2-Bromonaphtho[2,1-b][1]benzothiole | 1266680-27-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-Bromonaphtho[2,1-b][1]benzothiole
• 英文别名: 2-bromonaphtho[2,1-b][1]benzothiole
• CAS: 1266680-27-6
• 化学式: C₁₆H₉BrS
• 分子量: 313.217
• InChiKey: JYELFAHLPYPEEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-Bromonaphtho[2,1-b][1]benzothiole 在 正丁基锂 、 trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) 、 碘 、 sodium acetate 、 methyloxirane 作用下， 以 四氢呋喃 、 N,N-二甲基乙酰胺 、 甲苯 为溶剂， 反应 50.0h， 生成 benzo[b]benzo[5,6]phenanthro[4,3-d]thiophen-13-yldiphenylphosphane
  参考文献：
  名称：

  Synthesis and characterisation of a new helically chiral ruthenium complex

  摘要：

  A new helically chiral hexacyclic phosphine, containing one thiophene ring was prepared in good yield via a five-step sequence involving a palladium-catalysed Mizoroki-Heck coupling reaction and classical oxidative photocyclisation. A mononuclear air stable ruthenium complex of this phosphine was also prepared and characterised. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.11.104
• 作为产物：
  描述：

  2-vinylbenzo[b]thiophene 在 trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) 、 碘 、 sodium acetate 、 methyloxirane 作用下， 以 N,N-二甲基乙酰胺 、 甲苯 为溶剂， 反应 50.0h， 生成 2-Bromonaphtho[2,1-b][1]benzothiole
  参考文献：
  名称：

  Synthesis and characterisation of a new helically chiral ruthenium complex

  摘要：

  A new helically chiral hexacyclic phosphine, containing one thiophene ring was prepared in good yield via a five-step sequence involving a palladium-catalysed Mizoroki-Heck coupling reaction and classical oxidative photocyclisation. A mononuclear air stable ruthenium complex of this phosphine was also prepared and characterised. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.11.104

文献信息

• Synthesis, X-Ray Analysis, and Evaluation of the Optoelectronic Properties of a New Thia[6]helicene
  作者：Souad Moussa、Faouzi Aloui、Pascal Retailleau、Béchir Ben Hassine

  DOI：10.1080/00397911.2010.534572

  日期：2012.4.1

  Abstract The synthesis and structural characterization of a new hexahelicene derivative is reported. This compound features a new type of structure bearing a bromine atom. Suitable crystals of the latter indicate that its conformation closely resembles that of the unsubstituted [6]helicene, whose idealized symmetry is C2. The optoelectronic properties of this helical hexacyclic system were determined

  摘要 报道了一种新的六螺旋烯衍生物的合成和结构表征。这种化合物具有一种带有溴原子的新型结构。后者的合适晶体表明其构象与未取代的[6]螺旋的构象非常相似，其理想化的对称性为C2。确定了这种螺旋六环系统的光电特性并表现出非常有趣的行为。图形概要
• Synthesis and resolution of a new thiahexahelicene
  作者：Souad Moussa、Faouzi Aloui、Béchir Ben Hassine

  DOI：10.1016/j.tetlet.2012.07.076

  日期：2012.10

  selected position on the terminal aromatic ring, was prepared in a good yield through Heck coupling and photocyclization reactions. The X-ray crystal structure of the product indicates that its conformation closely resembles that of the unsubstituted hexahelicene, whose idealized symmetry is C2. Both enantiomers of the new helically chiral hexacyclic system have been successfully separated using (R)-

  通过Heck偶联和光环化反应，以高收率制备了在末端芳族环的选定位置上带有甲氧基的新的硫杂六环烯。产物的X射线晶体结构表明其构象与理想取代的对称性为C 2的未取代己烯的构象非常相似。使用（R）-2-邻苯二甲酰亚胺基丙酸氯化物作为手性拆分剂已成功分离出新的螺旋手性六环体系的两种对映体。
• [EN] COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRONIQUE ORGANIQUE, ÉLÉMENT ÉLECTRONIQUE ORGANIQUE L'UTILISANT, ET DISPOSITIF ÉLECTRONIQUE LE COMPRENANT<br/>[KO] 유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2017048025A1

  公开（公告）日：2017-03-23

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