethyl-3H-naphtho[2,1-d]thiazol-2-ylidene)-malonaldehyde-bis-phenylimine
  参考文献：
  名称：

  Hamer et al., Journal of the Chemical Society, 1947, p. 1434,1440

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium hydroxide 作用下， 生成 3-乙基-2-亚甲基-苯并[g][1,3]苯并噻唑
  参考文献：
  名称：

  Hamer et al., Journal of the Chemical Society, 1947, p. 954,956

  摘要：

  DOI：

文献信息

• Photoelectric conversion material, film containing the material, photoelectric conversion device, production method thereof, photosensor, imaging device and their use methods
  申请人：Fujifilm Corporation

  公开号：EP2292586A2

  公开（公告）日：2011-03-09

  A compound represented by the following formula (I), and a photoelectric conversion device containing the compound: wherein Z1 is a ring containing two carbon atoms and represents a 5-membered ring, a 6-membered ring or a condensed ring containing at least either a 5-membered ring or a 6-membered ring, each of L1, L2 and L3 independently represents an unsubstituted methane group or a substituted methine group, n represents an integer of 0 or more, each of R1, R2, R3, R4, R5 and R6 independently represents a hydrogen atom or a substituent, R1 and R2, R2 and R3, R4 and R5, or R5 and R6 may be combined with each other to form a ring, and each of R21 and R22 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, provided that the case where both R21 and R22 are an unsubstituted phenyl group is excluded.

  下式 (I) 所代表的化合物，以及含有该化合物的光电转换装置： 其中 Z1 是含有两个碳原子的环，代表 5 元环、6 元环或至少含有一个 5 元环或一个 6 元环的缩合环，L1、L2 和 L3 各自独立地代表未取代的甲烷基团或取代的甲基，n 代表 0 或以上的整数，R1、R2、R3、R4、R5 和 R6 各自独立地代表氢原子或取代基、R1和R2、R2和R3、R4和R5或R5和R6可相互结合形成一个环，R21和R22各自独立地代表取代的芳基、未取代的芳基、取代的杂芳基或未取代的杂芳基，但不包括R21和R22均为未取代的苯基的情况。
• Tolmachev,A.I.; Sribnaya,V.P., Journal of general chemistry of the USSR, 1965, vol. 35, p. 316 - 323
  作者：Tolmachev,A.I.、Sribnaya,V.P.

  DOI：——

  日期：——
• Tolmachev,A.I.; Sribnaya,V.P., Journal of general chemistry of the USSR, 1963, vol. 33, p. 3802 - 3808
  作者：Tolmachev,A.I.、Sribnaya,V.P.

  DOI：——

  日期：——
• Kiprianov,A.I.; Tolmachev,A.I., Journal of general chemistry of the USSR, 1960, vol. 30, p. 659 - 666
  作者：Kiprianov,A.I.、Tolmachev,A.I.

  DOI：——

  日期：——
• PHOTOELECTRIC CONVERSION MATERIAL, FILM CONTAINING THE MATERIAL, PHOTOELECTRIC CONVERSION DEVICE, PRODUCTION METHOD THEREOF, PHOTOSENSOR, IMAGING DEVICE AND THEIR USE METHODS
  申请人：HAMANO Mitsumasa

  公开号：US20110056562A1

  公开（公告）日：2011-03-10

  A compound represented by the following formula (I), and a photoelectric conversion device containing the compound: wherein Z 1 is a ring containing two carbon atoms and represents a 5-membered ring, a 6-membered ring or a condensed ring containing at least either a 5-membered ring or a 6-membered ring, each of L 1 , L 2 and L 3 independently represents an unsubstituted methine group or a substituted methine group, n represents an integer of 0 or more, each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 independently represents a hydrogen atom or a substituent, R 1 and R 2 , R 2 and R 3 , R 4 and R 5 , or R 5 and R 6 may be combined with each other to form a ring, and each of R 21 and R 22 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, provided that the case where both R 21 and R 22 are an unsubstituted phenyl group is excluded.