4-(10-Anthracen-9-yloxydecoxy)-9,14,19,24,26,28,30,32,34-nonamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene | 1492017-50-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4-(10-Anthracen-9-yloxydecoxy)-9,14,19,24,26,28,30,32,34-nonamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene
• CAS: 1492017-50-1
• 化学式: C₆₈H₇₆O₁₁
• 分子量: 1069.34
• InChiKey: MEXOXKNOSPHKDA-UHFFFAOYSA-N

物化性质

• 密度：
  1.137±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  17.1
• 重原子数：
  79
• 可旋转键数：
  22
• 环数：
  18.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  4-(10-Anthracen-9-yloxydecoxy)-9,14,19,24,26,28,30,32,34-nonamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene 反应 5.0h， 以100%的产率得到
  参考文献：
  名称：

  Dynamic Covalent Bond Based on Reversible Photo [4 + 4] Cycloaddition of Anthracene for Construction of Double-Dynamic Polymers

  摘要：

  Dynamic covalent bonds supplied by reversible anthracene dimerization were combined with pillar[5]arene/imidazole host-guest interactions to construct double-dynamic polymers. Heating such polymers (in solution or as a gel) led to depolymerization by dissociation of either the host-guest complexes alone or the complexes and the anthracene dimers, depending on the extent of heating. The polymers reformed readily upon cooling or irradiation.

  DOI：

  10.1021/ol403015s
• 作为产物：
  描述：

  蒽酮 、 12-((10-Bromodecyl)oxy)-15,32,35,52,55,72,75,92,95-nonamethoxy-1,3,5,7,9(1,4)-pentabenzenacyclodecaphane 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 以82%的产率得到4-(10-Anthracen-9-yloxydecoxy)-9,14,19,24,26,28,30,32,34-nonamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene
  参考文献：
  名称：

  Dynamic Covalent Bond Based on Reversible Photo [4 + 4] Cycloaddition of Anthracene for Construction of Double-Dynamic Polymers

  摘要：

  Dynamic covalent bonds supplied by reversible anthracene dimerization were combined with pillar[5]arene/imidazole host-guest interactions to construct double-dynamic polymers. Heating such polymers (in solution or as a gel) led to depolymerization by dissociation of either the host-guest complexes alone or the complexes and the anthracene dimers, depending on the extent of heating. The polymers reformed readily upon cooling or irradiation.

  DOI：

  10.1021/ol403015s