cyclohexyl vinyl sulfide | 18888-48-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: cyclohexyl vinyl sulfide
• 英文别名: Cyclohexane, (ethenylthio)-；ethenylsulfanylcyclohexane
• CAS: 18888-48-7
• 化学式: C₈H₁₄S
• 分子量: 142.265
• InChiKey: WZCMJGCQGDDUID-UHFFFAOYSA-N

物化性质

• 沸点：
  69-71 °C(Press: 9 Torr)
• 密度：
  0.93±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cyclohexyl vinyl sulfide 在 过氧乙酸 作用下， 以 乙醚 为溶剂， 生成 (vinylsulfonyl)cyclohexane
  参考文献：
  名称：

  A new method of synthesizing ?,?-unsaturated sulfides

  摘要：

  DOI：

  10.1007/bf00904043
• 作为产物：
  描述：

  环己硫醇 、 calcium carbide 在 水 、 potassium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以95%的产率得到cyclohexyl vinyl sulfide
  参考文献：
  名称：

  以碳化钙为乙炔源的高效无金属合成乙烯基硫代酸酯的途径

  摘要：

  在标准实验室设置中，不容易进行涉及高压乙炔的化学反应。爆炸的危险和技术难题极大地使设备复杂化，并大大增加了成本。

  DOI：

  10.1039/c5gc01552a

文献信息

• Intermolecular Radical Mediated Anti-Markovnikov Alkene Hydroamination Using<i>N</i>-Hydroxyphthalimide
  作者：Samuel W. Lardy、Valerie A. Schmidt

  DOI：10.1021/jacs.8b06881

  日期：2018.10.3

  An intermolecular anti-Markovnikov hydroamination of alkenes has been developed using triethyl phosphite and N-hydroxyphthalimide. The process tolerates a wide range of alkenes, including vinyl ethers, silanes, and sulfides as well as electronically unbiased terminal and internal alkenes. The resultant N-alkylphthalimides can readily be transformed to the corresponding primary amines. Mechanistic probes

  使用亚磷酸三乙酯和 N-羟基邻苯二甲酰亚胺开发了烯烃的分子间反马尔科夫尼科夫加氢胺化反应。该工艺可耐受多种烯烃，包括乙烯基醚、硅烷和硫化物以及电子无偏的末端和内部烯烃。所得的 N-烷基邻苯二甲酰亚胺可以很容易地转化为相应的伯胺。机理探针表明，该过程是通过亚磷酸酯促进的 N-羟基邻苯二甲酰亚胺的自由基脱氧来获得邻苯二甲酰亚胺自由基介导的。
• Sulfur-mediated C(sp 2 )–H imidation and 1,2-imidofluorination of vinyl sulfides
  作者：Zhanhui Yang、Shiyi Yang、Muhammad Sohail Haroone、Wei He、Jiaxi Xu

  DOI：10.1016/j.tet.2017.04.057

  日期：2017.6

  A new strategy for the C(sp2)–H imidation and 1,2-imidofluorination of vinylsulfides has been established through simple treatment with N-fluorobis(benzenesulfonyl)imide, which acts as both oxidant and nitrogen source. For alkyl and electron-rich aryl vinylsulfides, alkyl/arylthioenamines are produced in up to 92% total yields. However, for steric and electron-deficient aryl vinylsulfides, 1,2-imidofluorination

  通过用N-氟双（苯磺酰基）酰亚胺作为氧化剂和氮源的简单处理，已经建立了乙烯基硫化物的C（sp 2）-H酰亚胺化和1,2-亚氨基氟化的新策略。对于富含烷基和电子的芳基乙烯基硫化物，可以以高达92％的总收率生产烷基/芳基硫代亚胺。但是，对于空间位阻和电子缺陷的芳基乙烯基硫化物，可以以高达73％的收率制备1,2-亚氨基氟化产物。化学选择性由芳基取代基的空间和电子效应控制。提出将ion离子作为两个反应的关键中间体。
• Thermosetting compositions, thermal latent hydroxyl compounds, thermal latent thiol compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0452841A2

  公开（公告）日：1991-10-23

  Thermosetting compositions are excellent in storage stability, useful as one component thermosetting compositions, give cured products having excellent chemical properties, physical properties and weathering resistance and favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting compositions comprise a compound having in the molecule two or more hydroxyl groups and/or thiol groups blocked by a vinyl ether compound, a vinyl thioether compound or a heterocyclic compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked hydroxyl and/or thiol compound by heating and a thermal latent acid catalyst. The blocked hydroxyl and/or thiol group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有优异的储存稳定性，可用作单组分热固性组合物，固化后的产品具有优异的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 热固性组合物包括一种化合物，其分子中的两个或两个以上羟基和/或硫醇基团被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键并以氧或硫作为杂原子的杂环化合物阻断；一种化合物，其分子中的两个或两个以上活性官能团可通过加热与被阻断的羟基和/或硫醇化合物形成化学键；以及一种热潜伏酸催化剂。第一种化合物的受阻羟基和/或硫醇基团与第二种化合物的活性官能团可包含在同一分子中。
• Thermosetting compositions, thermal latent carboxyl compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0451738A2

  公开（公告）日：1991-10-16

  Thermosetting composition is excellent in storage stability, is useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有出色的储存稳定性，可用作单组分热固性组合物，固化后的产品具有出色的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 这种热固性组合物包括一种化合物，其分子中有两个或两个以上的羧基被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键且氧或硫为杂原子的杂化合物封住；一种化合物，其分子中有两个或两个以上的活性官能团，通过加热可与被封住的羧基化合物形成化学键；还可选择使用一种热潜伏酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。
• Thermosetting compositions, thermal latent acid catalysts, method of coating and coated articles
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0535667A2

  公开（公告）日：1993-04-07

  Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.

  热固性组合物包括：分子中具有两个或两个以上被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基型双键且氧或硫为杂原子的杂化合物封端的羧基的化合物；具有两个或两个以上可通过加热与被封端的羧基化合物形成化学键的活性官能团的化合物；特定的乙烯基醚或乙烯基硫醚和热潜酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。热固性组合物固化后的产品具有优异的化学性质、物理性质、耐候性和储存稳定性，可用于涂料组合物、油墨、粘合剂和模塑塑料。