tris<2-(1-anthraquinonyloxy)ethyl>amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: tris<2-(1-anthraquinonyloxy)ethyl>amine
• 英文别名: tris[2-(1-anthraquinonyloxy)ethyl]amine；1-[2-[Bis[2-(9,10-dioxoanthracen-1-yl)oxyethyl]amino]ethoxy]anthracene-9,10-dione
• 化学式: C₄₈H₃₃NO₉
• 分子量: 767.791
• InChiKey: ZDTUCXMHOSBPAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  58
• 可旋转键数：
  12
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  133
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1-氯蒽醌 在 sodium hydride 、 cesium fluoride 作用下， 以 二甲基亚砜 为溶剂， 反应 10.75h， 生成 tris<2-(1-anthraquinonyloxy)ethyl>amine
  参考文献：
  名称：

  Efficient synthesis of alkoxyanthraquinones from fluoroanthraquinones and their preliminary electrochemistry

  摘要：

  The reaction of 1,8-dichloroanthraquinone with CsF in DMSO under anhydrous conditions affords improved yields of the corresponding difluoro derivative 2. Nucleophilic displacement reactions using simple alkoxide nucleophiles or crown ether derivatives on 2 allows the preparation of 1,8-dialkoxyanthraquinones 5-10 in good to excellent yields. Compounds 8 and 10 exhibit enhanced sodium binding properties upon reduction to the corresponding mono- and dianions. Cation binding enhancements are larger than those previously observed for structurally related systems.

  DOI：

  10.1021/jo00060a010

文献信息

• Echegoyen L., Hafez Yehia, Lawson Raphael C., de Mendoza J., Torres T., J. Org. Chem, 58 (1993) N 8, S 2009-2012
  作者：Echegoyen L., Hafez Yehia, Lawson Raphael C., de Mendoza J., Torres T.

  DOI：——

  日期：——
• Echegoyen L., Hafez Y., Lawson R. C., de Mendoza J., Torres T., Tetrahedron Lett., 35 (1994) N 34, S 6383-6386
  作者：Echegoyen L., Hafez Y., Lawson R. C., de Mendoza J., Torres T.

  DOI：——

  日期：——
• Efficient synthesis of alkoxyanthraquinones from fluoroanthraquinones and their preliminary electrochemistry
  作者：L. Echegoyen、Yehia Hafez、Raphael C. Lawson、J. de Mendoza、T. Torres

  DOI：10.1021/jo00060a010

  日期：1993.4

  The reaction of 1,8-dichloroanthraquinone with CsF in DMSO under anhydrous conditions affords improved yields of the corresponding difluoro derivative 2. Nucleophilic displacement reactions using simple alkoxide nucleophiles or crown ether derivatives on 2 allows the preparation of 1,8-dialkoxyanthraquinones 5-10 in good to excellent yields. Compounds 8 and 10 exhibit enhanced sodium binding properties upon reduction to the corresponding mono- and dianions. Cation binding enhancements are larger than those previously observed for structurally related systems.